Patent classifications
B01J49/53
Lithium extraction in the presence of scalants
The present invention relates to recovery of lithium from liquid resources to produce lithium solutions while limiting impurity precipitation in the lithium solutions.
Lithium extraction in the presence of scalants
The present invention relates to recovery of lithium from liquid resources to produce lithium solutions while limiting impurity precipitation in the lithium solutions.
SYSTEM AND METHOD FOR REGENERATING AND RESTORING KINETIC PROPERTIES OF RESIN
A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.
SYSTEM AND METHOD FOR REGENERATING AND RESTORING KINETIC PROPERTIES OF RESIN
A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.
Extraction and recovery of Pd from aqueous solutions
Extraction of platinum-group elements, e.g. Pd, by adsorption from acidic aqueous solutions, using chelating acrylic fibers having amidoxime substituents followed by recovery by elution with an HCl-thiourea solution. From about 10% to 100% of the acrylic fiber CN are converted to amidoxime by reaction with NH.sub.2OH (hydroxylamine) in H.sub.2O/MeOH solution in the range of 30° C.-90° C. for from 15 min to 72 hrs. The adsorptive loading of elements onto the fiber and the efficiency of elution therefrom is substantially 100%, in multiple cycles of adsorption/elution. The novel fiber/extraction process is rapid, lending it to a continuous recovery operation. A portion of the CN groups of may be converted to carboxylate groups by reaction with NaOH. Short lengths of fiber are loaded into a vertical column and the pregnant solution introduced. Upon breakthrough, the fibers may be eluted, washed and recycled hundreds of times without removal from the column.
METHOD FOR PRODUCING LITHIUM-CONTAINING SOLUTION
Provided is a method for producing a lithium-containing solution that prevents the dissolution of the whole lithium manganese oxide while maintaining the efficiency of an elution step. The method for producing a lithium-containing solution comprises performing an adsorption step of contacting a lithium adsorbent obtained from lithium manganese oxide with a low lithium-containing liquid for adsorption to give post-adsorption lithium manganese oxide, an elution step of contacting the post-adsorption lithium manganese oxide with an acid solution to give a lithium-containing solution with residual manganese, and a manganese oxidation step of oxidating manganese to give a lithium-containing solution with a suppressed manganese concentration, performed in this order. The acid solution is a 0.5 mol/L or more and 4.0 mol/L or less hydrochloric acid solution. According to the production method, in the elution step, the dissolution of the whole lithium manganese oxide can be suppressed while maintaining the efficiency of exchange reaction between cations including Li.sup.+ and H.sup.+. Thus, the repeated use of the lithium adsorbent becomes possible.
RESIN FOR DESALINATION AND PROCESS OF REGENERATION
Disclosed is an ion exchange resin comprising a polymer having strong acid and strong base groups on the same polymer. In some forms the resin comprises a high density of polymers having strong acid and strong base groups on the same polymer. In some forms the strong acid and strong base groups are in close proximity to one another on the polymer. The disclosure further relates to a mixed bead resin for high salt level desalination.
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METHODS FOR CHROMATOGRAPHIC PROTEIN EXTRACTION AND PURIFICATION
Disclosed herein are methods and compositions for isolating a protein fraction from a potato sample. The methods include adjusting the potato sample containing the protein fraction to a pH of about 4.0 to 5.2; and loading the potato sample onto a sulfonated epoxy resin, wherein the sulfonated epoxy resin comprising Formula (I) is adjusted to a pH of about 4.0 to 4.5. The methods also include washing the sulfonated epoxy resin and eluting the protein fraction.
WATER SOFTENING DEVICE AND REGENERATION METHOD THEREOF
Provided is a water softening device including a water softening tank that softens raw water using a weakly acidic cation exchange resin, a pH adjustment tank, an electrolytic cell that produces acidic electrolyzed water, a conductivity measurement unit S.sub.1 that measures conductivity of the raw water, a conductivity measurement unit S.sub.2 that measures conductivity of soft water, a water flow amount detecting unit, and a control unit, wherein the control unit calculates a regeneration time for the weakly acidic cation exchange resin based on an amount of the hardness component adsorbed to the weakly acidic cation exchange resin calculated from a difference between the conductivity of the raw water and the conductivity of the soft water and from the accumulated water flow amount of the raw water, and performs a regeneration treatment of the weakly acidic cation exchange resin during the regeneration time.
Method for identifying the unit causing a raw water leak in a condenser of a thermal power plant
The present invention relates to a method for identifying the unit causing a raw water leak in a condenser of a thermal power plant consisting of n units.