Patent classifications
B01J37/0201
Rare-earth metal vanadates catalysts for NO.SUB.x .reduction at low temperatures
Provided are catalysts for reduction of nitrogen oxides including an active site including lanthanum vanadate represented by at least one of Formula 1 and Formula 2 and a support carrying the active site.
LaVO.sub.4 (wherein LaVO.sub.4 is polymorphous and has a tetragonal or monoclinic crystal structure) Formula 1
LaV.sub.3O.sub.9 (wherein LaV.sub.3O.sub.9 has a monoclinic crystal structure) Formula 2.
Method for catalyst production for C5-C12 paraffins isomerization
Present invention relates to a process for production of isomerization catalyst, containing a base of zirconia, a binder based on alumina and/or silica at-least one component of Group VI of the periodic table in the form of their oxyanions, a hydrogenation/dehydrogenation component loaded on the base, at least one metal selected from the group consisting of Pt, Pd, Sn, Re or mixtures thereof, and an peptization agent, wherein the peptizing agent is an organic acid and polymers, which improve the physicochemical properties of the isomerization catalyst for the production of C4-C12 paraffin's.
Process and Materials for Trim Dewaxing of Distillates
Described herein are novel and inventive dewaxing processes that employ dewaxing catalysts which are co-extrusions of two different zeolites, particularly two different 10MR zeolites or a co-extrusion of a 10MR zeolite and a 12MR zeolite in combination with a hydrogenation component. The hydrogenation component can be a mixture of non-noble metal components or a mixture of noble metal components. This novel and inventive process demonstrated a significant activity boost (as measured by increased cloud point reduction) and/or selectivity boost (as measured by reduced diesel loss) compared to either single zeolite component.
HYDROGENATION CATALYST AND PREPARATION METHOD THEREFOR AND USE THEREOF
A catalyst has a carrier and a hydrogenation active metal component supported on the carrier. The hydrogenation active metal component contains at least one Group VIB metal component and at least one Group VIII metal component, and the carrier is composed of phosphorus-containing alumina. When the hydrogenation catalyst is measured using a hydrogen temperature programmed reduction method (H.sub.2-TPR), the ratio of the peak height of the low-temperature reduction peak, P.sub.low-temp peak, at a temperature of 300-500° C. to the peak height of the high-temperature reduction peak, P.sub.hi-temp peak, at a temperature of 650-850° C., i.e. S=P.sub.low-temp peak/P.sub.hi-temp peak, is 0.5-2.0; preferably 0.7-1.9, and more preferably 0.8-1.8. The hydrogenation catalyst shows excellent heteroatom removal effect and excellent stability when used in hydrotreatment.
AMMONIA SYNTHESIS CATALYST AND METHOD FOR MANUFACTURING AMMONIA
Provided is a catalyst that is free from catalyst deactivation caused by reaction of the support and exhibits good catalytic activity in an ammonia synthesis reaction in a low-temperature, low-pressure process. The present invention relates to an ammonia synthesis catalyst having a structure in which at least one of ruthenium or an oxide of ruthenium is loaded on a titanium suboxide support represented by the composition formula TiOx where x represents a number satisfying 1.5<x<2.0.
CATALYST STRUCTURE FOR SYNTHESIS GAS PRODUCTION, SYNTHESIS GAS PRODUCTION APPARATUS, AND METHOD FOR PRODUCING CATALYST STRUCTURE FOR SYNTHESIS GAS PRODUCTION
A catalyst structure for synthesis gas production of a synthesis gas that contains carbon monoxide and hydrogen, the catalyst structure being provided with a carrier that has a porous structure, while being configured from a zeolite type compound; first catalyst particles that contain one or more iron group elements which are selected from the group consisting of nickel (Ni), iron (Fe) and cobalt (Co); and second catalyst particles that contain one or more platinum group elements which are selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh) and ruthenium (Ru). The catalyst structure for synthesis gas production has passages in communication with each other within the carrier. The first catalyst particles are present at least in the passages of the carrier; and the second catalyst particles are present at least either inside the carrier or on the outer surface of the carrier.
Process for converting one or more methyl halides to acyclic C3-C6 olefins
The present disclosure relates to a process for converting one or more methyl halides to acyclic C3-C6 olefins, said process comprising the steps of (a) providing a feedstream comprising one or more methyl halides; (b) providing a catalyst composition; and (c) contacting said feedstream with said catalyst composition under reaction conditions. The process is remarkable in that said reaction conditions include a reaction temperature below 400° C., and in that said catalyst composition comprises one or more molecular sieves with a Si/Al atomic ratio ranging from 2 to 18 and wherein said one or more molecular sieves comprise a plurality of pores, wherein said pores have a shape of an 8-membered ring or less.
Vanadium oxide supported catalyst for alkane dehydrogenation
A catalyst for non-oxidative dehydrogenation of alkanes and a method for making and using the same is disclosed. The catalyst can include vanadium oxide derived from vanadyl oxalate. More particularly the catalyst is prepared by a method comprising the steps of: (a) contacting a transition alumina support with an aqueous solution comprising a vanadium carboxylate material solubilized therein; (b) heating the contacted alumina support to remove the water and produce a catalyst precursor material in solid form; and (c) heating the solid catalyst precursor material in the presence of an oxidizing source at a temperature of 500 to 800° C. to produce an alumina supported catalytic material comprising vanadium oxide. The catalyst can be further modified with an alkali metal oxide like potassium oxide, the precursor thereof being introduced with the impregnation solution.
CATALYST-CONTAINING MATERIAL
A catalyst-containing material includes a refractory matrix and particles of one or more catalytic metal elements or catalytic oxides. The particles are dispersed through, and embedded in, the refractory matrix.
LOW TEMPERATURE NOX ADSORBER WITH ENHANCED REGENERATION EFFICIENCY
The present disclosure provides Low Temperature NO.sub.x-Absorber (LT-NA) catalyst compositions, catalyst articles, and an emission treatment system for treating an exhaust gas, each including the LT-NA catalyst compositions. Further provided are methods for reducing a NO.sub.x level in an exhaust gas stream using the LT-NA catalyst articles. In particular, the LT-NA catalyst compositions include a first zeolite, a first palladium component, and a plurality of platinum nanoparticles. The LT-NA catalyst compositions exhibit enhanced regeneration efficiency with respect to NO.sub.x adsorption capacity, even after hydrothermal aging.