Patent classifications
B01J38/42
Gas-phase catalytic fluorination with chromium catalysts
A process for the fluorination of a chlorinated C3 alkane or alkene compound having at least one chlorine atom into a fluorinated C3 alkane or alkene compound having at least one fluorine atom includes the following steps: a) contacting, in a reactor, the chlorinated compound with hydrogen fluoride in gas phase in the presence of a fluorination catalyst to produce a fluorinated compound, and b) regenerating the fluorination catalyst used in step a). The step (b) of regenerating the fluorination catalyst comprises (c) the treatment of said fluorination catalyst with an oxidizing agent-containing gas flow to form an oxidized fluorination catalyst, and (d) the treatment of the oxidized fluorination catalyst obtained in step (c) with a gaseous mixture comprising a reducing agent and an inert gas. The catalyst regenerated in step b) is reused in step a) and the reducing agent is selected from C.sub.1-C.sub.10 hydrohalocarbons.
Gas-phase catalytic fluorination with chromium catalysts
The present invention relates to a method for fluorinating a chlorinated compound including the steps of (a) placing said chlorinated compound in contact with gaseous hydrogen fluoride within a reactor and in the presence of a fluorination catalyst to produce a fluorinated compound, and (b) regenerating the fluorination catalyst used in step a), the step of regenerating the fluorination catalyst including (c) treating said fluorination catalyst with an oxidizing agent to form an oxidized fluorination catalyst, and (d) treating the oxidized fluorination catalyst obtained in step (c) with a gas mixture including a reducing agent.
Gas-phase catalytic fluorination with chromium catalysts
The present invention relates to a method for fluorinating a chlorinated compound including the steps of (a) placing said chlorinated compound in contact with gaseous hydrogen fluoride within a reactor and in the presence of a fluorination catalyst to produce a fluorinated compound, and (b) regenerating the fluorination catalyst used in step a), the step of regenerating the fluorination catalyst including (c) treating said fluorination catalyst with an oxidizing agent to form an oxidized fluorination catalyst, and (d) treating the oxidized fluorination catalyst obtained in step (c) with a gas mixture including a reducing agent.
Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.
Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.
USE OF A CONTINUOUS CATALYST REGENERATION TYPE REFORMER FOR THE AROMAX® CATALYST PROCESS
The present disclosure relates to the aromatization of hydrocarbons with an aromatization catalyst, including methods of aromatization comprising the use of a continuous catalyst regeneration type reformer.
REGENERATION TOWER FOR CONTINUOUS CATALYTIC REFORMING PROCESS
The regeneration tower with a cylindrical section and a conical section has a tertiary screen covering an opening in the conical section which prevents any catalyst that escapes from the cylindrical catalyst bed or the catalyst bed in the conical section from entering the oxygen-rich chlorination zone. The regeneration tower may also have one or more additional changes. The length of the cylindrical section can be increased. The inner screen in the cylindrical section may comprise punch plate or slotted plate. A secondary screen can be added in front of the inner screen in the cylindrical section.
REGENERATION TOWER FOR CONTINUOUS CATALYTIC REFORMING PROCESS
The regeneration tower with a cylindrical section and a conical section has a tertiary screen covering an opening in the conical section which prevents any catalyst that escapes from the cylindrical catalyst bed or the catalyst bed in the conical section from entering the oxygen-rich chlorination zone. The regeneration tower may also have one or more additional changes. The length of the cylindrical section can be increased. The inner screen in the cylindrical section may comprise punch plate or slotted plate. A secondary screen can be added in front of the inner screen in the cylindrical section.
Aromatization processes using both fresh and regenerated catalysts, and related multi-reactor systems
Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.
Aromatization processes using both fresh and regenerated catalysts, and related multi-reactor systems
Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.