B01J37/082

CHEMICAL HOMOGENEITY AND CATALYTIC PERFORMANCE OF MIXED-METAL OXIDE CATALYSTS
20230211319 · 2023-07-06 ·

A method for preparing a mixed-metal oxide catalyst comprising molybdenum, vanadium, at least one of niobium or tantalum, and at least one of tellurium or antimony and useful for the oxidative dehydrogenation of ethane to ethylene, the method comprising preparing a catalyst precursor, pressing the precursor into a dense pellet using a pressure of greater than about 5,000 psi, and annealing the pellet to form the mixed-metal oxide catalyst.

Catalyst comprising a mixture of an AFX-structure zeolite and a BEA-structure zeolite and at least one transition metal for selective reduction of NOx

The invention relates to a catalyst comprising a mixture of AFX-structure and BEA-structure zeolites and at least one additional transition metal, to the process for preparing same and to the use thereof for the selective catalytic reduction of NOx in the presence of a reducing agent such as NH.sub.3 or H.sub.2.

Selective catalytic reduction catalyst on a filter substrate

A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.

CATALYST FOR CARBONYLATION OF DIMETHYL ETHER AND METHOD FOR PREPARING THE SAME

Disclosed are a catalyst for carbonylation of dimethyl ether that has high catalyst activity and can be regenerated using a fluidized bed reactor, and a method for preparing the same. The catalyst for carbonylation of dimethyl ether includes a support having a first density; and ferrierite zeolite catalyst particles bound to a surface of the support via a polymer binder and having a second density smaller than the first density.

Lignite char supported nano-cobalt composite catalyst and preparation method thereof

The present disclosure provides a lignite char supported nano-cobalt composite catalyst and a preparation method thereof. In the method, lignite is used as a raw material, and a lignite char supported high dispersion nano-cobalt composite catalyst is obtained by a modified impregnation method followed by a high temperature pyrolysis process. The composite catalyst prepared by the present disclosure has a hierarchical pore structure, a high specific surface area, and uniformly dispersing nano-sized cobalts on the lignite char with controllable particle size, so that the obtained catalyst has an excellent catalytic activity for low-temperature CO.sub.2 methanation; moreover, the preparation process is simple and feasible, the raw materials used are cheap and easily available. Therefore, the composite catalyst is very suitable for industrial production and application.

Heteroatom-Doped Zeolites For Bifunctional Catalytic Applications

Provided herein are methods for hydroisomerization of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with hydrogen and a catalyst to yield a hydrocarbon product having an increase in branched hydrocarbons relative to the hydrocarbon feedstock. The present catalysts comprise a heteroatom-doped Beta zeolite having a trivalent cation as a framework metal oxide, an extra-framework species comprised of cerium and/or cobalt, and from 0.01 to 1.5 wt. % of a group VIII or VIB metal, or a combination thereof.

Process for the production of a zeolitic material via interzeolitic conversion

The present invention relates to a process for the preparation of a zeolitic material SiO.sub.2 and X.sub.2O.sub.3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO.sub.2 and X.sub.2O.sub.3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or MFI-type framework structure to a second zeolitic material comprising SiO.sub.2 and X.sub.2O.sub.3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.

HYDROGENATED TIO2 DENITRATION CATALYST, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
20220387978 · 2022-12-08 ·

The present invention relates to the technical field of flue gas denitration catalysts, and discloses a hydrogenated TiO.sub.2 denitration catalyst and a preparation method and use thereof. The hydrogenated TiO.sub.2 denitration catalyst has a crystal form of anatase form, with oxygen vacancies and surface hydroxyl groups; wherein the hydrogenated TiO.sub.2 denitration catalyst contains TiO.sub.2, SO.sub.3 and P.sub.2O.sub.5, and based on the total weight of the hydrogenated TiO.sub.2 denitration catalyst, the content of TiO.sub.2 is 98-99.8% by weight, the content of SO.sub.3 is 0.2-1% by weight, and the content of P.sub.2O.sub.5 is 0.1-0.2% by weight. The hydrogenated TiO.sub.2 denitration catalyst has high denitration activity at 300-400° C. and N.sub.2 selectivity as high as 85% or more, and can be used in NH.sub.3—SCR denitration.

Heteroatom-doped zeolites for bifunctional catalytic applications

Provided herein are methods for hydroisomerization of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with hydrogen and a catalyst to yield a hydrocarbon product having an increase in branched hydrocarbons relative to the hydrocarbon feedstock. The present catalysts comprise a heteroatom-doped Beta zeolite having a trivalent cation as a framework metal oxide, an extra-framework species comprised of cerium and/or cobalt, and from 0.01 to 1.5 wt. % of a group VIII or VIB metal, or a combination thereof.

PROCESS FOR MAKING BIOBASED PRODUCTS FROM SUGARS
20220363628 · 2022-11-17 · ·

An integrated, co-product capable process is provided for producing taurine in particular with optionally one or both of monoethanolamine and diethanolamine from one or more sugars, comprising pyrolyzing one or more sugars to produce a crude pyrolysis product mixture including glycolaldehyde and formaldehyde; optionally removing formaldehyde from the crude pyrolysis product mixture, then combining the crude pyrolysis product mixture with an aminating agent in the presence of hydrogen and further in the presence of a catalyst to produce at least monoethanolamine from the crude pyrolysis product mixture; optionally recovering diethanolamine from the crude reductive amination product, sulfating at least a portion to all of the monoethanolamine product to produce 2-aminoethyl hydrogen sulfate ester; and sulfonating the 2-aminoethyl hydrogen sulfate ester to produce taurine.