B01J41/07

Alkaline anion exchange membranes derived from diphenylethylene and co-monomer feedstock

The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the α-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.

Alkaline anion exchange membranes derived from diphenylethylene and co-monomer feedstock

The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the α-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.

Longitudinal gradient chromatography columns
11198117 · 2021-12-14 · ·

An ion exchange chromatography column contains an ion exchange stationary phase that includes a charged substrate, a plurality of first particles, and a plurality of second particles. The plurality of first particles each include first ion exchange groups and the first particles are ionically bound to the charged substrate. The plurality of second particles each include second ion exchange groups and the second particles are ionically bound to the charged substrate. The first particles having a first ion exchange group density, and the second particles having a second ion exchange group density. The first ion exchange group density is greater than the second ion exchange group density. The ion exchange chromatography column has a number of zones connected in series where each zone can have a varying level of first ion exchange groups and second ion exchange group from the inlet zone to the outlet zone.

Longitudinal gradient chromatography columns
11198117 · 2021-12-14 · ·

An ion exchange chromatography column contains an ion exchange stationary phase that includes a charged substrate, a plurality of first particles, and a plurality of second particles. The plurality of first particles each include first ion exchange groups and the first particles are ionically bound to the charged substrate. The plurality of second particles each include second ion exchange groups and the second particles are ionically bound to the charged substrate. The first particles having a first ion exchange group density, and the second particles having a second ion exchange group density. The first ion exchange group density is greater than the second ion exchange group density. The ion exchange chromatography column has a number of zones connected in series where each zone can have a varying level of first ion exchange groups and second ion exchange group from the inlet zone to the outlet zone.

Longitudinal gradient chromatography columns
11198117 · 2021-12-14 · ·

An ion exchange chromatography column contains an ion exchange stationary phase that includes a charged substrate, a plurality of first particles, and a plurality of second particles. The plurality of first particles each include first ion exchange groups and the first particles are ionically bound to the charged substrate. The plurality of second particles each include second ion exchange groups and the second particles are ionically bound to the charged substrate. The first particles having a first ion exchange group density, and the second particles having a second ion exchange group density. The first ion exchange group density is greater than the second ion exchange group density. The ion exchange chromatography column has a number of zones connected in series where each zone can have a varying level of first ion exchange groups and second ion exchange group from the inlet zone to the outlet zone.

APPARATUS FOR PRODUCING NON-AQUEOUS ELECTROLYTIC SOLUTION AND METHOD FOR PRODUCING NON-AQUEOUS ELECTROLYTIC SOLUTION
20210384557 · 2021-12-09 · ·

Provided is an apparatus for producing a non-aqueous electrolytic solution capable of easily performing purification treatment by removal of acidic impurities such as hydrogen fluoride contained in a non-aqueous electrolytic solution.

The apparatus for producing a non-aqueous electrolytic solution comprises an ion exchange unit accommodating a weakly basic anion exchange resin through which an alkali metal salt electrolyte-containing solution having the alkali metal salt electrolyte dispersed in an carbonate ester is passed to obtain the non-aqueous electrolytic solution, wherein the weakly basic anion exchange resin has a styrene-based resin as substrate and an amino group as weakly basic anion exchange group.

APPARATUS FOR PRODUCING NON-AQUEOUS ELECTROLYTIC SOLUTION AND METHOD FOR PRODUCING NON-AQUEOUS ELECTROLYTIC SOLUTION
20210384557 · 2021-12-09 · ·

Provided is an apparatus for producing a non-aqueous electrolytic solution capable of easily performing purification treatment by removal of acidic impurities such as hydrogen fluoride contained in a non-aqueous electrolytic solution.

The apparatus for producing a non-aqueous electrolytic solution comprises an ion exchange unit accommodating a weakly basic anion exchange resin through which an alkali metal salt electrolyte-containing solution having the alkali metal salt electrolyte dispersed in an carbonate ester is passed to obtain the non-aqueous electrolytic solution, wherein the weakly basic anion exchange resin has a styrene-based resin as substrate and an amino group as weakly basic anion exchange group.

FILTER MEDIA COMPRISING ADSORPTIVE PARTICLES

Filter media comprising adsorptive particles are generally described. In some embodiments, the adsorptive particles are present in a relatively large amount, in a layer discrete from one or more other layers and/or fiber webs also present in the filter media, and/or in a layer that comprises a relatively low amount of fibers. In some embodiments, the filter media further comprises a non-woven fiber web comprising fibers with relatively small diameters.

METHODS FOR REMOVING IODATE FROM AQUEOUS SOLUTIONS
20220199274 · 2022-06-23 ·

Methods and materials are described for the removal of iodate from aqueous solutions. The methods comprise reduction of the iodate to iodide and subsequent or concurrent removal of the iodide by sorption, ion exchange, or precipitation. These methods are effective for the removal of radioactive iodine from radioactive and nuclear wastes.

METHODS FOR REMOVING IODATE FROM AQUEOUS SOLUTIONS
20220199274 · 2022-06-23 ·

Methods and materials are described for the removal of iodate from aqueous solutions. The methods comprise reduction of the iodate to iodide and subsequent or concurrent removal of the iodide by sorption, ion exchange, or precipitation. These methods are effective for the removal of radioactive iodine from radioactive and nuclear wastes.