B01J37/0027

Method for producing oxide catalyst and method for producing unsaturated nitrile

A method for producing an oxide catalyst according to the present invention is a method for producing an oxide catalyst containing Mo, V, Sb, and Nb, the method including: a raw material preparation step of obtaining an aqueous mixed liquid containing Mo, V, Sb, and Nb; an aging step of subjecting the aqueous mixed liquid to aging at more than 30° C.; a drying step of drying the aqueous mixed liquid, thereby obtaining a dried powder; and a calcination step of calcining the dried powder, thereby obtaining the oxide catalyst, wherein, in the raw material preparation step and/or the aging step, precipitation of Nb is facilitated by performing at least one operation selected from the group consisting of the following (I) to (III): (I) in the raw material preparation step, the aqueous mixed liquid is prepared by mixing a Nb raw material liquid containing Nb with a MoVSb raw material liquid containing Mo, V, and Sb, wherein ammonia is added to at least one of the MoVSb raw material liquid, the Nb raw material liquid, and the aqueous mixed liquid such that a molar ratio in terms of NH.sub.3/Nb in the aqueous mixed liquid is adjusted to be 0.7 or more, and in the aging step, a temperature of the aqueous mixed liquid is adjusted to more than 50° C.; (II) in the aging step, a temperature of the aqueous mixed liquid is adjusted to more than 65° C.; and (III) in the raw material preparation step, the aqueous mixed liquid is prepared by mixing a Nb raw material liquid containing Nb with a MoVSb raw material liquid containing Mo, V, and Sb, wherein a molar ratio in terms of H.sub.2O.sub.2/Nb in the Nb raw material liquid is adjusted to less than 0.2, and in the aging step, a temperature of the aqueous mixed liquid is adjusted to more than 50° C.

METHOD FOR PREPARING CATALYTIC NANOPARTICLES, CATALYST SURFACES, AND/OR CATALYSTS

A method for preparing catalyst particles that includes providing an average atomic number Zavr for a catalyst starting material, providing an ion beam having an ion beam current and selecting an ion beam dose X expressed in ions/g, based on the weight of the catalyst starting material, where X follows the following equations: (7/Zavr)×10.sup.18 ions/g<X<(7/Zavr)×6×10.sup.19 ions/g, implanting the catalyst starting material with an ion beam dose X primarily comprising the selected ions, where the ratio of the current of the ion beam current to the cross-section area of the ion beam, measured at the point of contact with the catalyst starting material is at least 1.2 μA/mm.sup.2, thereby obtaining a catalyst. The resulting catalyst particles are useful in NOx, CO, and/or HC emission reduction devices, fuel cells, or catalysts in chemical reactions.

Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis

Set forth herein is a Fischer-Tropsch catalytic system that allows for the efficient and selective conversion of syngas to useful hydrocarbons (nC.sub.4-nC.sub.24) as well as heavy alcohols (nC.sub.1-nC.sub.9) under ambient conditions. The instantly disclosed catalytic system is more practical and scalable than other known Fischer-Tropsch catalytic systems. Also set forth herein new catalysts which comprise supported metal-oxide-based catalysts. These catalysts are useful for the conversion of syngas into liquid hydrocarbon fuels under ambient reaction conditions. The instantly disclosed catalytic system can be made in a one-pot high mass production method, which is commercially practical and scalable. A variety of reaction products can be produced by making minor adjustments to the processes disclosed herein, e.g., by adjusting catalyst composition, reaction temperature and/or reaction pressure. The instantly disclosed process(es) produce Fischer-Tropsch products, heavy hydrocarbons (e.g., paraffin's, olefins, and their derivatives), and alcohols.

Hexaaluminate-comprising catalyst for the reforming of hydrocarbons and a reforming process

A hexaaluminate-containing catalyst containing a hexaaluminate-containing phase which includes cobalt and at least one further element of La, Ba or Sr. The catalyst contains 2 to 15 mol % Co, 70 to 90 mol % Al, and 2 to 25 mol % of the further element of La, Ba or Sr. In addition to the hexaaluminate-containing phase, the catalyst can include 0 to 50% by weight of an oxidic secondary phase. The process of preparing the catalyst includes contacting an aluminum oxide source with cobalt species and at least with an element from the group of La, Ba and Sr. The molded and dried material is preferably calcined at a temperature greater than or equal to 800° C. In the reforming process for reacting hydrocarbons in the presence of CO.sub.2, the catalyst is used at a process temperature of greater than 700° C., with the process pressure being greater than 5 bar.

Reusable porous Na(SiAl)O6.xH2O/NiFe2O4 structure for selective removal of heavy metals from waste waters
11014082 · 2021-05-25 ·

The 3-Glycidoxypropyltrimethoxysilane (GPTMS) decorated magnetic more-aluminosilicate shell Na(Si.sub.2Al)O.sub.6.xH.sub.2O/NiFe.sub.2O.sub.4 structures were hydrothermally prepared and were well characterized by different analysis methods. The XRD patterns were truly proved the formation of the aluminosilicate layer on the surface of the magnetic cores. In addition to the TGA curve which implied on the presence of the GPTMS organic segment, nitrogen adsorption-desorption isotherms demonstrated that the final sample has high specific surface area. The products were incredibly able to remove the toxic lead and cadmium ions from the wastewaters. Furthermore, the mechanism of the sorption and the role of GPTMS in enhancing the sorption capacity of the structures were comprehensively discussed.

Catalyst and process using the catalyst

A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity. The zinc is contained in aggregates which have a size across their largest dimension of up to 1 micron. The aggregates are distributed throughout at least the surface region of the catalyst and greater than 40 weight % of the aggregates contain a concentration of zinc that is within ±1 weight % of the modal concentration of zinc in those aggregates.

METHOD FOR PREPARING CATALYTIC NANOPARTICLES, CATALYST SURFACES, AND/OR CATALYSTS

A method for preparing catalyst particles that includes providing a catalyst starting material, an ion beam, and an electrostatic charge reduction device selected from a source of UV light, a source of X-rays, an electron beam, and an electrically grounded catalytic starting material carrier. The method further includes implanting the catalyst starting material with an ion beam dose primarily made of monocharged or monocharged and multicharged ions with an energy of the monocharged ions in the ion beam from at least 10 keV to at most 100 keV thereby obtaining a catalyst. The obtained catalyst particles particles are useful in NOx, CO, and/or HC emission reduction devices, fuel cells, or catalysts in chemical reactions.

NOVEL METHOD OF CATALYST PREPARATION BY PRESSURE DILUTION
20210114000 · 2021-04-22 ·

Described is a method for the preparation of a reforming catalyst. The method comprises: (a) depositing a metal precursor on a porous support by wet impregnation, wherein the porous support is selected from the group consisting of a fumed silica, a fumed metal oxide, and combinations thereof; (b) drying the porous support after depositing the metal precursor to form a powder; (c) adding additional porous support to the powder to form a diluted powder; and (d) pressing the diluted powder to form pellets.

Copper oxide nanoparticles synthesized using <i>Rhatany </i>root extract

The copper oxide nanoparticles synthesized using Rhatany root extract involves preparing the Rhatany root extract by adding powdered Rhatany roots to boiling water, allowing the mixture to soak overnight, and removing any solid residue by filtering to obtain the aqueous extract. The copper oxide nanoparticles are prepared by mixing equal volumes of the aqueous Rhatany root extract and 0.1 M aqueous copper sulfate, heating the mixture at 80 C. for 40 minutes, and adding 1 M sodium hydroxide dropwise to the mixture to precipitate CuO. The precipitate is removed by centrifuge, washed with ethanol, dried, and calcined at 400 C. for 4 hours to obtain the copper oxide nanoparticles. The resulting nanoparticles proved effective in degrading wastewater dyes, showed anticancer activity against human cervical cancer by cell viability assay, and showed antibacterial activity against various strains of bacteria by agar diffusion.

Graphene modified iron-based catalyst and preparation and application thereof for use in Fischer-Tropsch reaction

The present disclosure disclosures a graphene modified iron-based catalyst and preparation and application thereof for use in Fischer-Tropsch reaction, belonging to the technical field of catalytic conversion of synthesis gas. The catalyst consists of, by mass percent, 0.01-30% of graphene, 0-20% of promoter and 60-99.99% of iron oxide powder. The preparation process of the catalyst is as follows: the graphene, the iron oxide powder and the promoter are sequentially placed in an aqueous solution for ultrasonic treatment and stirring, and then rotary evaporation, drying and calcining are conducted. The preparation method is simple. The catalyst shows excellent activity in the Fischer-Tropsch reaction, and maintains a high CO conversion rate of 90% or above for a long time at a very high reaction space velocity; meanwhile, the alkane content in a product is low, and an olefin-alkane ratio can reach 14, thus having an extremely high industrial application value.