A ceramic honeycomb structure comprising large numbers of cells partitioned by porous cell walls, the cell walls having (a) porosity of 50-80%, and when measured by mercury porosimetry, (b) a median pore diameter being 25-50 μm, (c) (i) a cumulative pore volume in a pore diameter range of 20 μm or less being 25% or less of the total pore volume, (ii) a cumulative pore volume in a pore diameter range of more than 20 μm and 50 μm or less being 50% or more of the total pore volume, and (iii) a cumulative pore volume in a pore diameter range of more than 50 μm being 12% or more of the total pore volume.

Provided herein is an alkane dehydrogenation catalyst, a method of manufacturing an alkane dehydrogenation catalyst, and a method of converting alkanes to alkenes.

A process for producing an unsupported molybdenum sulfide nanocatalyst comprising atomizing a molybdenum oxide solution to form a molybdenum oxide aerosol, pyrolyzing the molybdenum oxide aerosol with a laser beam to form the unsupported molybdenum-based nanocatalyst, and pre-sulfiding at least a portion of the unsupported molybdenum-based nanocatalyst to form an unsupported molybdenum sulfide nanocatalyst, wherein the unsupported molybdenum-based nanocatalyst, the unsupported molybdenum sulfide catalyst or both are in the form of nanoparticles with a diameter of 1-10 nm and in a distorted rutile crystalline structure. A method of selective deep hydrodesulfurization whereby a hydrocarbon feedstock having at least one sulfur-containing component and at least one hydrocarbon is contacted with the unsupported molybdenum sulfide nanocatalyst.

The present disclosure provides a synthesis method of a g-C.sub.3N.sub.4/C composite material based on a hollyhock stalk, including the following steps: (1) pretreatment of hollyhock stalks; and (2) fabrication of the g-C.sub.3N.sub.4/C composite material. In this method, with the hollyhock stalk as a carbon skeleton, g-C.sub.3N.sub.4 is spread on a template surface to form a laminated layer, and a composite system with a special structure is constructed. Compared with pure phase g-C.sub.3N.sub.4, the composite material substantially increases specific surface area and has a clear interface; the carbon skeleton not only functions as a rigid support, but also increases the electron transfer efficiency of the composite material, thereby improving the separation efficiency of photogenerated carriers and the utilization rate of visible light. Raw materials used in the method are inexpensive and environmentally friendly, which can be used for industrial production and bulk production of eco-friendly materials for harnessing environmental organic pollutants.

A catalyst composition comprising MgO, Al.sub.2O.sub.3 and one or more further alkaline earth metal oxides, provides for outstanding catalytic production of propylene when employed together with a metathesis catalyst.

A nitrous oxide (N.sub.2O) removal catalyst composite is provided, comprising a N.sub.2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H.sub.2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H.sub.2-TPR). Methods of making and using the same are also provided.

An ammonia synthesis catalyst having high activity is obtained by having a two-dimensional electride compound having a lamellar crystal structure such as Ca.sub.2N support a transition metal. However, since the two-dimensional electride compound is unstable, the stability of the catalyst is low. In addition, in cases where a two-dimensional electride compound is used as a catalyst support, it is difficult to shape the catalyst depending on reactions since the two-dimensional electride compound has poor processability. A composite which includes a transition metal, a support and a metal amide compound, wherein the support is a metal oxide or a carbonaceous support; and the metal amide compound is a metal amide compound represented by general formula (1). M(NH.sub.2).sub.x . . . (1) (In general formula (1), M represents at least one metal atom selected from the group consisting of Li, Na, K, Be, Mg, Ca, Sr, Ba and Eu; and x represents the valence of M.)

In a method of manufacturing open-cell bodies, individual parts of an open pore plastic in a size which corresponds to the size of the bodies to be manufactured while taking account of the shrinkage on a sintering or an open pore plastic element having predetermined break points which take account of the size and geometrical design of bodies to be manufactured are/is in filtrated and coated with a suspension in which at least one powdery material is contained. Organic components are expelled after a first heat treatment. Subsequently, a sintering is carried out. Parts of porous plastic provided with the suspension are separated before the first heat treatment or wherein, afterwards the open-cell element which is obtained from the plastic element from the material with which the bodies are formed is cut by forces and thereby separated bodies can be obtained.

The present invention relates to a process for the preparation of catalyst(s), comprising the cokneading of boehmite with an active phase comprising a salt of heteropolyanion of Keggin and/or lacunary Keggin and/or substituted lacunary Keggin and/or Anderson and/or Strandberg type, and their mixtures, exhibiting, in its structure, molybdenum and cobalt and/or nickel. The present invention also relates to a process for the hydrotreating and/or hydroconversion of a heavy hydrocarbon feedstock in the presence of catalyst(s) prepared according to said process.

Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650° C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.