Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.

The current invention relates a process for making and using a bulk catalyst precursor (i.e. no support material is added as such) comprising Ni and Mo and/or W and an organic component, wherein the molar ratio of C:(Mo+W) ranges from 1.5 to 10. The bulk catalyst precursor is prepared from a mixture of metal-precursors with an organic agent. The organic agent is partly decomposed to form a mixed metal-oxide/C phase which is in effect the bulk catalyst precursor. This bulk catalyst precursor (i) is effectively insoluble in water (ii) does not have any appreciable pore volume or surface area and (iii) does not contain a (nano)crystalline metal-oxide phase as characterized by XRD.

The current invention relates a process for making and using a bulk catalyst precursor (i.e. no support material is added as such) comprising Ni and Mo and/or W and an organic component, wherein the molar ratio of C:(Mo+W) ranges from 1.5 to 10. The bulk catalyst precursor is prepared from a mixture of metal-precursors with an organic agent. The organic agent is partly decomposed to form a mixed metal-oxide/C phase which is in effect the bulk catalyst precursor. This bulk catalyst precursor (i) is effectively insoluble in water (ii) does not have any appreciable pore volume or surface area and (iii) does not contain a (nano)crystalline metal-oxide phase as characterized by XRD.

Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.

Composite catalysts includes zeolite particles at least partially embedded in a catalyst support material and at least one catalytically active compound deposited on the outer surfaces and pore surfaces of the catalyst support material, zeolite particles, or both. A method of making the composite catalysts may include preparing a catalyst precursor mixture that includes the zeolite, catalyst support material, triblock copolymer surfactant, and the catalytically active compound precursor and spray drying the catalyst precursor mixture. The composite catalysts may be used as a single catalyst for conducting olefin metathesis and cracking reactions. A method for producing propene may include contacting a butene-containing feed with the composite catalysts.

The disclosure discloses an anti-haze anti-harmful gas air filter membrane as well as a preparation method and application thereof. The air filter membrane comprises a nano fiber membrane made of nano fibers and having a two-dimensional or three-dimensional network structure. The nano fiber membrane can be a high-molecular polymer nano fiber membrane prepared by utilizing an electrostatic spinning process, and can also be doped with an organic or inorganic additive capable of adsorbing and absorbing harmful gases, such as VOCs, NO.sub.x, SO.sub.x and NH.sub.3, in the air and/or a photocatalyst capable of degrading these harmful gases in a photocatalysis manner, or the like. The anti-haze anti-harmful gas air filter membrane disclosed by the disclosure can efficiently filter PM2.5 and PM10 particulate pollutants and the like in the air and simultaneously can efficiently identify and clear multiple harmful gases in the air. The anti-haze anti-harmful gas air filter membrane has a wide application prospect in the field of air purification, for example, can be applied to air purification devices, such as screen windows, gauze masks and filter screens.

The disclosure discloses an anti-haze anti-harmful gas air filter membrane as well as a preparation method and application thereof. The air filter membrane comprises a nano fiber membrane made of nano fibers and having a two-dimensional or three-dimensional network structure. The nano fiber membrane can be a high-molecular polymer nano fiber membrane prepared by utilizing an electrostatic spinning process, and can also be doped with an organic or inorganic additive capable of adsorbing and absorbing harmful gases, such as VOCs, NO.sub.x, SO.sub.x and NH.sub.3, in the air and/or a photocatalyst capable of degrading these harmful gases in a photocatalysis manner, or the like. The anti-haze anti-harmful gas air filter membrane disclosed by the disclosure can efficiently filter PM2.5 and PM10 particulate pollutants and the like in the air and simultaneously can efficiently identify and clear multiple harmful gases in the air. The anti-haze anti-harmful gas air filter membrane has a wide application prospect in the field of air purification, for example, can be applied to air purification devices, such as screen windows, gauze masks and filter screens.

Disclosed is a polyoxometalate compound including a metal-substituted polyoxometalate. The metal-substituted polyoxometalate includes a polyoxometalate having defect sites, a substituting metal atom introduced into the defect sites, and an organic ligand. The substituting metal atom is divalent platinum or palladium. The organic ligand may be a bidentate ligand having an aliphatic heterocycle containing two nitrogen atoms coordinately bonded to the substituting metal atom. One substituting metal atom is introduced into one defect site.

Disclosed is a polyoxometalate compound including a metal-substituted polyoxometalate. The metal-substituted polyoxometalate includes a polyoxometalate having defect sites, a substituting metal atom introduced into the defect sites, and an organic ligand. The substituting metal atom is divalent platinum or palladium. The organic ligand may be a bidentate ligand having an aliphatic heterocycle containing two nitrogen atoms coordinately bonded to the substituting metal atom. One substituting metal atom is introduced into one defect site.

An ink composition, including a quantum dot; a metal catalyst; an aromatic halide compound; an ene compound including at least one C—H moiety and a carbon-carbon unsaturated bond; and optionally, a metal oxide particle, wherein the metal catalyst is a metal salt, a metal coordination complex, or a combination thereof, wherein the metal catalyst comprises a metal that is palladium, nickel, ruthenium, rhodium, iridium, iron, cobalt, chromium, copper, platinum, silver, gold, or a combination thereof.