Patent classifications
B01J38/64
Method for storage and release of hydrogen
The invention provides a process for the production of hydrogen, comprising catalytically decomposing a concentrated aqueous solution of potassium formate in a reaction vessel to form bicarbonate slurry and hydrogen, discharging the hydrogen from said reaction vessel, and treating a mixture comprising the bicarbonate slurry and the catalyst with an oxidizer, thereby regenerating the catalyst. Pd/C catalysts useful in the process are also described.
Method for storage and release of hydrogen
The invention provides a process for the production of hydrogen, comprising catalytically decomposing a concentrated aqueous solution of potassium formate in a reaction vessel to form bicarbonate slurry and hydrogen, discharging the hydrogen from said reaction vessel, and treating a mixture comprising the bicarbonate slurry and the catalyst with an oxidizer, thereby regenerating the catalyst. Pd/C catalysts useful in the process are also described.
Methods for regenerating sulfur-contaminated aromatization catalysts
Methods for regenerating a sulfur-contaminated catalyst are disclosed. Such methods may employ a step of washing the sulfur-contaminated catalyst with an aqueous solution containing an alkali metal, followed by contacting the washed catalyst with a halogen solution containing chlorine and fluorine.
Methods for regenerating sulfur-contaminated aromatization catalysts
Methods for regenerating a sulfur-contaminated catalyst are disclosed. Such methods may employ a step of washing the sulfur-contaminated catalyst with an aqueous solution containing an alkali metal, followed by contacting the washed catalyst with a halogen solution containing chlorine and fluorine.
COMBUSTION SYSTEM
A combustion system operated at low cost is provided. A combustion system 1 includes a combustion device 10 that burns fuel, an exhaust line L1 through which exhaust gas flows, the exhaust gas being generated through combustion of the fuel in the combustion device 10, an air preheater 30 that is disposed in the exhaust line L1 and that recovers heat from the exhaust gas, and a denitration device 40 that is disposed in the exhaust line L1 and that removes nitrogen oxide from the exhaust gas using a denitration catalyst. The denitration device 40 is disposed downstream from the air preheater 30 in the exhaust line L1, and the denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more.
DENITRATION CATALYST AND METHOD FOR PRODUCING THE SAME
There is provided a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A denitration catalyst molded in a block shape contains 43 wt % or more of vanadium pentoxide. The denitration catalyst has a BET specific surface area of 30 m.sup.2/g or more and is used for denitration at 200? C. or lower.
METHOD FOR RECYCLING DENITRATION CATALYST
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of removing a used denitration catalyst from a denitration device and then coating the used denitration catalyst with a catalyst component. The catalyst component contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more, and the denitration catalyst after recycling is used for denitration at 200? C. or lower.
METHOD FOR RECYCLING DENITRATION CATALYST
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of spraying an aqueous solution with a pH of 7 or more onto a used denitration catalyst while the denitration catalyst is set in a denitration device to remove a surface of the denitration catalyst. The denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more. The denitration catalyst after recycling is used for denitration at 200? C. or lower.
METHOD FOR RECYCLING DENITRATION CATALYST
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of spraying an aqueous solution with a pH of 7 or more onto a used denitration catalyst while the denitration catalyst is set in a denitration device to remove a surface of the denitration catalyst. The denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more. The denitration catalyst after recycling is used for denitration at 200? C. or lower.
IONIC LIQUID CATALYST TREATING SYSTEM
A process removing ionic liquid from a process stream is described. The process stream is introduced into a coalescer to form an ionic liquid stream and a first treated process stream which has less ionic liquid than the process stream. The first treated process stream is introduced into a separator to form a second treated process stream. The second treated process stream has less ionic liquid than the first treated process stream. The separator is selected from a filtration zone comprising sand or carbon, an adsorption zone, a scrubbing zone, an electrostatic separation zone, or combinations thereof.