Patent classifications
B01J37/03
Catalyst for exhaust gas oxidation, method for producing same, and exhaust gas oxidation method using same
Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.
Cu.SUB.y./MMgO.SUB.x .interfacial catalyst for selective alkyne hydrogenation and its preparation method
Cu.sub.y/MMgO.sub.x interfacial catalyst for selective alkyne hydrogenation and its preparation method are disclosed. The preparation method of the catalyst includes: the mixture of salt and alkali solution is nucleated momentarily by nucleation/crystallization isolation method, preparing the composite metal hydroxide Cu.sub.yMMg.sub.4-LDHs as precursor, which has typical hexagonal morphology of the double hydroxide; the precursor is topologically transformed by heat treatment to produce unsaturated oxide; the catalyst with Cu.sub.y-MMgO.sub.x interface structure is prepared by separating and electronically modifying Cu particles. By adjusting the ratio of Cu.sup.2+/M.sup.3+ in LDHs, the electronic and geometric structure of Cu.sub.y-MMgO.sub.x interface can be flexibly controlled, thus enhancing the reaction activity, product selectivity and stability. The catalyst can be used in the selective hydrogenation of various alkynes in the fields of petrochemical and fine chemical industry, with the outstanding catalytic activity and C═C double bond selectivity. The catalyst also has good reusability.
Method for preparing ZSM-5 zeolite
The present invention relates to a method for preparing ZSM-5 zeolite. The present invention can provide a method for preparing ZSM-5 zeolite comprising the steps of: preparing a first solution in a solution state by heating a mixture comprising a silica source, an alumina source, a neutralizing agent and a crystalline ZSM-5 nucleus; preparing a reaction mother liquid by mixing a second solution comprising salts into the first solution; and continuously crystallizing by continuously supplying the reaction mother liquid to a hydrothermal synthesis reactor, wherein formula [1] below is satisfied.
0.20≤W.sub.a/W.sub.b≤0.40 Formula [1]
Mixed oxide catalyst for oxygen storage applications and a method for making the catalyst
Catalyst material composed of a sodium incorporated cerium-zirconium based mixed oxide catalyst material, such as Ce—Zr/Al.sub.2O.sub.3, for oxygen storage capacity applications. The sodium incorporated cerium-zirconium based mixed oxide catalyst material is synthesized by co-precipitation techniques using sodium carbonate as the precipitating agent and exhibits a high oxygen storage capacity.
METHOD FOR PREPARING A CATALYST SUPPORT
A process for preparing a powder support containing alumina and silica or their derivatives for a catalyst of a Fischer-Tropsch type reaction, including stage (a) of preparing a first reactant containing an alumina compound or precursor including a reaction for peptization of an alumina compound or precursor in the presence of an acid, to form solid particles in suspension, stage (b) of preparing a second reactant based on silicic acid and/or on a compound or precursor of silicic acid, including a controlled aging treatment of the silicic acid targeted at its polymerization up to a degree of conversion of the silicic acid of at most 70%, stage (c) of mixing the two reactants in a mixer, and the pH of the first reactant is adjusted to a value not exceeding a given maximum pH threshold.
ALUMINA WITH A PARTICULAR PORE PROFILE
The present invention relates to an alumina with a particular pore profile and good thermal stability. This alumina is also characterized in that it has a high bulk density. The alumina has, after calcining in air at 1100° C. for 5 hours: a pore volume in the range of pores with a size of between 5 nm and 100 nm which is between 0.50 and 0.75 mL/g, more particularly between 0.50 and 0.70 mL/g; and a pore volume in the range of pores with a size of between 100 nm and 1000 nm which is less than or equal to 0.20 mL/g, more particularly less than or equal to 0.15 mL/g, or even less than or equal to 0.10 mL/g.
ALUMINA WITH A PARTICULAR PORE PROFILE
The present invention relates to an alumina with a particular pore profile and good thermal stability. This alumina is also characterized in that it has a high bulk density. The alumina has, after calcining in air at 1100° C. for 5 hours: a pore volume in the range of pores with a size of between 5 nm and 100 nm which is between 0.50 and 0.75 mL/g, more particularly between 0.50 and 0.70 mL/g; and a pore volume in the range of pores with a size of between 100 nm and 1000 nm which is less than or equal to 0.20 mL/g, more particularly less than or equal to 0.15 mL/g, or even less than or equal to 0.10 mL/g.
ALUMINA WITH A PARTICULAR PORE PROFILE
The present invention relates to an alumina with a particular pore profile and good thermal stability. This alumina is also characterized in that it has a high bulk density. The alumina has, after calcining in air at 1100° C. for 5 hours: a pore volume in the range of pores with a size of between 5 nm and 100 nm which is between 0.50 and 0.75 mL/g, more particularly between 0.50 and 0.70 mL/g; and a pore volume in the range of pores with a size of between 100 nm and 1000 nm which is less than or equal to 0.20 mL/g, more particularly less than or equal to 0.15 mL/g, or even less than or equal to 0.10 mL/g.
PROCESS OF OBTAINING A CATALYST, CATALYST AND PRE-TREATMENT PROCESS OF ACIDIC CHARGES
The present invention concerns a catalyst and pre-treatment process for acidic charges consisting of sulfated zirconia and cerium for the production of biofuels, characterized in that the catalyst has greater activity and resistance to deactivation with acidic charges.
PROCESS OF OBTAINING A CATALYST, CATALYST AND PRE-TREATMENT PROCESS OF ACIDIC CHARGES
The present invention concerns a catalyst and pre-treatment process for acidic charges consisting of sulfated zirconia and cerium for the production of biofuels, characterized in that the catalyst has greater activity and resistance to deactivation with acidic charges.