The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C.sub.2+ compounds and non-C.sub.2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C.sub.2+ impurities from the C.sub.2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H.sub.2 with CO and/or CO.sub.2 in the non-C.sub.2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.

The present application relates to a multifunctional filter medium and a method of manufacturing the same. The multifunctional filter medium of the present application is capable of significantly reducing fine dust, harmful microorganisms, and toxic gases and reducing a pressure decrease during filtration due to exclusion of high-density nanofiber, thereby minimizing energy required for filtration and exhibiting sufficient filtration performance as a single filter medium.

A catalyst fibrous structure having a catalyst metal carried on a fibrous structure, wherein (a) a Log differential micropore volume distribution curve thereof obtained by measurement using a mercury intrusion technique has a peak having a maximum micropore diameter in the range of from 0.1 m to 100 m: (b) a Log, differential micropore volume at the peak is 0.5 mL/g or more; and (c) an amount of a catalyst metal compound and a binder carried per unit volume is 0.05 g/mL or more. Also, a production method for producing a catalyst fibrous structure.

A retaining material that can sufficiently maintain the function of retaining a pollution control element in a pollution control device at high temperature. In one aspect, the retaining material has a mat shape and contains inorganic fiber material, with the retaining material containing: a surface layer containing inorganic colloid particles; and an internal region positioned further to the inside than the surface layer, impregnated with inorganic colloid particles and organic binder; wherein the surface layer contains inorganic colloid particles at a higher concentration than the internal region; and the amount of inorganic colloid particles in the internal region is 1 mass % to 10 mass % based on the total mass of the retaining material.

This present invention discloses method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material. The method comprises: immersing a filter material in a solution containing sodium lauryl sulfate and nitric acid; first modifying the surface of the filter material by using the sodium lauryl sulfate so that a charge layer is wound around the surface of the filter material and tightly absorbs H.sup.+ in an acid solution; and then adding potassium permanganate as an oxidant to react with H.sup.+ on the surface of the filter material to generate nano flower-like manganese dioxide in situ on the surface of the filter material, so as to obtain a composite filter material having a denitration function. Since the surface of the filter fiber is uniformly coated with a layer of nanoflower-like manganese dioxide, the manganese dioxide of such a morphology has a larger specific surface area and a higher pore volume than ordinary manganese dioxide, and is more conducive to the diffusion of the reaction gas, and therefore the catalytic filter material has very excellent low-temperature activity, the NOx removal efficiency reach 97% at 160 C., and the composite filter material has excellent bonding strength, gas permeability and catalytic stability. In addition, the method is environmentally friendly, reagents used in the experiment are cheap and readily available, and the experimental process is easy to operate, and the reaction process takes only 2-3 hours; therefore, the method is advantageous for large-scale experimental production.

The present development is a metal particle coated nanowire catalyst for use in the hydrodesulfurization of fuels and a process for the production of the catalyst. The catalyst comprises titanium(IV) oxide nanowires wherein the nanowires are produced by exposure of a TiO.sub.2KOH paste to microwave radiation. Metal particles selected from the group consisting of molybdenum, nickel, cobalt, tungsten, or a combination thereof, are impregnated on the metal oxide nanowire surface. The metal impregnated nanowires are sulfided to produce catalytically-active metal particles on the surface of the nanowires The catalysts of the present invention are intended for use in the removal of thiophenic sulfur from liquid fuels through a hydrodesulfurization (HDS) process in a fixed bed reactor. The presence of nanowires improves the HDS activity and reduces the sintering effect, therefore, the sulfur removal efficiency increases.

The present invention provides a process for preparing a catalyst, wherein said process comprises:(i) preparing a mixture of one or more aromatic alcohol monomers and/or non-aromatic monomers, solvent, polymerization catalyst, crosslinking agent, suspension stabilizing agent and one or more metal salts, under conditions sufficient to produce polymeric beads doped with one or more metals or salts thereof; (ii) carbonizing, activating and then reducing the polymeric beads produced in step (i) to produce metal nanoparticles-doped porous carbon beads; (iii) subjecting the metal nanoparticles-doped porous carbon beads produced in step (ii) to chemical vapour deposition in the presence of a carbon source to produce metal nanoparticles-doped porous carbon beads comprising carbon nanofibers; and (iv) doping the metal nanoparticles-doped porous carbon beads comprising carbon nanofibers produced in step (iii) with an oxidant; catalyst prepared by said process; and a process for treating waste water from an industrial process for producing propylene oxide, which process comprises subjecting the waste water to a catalytic wet oxidation treatment in the presence of said catalyst.

Mixed-phase TiO.sub.2 nanofibers prepared via a sol-gel technique followed by electrospinning and calcination are provided as photocatalysts. The calcination temperature is adjusted to control the rutile phase fraction in TiO.sub.2 nanofibers relative to the anatase phase. Post-calcined TiO.sub.2 nanofibers composed of 38 wt % rutile and 62 wt % anatase exhibited the highest initial rate constant of UV photocatalysis. This can be attributed to the combined influences of the fibers' specific surface areas and their phase compositions.

The present disclosure relates to a reactor containing of catalyst particles, a layer of fibrous catalyst particles support below said catalyst particles and a lower means of structural support below said catalyst particles with the associated benefit of such a reactor having increased space for catalyst particles, compared to a reactor with inert particles supporting the catalyst particles.

The invention relates to a wall flow filter for removing particulate matter from the exhaust of internal combustion engines, comprising a wall flow filter substrate having a length L, and different coatings Z and F, the wall flow filter substrate being provided with channels E and A which run parallel between a first end and a second end of the wall flow filter substrate, are separated by porous walls, and form surfaces O.sub.E and O.sub.A, respectively; channels E are closed at the second end, and channels A are closed at the first end; coating Z is disposed in the porous walls and/or on surfaces O.sub.A, but not on surfaces O.sub.E, and contains palladium and/or rhodium and a cerium/zirconium mixed oxide. The wall flow filter is characterized in that coating F is disposed in the porous walls and/or on surfaces O.sub.E, but not on surfaces O.sub.A, and comprises a mineral material and no precious metal.