Patent classifications
B01J2219/0894
Diphasic gas/liquid plasma reactor
The present invention relates to a microfluidic or millifluidic device (1) comprising: —a support (2) made at least partially of a dielectric material, the support (2) comprising a first inlet (21a) adapted to be connected to a first reservoir containing gas, a second inlet (21b) adapted to be connected to a second reservoir containing liquid, an outlet (22) adapted to be connected to a receiver container containing gas and/or liquid, and a main microchannel or millichannel (3) present in the dielectric material allowing the liquid and the gas to flow from the inlets towards the outlet, —one or several ground electrode(s) (4) embedded in said dielectric material and extending along the main microchannel or millichannel (3), and —one or several high-voltage electrode(s) (5) embedded in said dielectric material and extending along the main microchannel or millichannel (3), wherein the high-voltage electrode(s) (5) and the ground electrode(s) (4) are located on opposite sides of the main microchannel or millichannel (3) so as to be able to generate an electric field inside the main microchannel or millichannel (3). The present invention relates also to a method for generating a plasma in a continuous manner using such a microfluidic or millifluidic device (1).
Continuous methods for treating liquids and manufacturing certain constituents (e.g., nanoparticles) in liquids, apparatuses and nanoparticles and nanoparticle/liquid solution(s) resulting therefrom
This invention relates generally to novel methods and novel devices for the continuous manufacture of nanoparticles, microparticles and nanoparticle/liquid solution(s). The nanoparticles (and/or micron-sized particles) comprise a variety of possible compositions, sizes and shapes. The particles (e.g., nanoparticles) are caused to be present (e.g., created) in a liquid (e.g., water) by, for example, preferably utilizing at least one adjustable plasma (e.g., created by at least one AC and/or DC power source), which plasma communicates with at least a portion of a surface of the liquid. At least one subsequent and/or substantially simultaneous adjustable electrochemical processing technique is also preferred. Multiple adjustable plasmas and/or adjustable electrochemical processing techniques are preferred. The continuous process causes at least one liquid to flow into, through and out of at least one trough member, such liquid being processed, conditioned and/or effected in said trough member(s). Results include constituents formed in the liquid including micron-sized particles and/or nanoparticles (e.g., metallic-based nanoparticles) of novel size, shape, composition and properties present in a liquid.
Plasma dry reforming apparatus
The present invention discloses a plasma dry reforming apparatus for producing synthetic gas, main components of which are hydrogen and carbon monoxide, by reforming methane and carbon dioxide injected in plasma, the apparatus comprising: a plasma reformer 100, 200 which produces carbon dioxide plasma by making carbon dioxide supplied therein into plasma, ignites plasma flame by supplying hydrocarbon to the produced dioxide plasma, and produces synthetic gas by supplying methane to the plasma flame.
Method and device for treating two-phase fragmented or pulverized material by non-isothermal reactive plasma flux
Method and device implemented in a reactor for the plasma treatment of carried fragmented material or of pulverized elements by a support gas where the main element is an intermediate temperature plasma (PIT) generator fed by a source of electric pulses, the amplitude of whose current is limited and for which the generating frequency, the duration of the pulses and the duration of the time spans between the pulses are determined in such a way as to generate a nonthermal plasma (PIT) of large extent, the plasma and the carrier gas flux (4) laiden with the fragments of material or of pulverized elements to be treated (5) moving along helical trajectories coaxial with the axis of the reactor at controlled angles a and B respectively relative to the plane perpendicular to the axis of the reactor, the angles a and B being able to vary in a given manner according to the properties of the material to be treated and the technological parameters and the dimensions of the reactor. Use of the invention both for the combustion of combustible powders in the boilers of electric power plants and for the generation of solid or gaseous combustible products, of given properties and dimensions, effected through the organization of plasmochemical reactions on fragments or pulverized elements of organic materials in the reactor.
LIQUID TREATMENT APPARATUS
A liquid treatment apparatus comprises: a first tank in which a first gas containing nitrogen and oxygen and a liquid are stored; a plasma generating apparatus, including a first electrode and a second electrode, which effects discharge between the first electrode and the second electrode and thereby generates plasma that makes contact with at least part of the liquid; and a gas supply apparatus that supplies a first part of the first gas from the first tank to the plasma generating apparatus.
Reactor comprising a plasma source and a catalyst comprising a mesoporous support material for the preparation of ethene from methane
The invention relates to a reactor comprising a plasma source and a catalyst comprising a mesoporous support. The invention also relates to a process comprising feeding methane to said reactor in order to obtain one or more of ethene, hydrogen and carbon as well as downstream products derived from ethene thus obtained. The invention relates to a reactor comprising as reactor parts: a. a housing and in said housing; b. a plasma source; and c. a catalyst, wherein said catalyst comprises as catalyst parts: i) a mesoporous support; ii) a metal selected from the group Pd, Ni, Ag or at least two thereof, wherein the metal is carried by said mesoporous support; wherein at least a part of said plasma source is located in said housing upstream of said catalyst.
Liquid treatment device and liquid treatment method
The present disclosure provides a liquid treatment device and a liquid treatment method each capable of efficiently generating plasma and treating a liquid in a short time period. A liquid treatment device according to the present disclosure includes a first electrode, a second electrode disposed in a liquid, an insulator disposed surrounding the first electrode through a space, the insulator having an opening portion at a position in contact with the liquid, and a power supply that applies an AC voltage or a pulse voltage between the first electrode and the second electrode.
SYSTEMS AND METHODS FOR PROCESSING GASES
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.
LOW PRESSURE GENERATING PLASMA REACTOR CLOSED LOOP PROCESS AND SYSTEM
The present invention provides a low pressure generating plasma reactor closed loop process, comprising: feeding a fresh feed gas flow and a fresh feed absorption liquid flow to a plasma reactor closed loop comprising a condenser, a liquid loop, a recycle gas loop, and a plasma generator; converting feed gas to reactive plasma products in the plasma generator; quenching and absorbing the reactive plasma products into an absorption liquid circulating in the liquid loop where the reactive plasma products react to form liquid reaction products, thereby generating low pressure in the closed loop; monitoring the composition and low pressure of the recycle gas loop and, if the pressure increases, adjusting the composition of the fresh feed gas flow and/or fresh feed absorption liquid flow to bring the composition of the feed gas towards stoichiometric ratio with the absorbed reactive plasma products; extracting circulating absorption liquid, containing the liquid reaction products, from the plasma reactor closed loop as a product flow. The present invention also provides a low pressure generating plasma reactor closed loop system, comprising a plasma generator, a condenser, a recycle gas loop, a liquid loop, and a pump.
METHOD FOR MANUFACTURING POROUS CARBON MATERIAL DOPED WITH HETEROGENEOUS ELEMENT AND POROUS CARBON MATERIAL DOPED WITH HETEROGENEOUS ELEMENT PREPARED THEREFROM
A method for manufacturing a porous carbon material doped with a heterogeneous element and a porous carbon material doped with a heterogeneous element manufactured using the method are proposed. The method includes melting carbon precursor powder that contains one or more kinds of heterogeneous elements selected from metal and nonmetal to prepare a precursor melt; disposing a pair of metal wires in the precursor melt; and applying power to the metal wires to perform plasma-discharge, thus forming and aggregating carbon nanoparticles doped with the heterogeneous element while having a micropore and thereby forming a porous carbon material having a meso-macro hierarchical pore structure. As the heterogeneous element is bound to carbon of the carbon precursor, the carbon nanoparticles are formed in an amorphous structure while being doped with the heterogeneous element, thus increasing an active site.