Patent classifications
B01J49/06
METHOD AND DEVICE OF REMOVING AND RECYCLING METALS FROM MIXING ACID SOLUTION
A method and device of removing and recycling metals from a mixing acid solution, includes adsorbing a mixing acid solution with a pH value of −1 to 4 and a cobalt ion concentration of 100 to 1,000 mg/L by at least two cation resins in series setting to the cobalt ion concentration in the mixing acid solution is less than 10 mg/L, and then adjusting the pH value of the mixing acid solution after adsorption to meet a discharge standard, wherein the particle size of the at least two cation resins in series setting is 150˜1,200 μm. After the cation resins are saturated by adsorption, regenerating the cation resins by sulfuric acid to form a cobalt sulfate solution, and then electrolytically treating the cobalt sulfate solution to obtain electrolytic cobalt and sulfuric acid electrolyte. The operation process is simple without complicated equipment, and it can effectively recycle metals from mixing acid solutions. The cationic resin and sulfuric acid solution can also be reused, so the method of the present invention has environmental and economic benefits.
Ion-exchange resin regeneration system
An ion-exchange resin regeneration system includes: salt water flowing means that flows an aqueous sodium chloride solution or an aqueous potassium chloride solution into a container storing ion-exchange resin; and hard water component crystallizing means that crystallizes and removes hard water components containing metal ions from drained water arising from the ion-exchange resin through which the aqueous sodium chloride solution or the aqueous potassium chloride solution has flowed.
Composite Extractant-Enhanced Polymer Resin, Method of Making the Same, and Its Usage for Extraction of Valuable Metal(s)
A composite extractant-enhanced polymer resist comprising an extractant and a polymer resin for direct extraction of valuable metals such as rare earth metals, and more specifically, scandium, Born an acid-leaching slurry and/or acid-leaching solution in which ferric ions are not required to be reduced into ferrous ions. The extractant may be cationic, non-ionic, or anionic. More specifically, the extractant di(2-ethylhexyl)phosphoric acid may be used. The polymer resin may be non-functional or have functional groups of sulfonic acid, carboxylic acid, iminodiacetic acid, phosphoric acid, or amines. The composite extractant-enhanced polymer resin may be used for extraction of rare earth metals from acid-leaching slurries or solutions.
Composite Extractant-Enhanced Polymer Resin, Method of Making the Same, and Its Usage for Extraction of Valuable Metal(s)
A composite extractant-enhanced polymer resist comprising an extractant and a polymer resin for direct extraction of valuable metals such as rare earth metals, and more specifically, scandium, Born an acid-leaching slurry and/or acid-leaching solution in which ferric ions are not required to be reduced into ferrous ions. The extractant may be cationic, non-ionic, or anionic. More specifically, the extractant di(2-ethylhexyl)phosphoric acid may be used. The polymer resin may be non-functional or have functional groups of sulfonic acid, carboxylic acid, iminodiacetic acid, phosphoric acid, or amines. The composite extractant-enhanced polymer resin may be used for extraction of rare earth metals from acid-leaching slurries or solutions.
DEVICES FOR EFFICIENT SORBENT UTILIZATION IN LITHIUM EXTRACTION
The present disclosure relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.
DEVICES FOR EFFICIENT SORBENT UTILIZATION IN LITHIUM EXTRACTION
The present disclosure relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.
System and method for restoring kinetic properties of resin
A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.
AUTOMATIC RECHARGER BRINE PREPARATION FROM A SALT BAG
The disclosure relates to systems and methods for generating a brine solution using a salt bag for recharging zirconium phosphate in a reusable sorbent module. The salt bag can be a double layer bag. An inner water permeable bag can contain solid salts and can be surrounded by an outer water impermeable bag. Water can be added to dissolve the salts in the inner bag and the resulting solution can be collected as a brine solution for use in recharging the zirconium phosphate.
Water softener apparatus
A water softener apparatus comprises two water softener tanks one of which is always operating, valves controlling the flow of water and a flow-meter, wherein, after a set volume of water has passed through one tank, water is passed through the other tank. The apparatus uses ion-exchange tanks which may be regenerated by brine when not softening hard water. The flow-meter preferably comprises an actuator which moves in a cyclic movement in response to the flow of a set quantity of water and actuates two service valves which send pressured water signals to a drain shuttle valve. The drain shuttle valve then diverts hard water from one tank to another and initiates regeneration of the first tank. A regeneration meter terminates the alternate regeneration of the two tanks. The regeneration meter is positioned in the apparatus of a point where brine for regeneration of the two water softener components is received into the apparatus.
Systems and methods for onsite sorbent material reuse
Methods, sorbent cartridges and cleaning devices are disclosed for refurbishing sorbent materials. In one implementation among multiple implementations, a medical fluid delivery method includes: providing a sorbent cartridge including H.sup.+ZP within a casing for a treatment; and after the treatment, refurbishing the H.sup.+ZP while maintained within the casing via (i) regenerating the non-disinfected H.sup.+ZP by flowing an acid solution through the casing, (ii) rinsing the regenerated H.sup.+ZP while maintained within the casing, (iii) disinfecting the regenerated and rinsed H.sup.+ZP by flowing a disinfecting agent through the casing, and (iv) rinsing the regenerated and disinfected H.sup.+ZP while maintained within the casing. Multiple batch sorbent refurbishing implementations are also disclosed.