Patent classifications
B01J2219/00168
Continuous solid-state polymerisation device and method
The continuous solid-state polymerization device of the present invention comprises: a feeder for continuously introducing a prepolymer; a horizontal reactor which is connected via a first connecting part to the feeder and receives the prepolymer from the feeder so as to subject same to solid-state polymerization, wherein the reactor itself is rotated; a stirring device which comprises a stirring shaft rotating inside the horizontal reactor, in the direction opposite to that of the rotational axis of the horizontal reactor, and comprises stirring blades joined vertically to the stirring shaft; and a chamber which is connected via a second connecting part to the horizontal reactor and, once the solid-state polymerization has been completed, receives the resulting polymer discharged from the horizontal reactor, and, here, the feeder, the horizontal reactor and the chamber are in a vacuum state. The continuous solid-state polymerization device prevents the formation of prepolymer stagnation zones, and allows solid-state polymerization to take place continuously in the vacuum state without any inert gas.
Method for preparing a catalyst support
A process for preparing a powder support containing alumina and silica or their derivatives for a catalyst of a Fischer-Tropsch type reaction, including stage (a) of preparing a first reactant containing an alumina compound or precursor including a reaction for peptization of an alumina compound or precursor in the presence of an acid, to form solid particles in suspension, stage (b) of preparing a second reactant based on silicic acid and/or on a compound or precursor of silicic acid, including a controlled aging treatment of the silicic acid targeted at its polymerization up to a degree of conversion of the silicic acid of at most 70%, stage (c) of mixing the two reactants in a mixer, and the pH of the first reactant is adjusted to a value not exceeding a given maximum pH threshold.
OXYGEN-BASED CONTROL OF POLYMERIZATION REACTIONS
Methods and devices for controlling polymerization reactions using the controlled addition of oxygen to a reactor. The method may include providing a reactor comprising one or more chemical components suitable for facilitating a polymerization reaction and continuously measuring one or more polymer characteristics of polymers generated by the polymerization reaction in the reactor. The method may also include determining, using a control algorithm, based on the continuous measurements of one or more polymer characteristics, the amount of oxygen to add to the reactor at one or more time points during the polymerization reaction in order to cause the one or more polymer characteristics to follow a predetermined target trajectory.