Disclosed is an in-situ preparation method for a catalyst for Reaction I: methanol and/or dimethyl ether with toluene are used to prepare light olefins and co-produce para-xylene, and/or Reaction II: methanol and/or dimethyl ether with benzene are used to prepare at least one of toluene, para-xylene and light olefins, comprising: contacting at least one of a phosphorus reagent, a silylation reagent and water vapor with a molecular sieve in a reactor to prepare, in situ, the catalyst for the Reaction I and/or the Reaction II, wherein the reactor is a reactor of the Reaction I and/or the Reaction II. By directly preparing a catalyst in a reaction system, the entire chemical production process is simplified, the catalyst preparation and transfer steps are saved, and the operation thereof is easy. The catalyst prepared in situ can be directly used for in situ reactions.

The present disclosure relates to the technical field of fine chemical engineering, and particularly discloses a stepwise solidus synthesis method for a micro-mesoporous calcium aluminate catalyst, comprising: mixing a calcium oxide-based powder with an alumina-based powder and an adhesion pore-enlarging agent; pelleting and molding the mixture; pyrolyzing and coking the pelleted and molded product in a rotary kiln reactor under the conditions including an outlet reaction temperature of 300 C.500 C. and a residence time of 0.23.5 h; and subsequently carrying out a solidus reaction in an internal heating rotary kiln reactor under the conditions including an outlet reaction temperature of 900 C.1,500 C. and a residence time of 0.15 h to produce calcium aluminate; decomposing and gasifying the pyrolyzed char in the calcium aluminate to promote the formation of pores, thereby producing micro-mesoporous calcium aluminate catalyst; wherein the weight ratio between the calcium oxide-based powder and the alumina-based powder is within a range of 12:(215), the added amount of the adhesion pore-enlarging agent accounts for 0.115% by weight of a total amount of the calcium oxide-based powder and alumina-based powder; wherein the weight of the calcium oxide-based powder is calculated based on calcium oxide, and the weight of the alumina-based powder is calculated based on alumina. The calcium aluminate catalyst prepared with the method provided by the present disclosure has advantages of large specific surface area, low density and high strength.

The present invention provides a process for in-situ preparation of metal oxide(s) comprising the step of precipitating a metal salt solution with Fehling's reagent B and glucose at a suitable temperature. The metal oxide(s) prepared according to the present invention can be used for diverse applications including their utility as catalyst(s) in one or more reactions. The present invention further provides a highly selective bi-functional hybrid catalyst for direct conversion of syn-gas to dimethyl ether (DME) and methods of preparation thereof. The one or more metal oxide(s) can be directly obtained from the metal precursors following the method(s) of the present invention instead of metal hydroxides as in conventional known methods, thereby eliminating the necessity of high temperature calcination step(s) and rigorous reduction procedure(s).

Described is a method for preparing a NOx storage-reduction catalyst article that includes a ruthenium composite as an active ingredient, and an exhaust treatment system including same. Proposed is a stable preparation method or an on-site simultaneous preparation method which is simplified as well as capable of preparing an NSR article exhibiting an equal level of activity, the method in which the NSR article is prepared by preliminarily preparing a heat-resistant ruthenium composition, mixing the same with de-NOxing components and applying same on a carrier.

The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.

The present disclosure relates to the technical field of fine chemical engineering, and particularly discloses a stepwise solidus synthesis method for a micro-mesoporous calcium aluminate catalyst, comprising: mixing a calcium oxide-based powder with an alumina-based powder and an adhesion pore-enlarging agent; pelleting and molding the mixture; pyrolyzing and coking the pelleted and molded product in a rotary kiln reactor under the conditions including an outlet reaction temperature of 300 C.500 C. and a residence time of 0.23.5 h; and subsequently carrying out a solidus reaction in an internal heating rotary kiln reactor under the conditions including an outlet reaction temperature of 900 C.1,500 C. and a residence time of 0.15 h to produce calcium aluminate; decomposing and gasifying the pyrolyzed char in the calcium aluminate to promote the formation of pores, thereby producing micro-mesoporous calcium aluminate catalyst; wherein the weight ratio between the calcium oxide-based powder and the alumina-based powder is within a range of 12:(215), the added amount of the adhesion pore-enlarging agent accounts for 0.115% by weight of a total amount of the calcium oxide-based powder and alumina-based powder; wherein the weight of the calcium oxide-based powder is calculated based on calcium oxide, and the weight of the alumina-based powder is calculated based on alumina. The calcium aluminate catalyst prepared with the method provided by the present disclosure has advantages of large specific surface area, low density and high strength.

A process is used for oligomerizing C2- to C8-olefins in several reaction stages in which the starting mixture and the respective outputs from the reaction stages are separated and are fed to different reaction stages.

In this fuel cell electrode catalyst layer, a catalyst is supported on a carrier comprising inorganic oxide particles. The fuel cell electrode catalyst layer is provided with a porous structure. When a mercury penetration method is used to measure the pore size distribution of the porous structure, a peak is observed in the range spanning from 0.005 m to 0.1 m inclusive, and a peak is also observed in the range spanning from over 0.1 m to not more than 1 m. When P1 represents the peak intensity in the range spanning from 0.005 m to 0.1 m inclusive, and P2 represents the peak intensity in the range spanning from over 0.1 m to not more than 1 m, the value of P2/P1 is 0.2-10 inclusive. It is preferable that the inorganic oxide be tin oxide.

A catalyst for producing unsaturated aldehyde and unsaturated carboxylic acid, wherein the cumulative pore volume (A) of pores having a pore diameter of 1 m or more and 100 m or less, in the catalyst, is 0.12 ml/g or more and 0.19 ml/g or less, and the ratio (A/B) of the cumulative pore volume (A) to the cumulative pore volume (B) of pores having a pore diameter of 1 m or more and 100 m or less, in a pulverized product not passing through a Tyler 6 mesh, in a pulverized product obtained by pulverization of the catalyst under a particular condition is 0.30 or more and 0.87 or less.

A method for producing an oligosilane including a reaction step of introducing a fluid containing a hydrosilane into a continuous reactor provided with a catalyst layer inside to produce an oligosilane from the hydrosilane and discharging a fluid containing the oligosilane from the reactor. The reaction step satisfies all of the following conditions (i) to (iii): (i) a temperature of the hydrosilane-containing fluid at an inlet of the catalyst layer is higher than a temperature of the oligosilane-containing fluid at an outlet of the catalyst layer; (ii) the temperature of the hydrosilane-containing fluid at the inlet of the catalyst layer is from 200 to 400 C.; and (iii) the temperature of the oligosilane-containing fluid at the outlet of the catalyst layer is from 50 to 300 C.