B01J2219/185

METHOD AND REACTOR FOR CONVERSION OF HYDROCARBONS
20230256406 · 2023-08-17 ·

A reactor and method for the conversion of hydrocarbon gases utilizes a reactor (12, 312, 412, 512, 612, 712) having a unique feed assembly with an original vortex combustion chamber (40, 340, 436, 536, 636, 736), a diverging conduit (48, 348, 448, 548, 648, 748), and a cylindrical reactor chamber (40, 340, 436, 536, 636, 736). This design creates a compact combustion zone and an inwardly swirling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a diverging conduit (48, 348, 448, 548, 648, 748). The feed streams can be introduced into the reactor at any angle (perpendicular, axial, or something between, or a combination of the above forms) with swirling flow components. This provides conditions suitable for efficient cracking of hydrocarbons, such as ethane, to form olefins.

Method of manufacturing bio-diesel and reactor

A reactor and process for the production of bio-diesel. The reactor includes one or more coiled reaction lines. The lines are positioned within a tank containing a heat transfer media such as molten salt, maintained at about 750° F. A pump circulates the media within the tank. An emulsion of alcohol; refined feed stock, including glycerides and/or fatty acids; and preferably water is pumped through the reaction lines at temperatures and pressures sufficient to maintain the alcohol in a super-critical state. The curvature of the coils, pump pulsing, and the flow rate of the emulsion keep the emulsion in a turbulent state while in the reactor, ensuring thorough mixing of the alcohol and feed stock. The alcohol reacts with the glycerides and fatty acids to form bio-diesel. The reaction is fast, efficient with regard to energy input and waste generation, and requires minimal alcohol.

Method for carrying out a gas/fluid two-phase high-pressure reaction

A process for performing a continuous gas/liquid biphasic high-pressure reaction, wherein a gas and a liquid are introduced into a backmixed zone of a reactor and in the backmixed zone the gas is dispersed in the liquid by stirring, injection of gas and/or a liquid jet, a reaction mixture consecutively traverses the backmixed zone and a zone of limited backmixing, and a liquid reaction product is withdrawn at a reaction product outlet of the zone of limited backmixing, wherein the reactor comprises: an interior formed by a cylindrical vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by means of internals into the backmixed zone, the zone of limited backmixing and a cavity, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a third internal element which in the interior extends in the longitudinal direction of the reactor and is open at the bottom, wherein the third internal element forms the cavity in which gas bubbles collect and do not escape upwards, thus preventing the volume of the cavity from being occupied by liquid and reducing the reaction volume. The reaction volume of the reactor used in the process can be reversibly reduced in simple fashion. The invention further relates to a process for adapting the reaction volume of a reactor suitable for performing a gas/liquid biphasic high-pressure reaction having an outlet for a liquid reaction product in which an internal element is arranged so as to form a cavity open at the bottom in which gas bubbles collect and do not escape upwards, thus preventing the volume of the cavity from being occupied by liquid and reducing the reaction volume.

SYSTEMS AND METHODS FOR MAKING CERAMIC POWDERS

Systems and methods for making ceramic powders configured with consistent, tailored characteristics and/or properties are provided herein. In some embodiments a system for making ceramic powders, includes: a reactor body having a reaction chamber and configured with a heat source to provide a hot zone along the reaction chamber; a sweep gas inlet configured to direct a sweep gas into the reaction chamber and a sweep gas outlet configured to direct an exhaust gas from the reaction chamber; a plurality of containers, within the reactor body, configured to retain at least one preform, wherein each container is configured to permit the sweep gas to flow therethrough, wherein the preform is configured to permit the sweep gas to flow there through, such that the precursor mixture is reacted in the hot zone to form a ceramic powder product having uniform properties.

METHOD FOR CARRYING OUT A GAS/FLUID TWO-PHASE HIGH-PRESSURE REACTION

A process for performing a continuous gas/liquid biphasic high-pressure reaction, wherein a gas and a liquid are introduced into a backmixed zone of a reactor and in the backmixed zone the gas is dispersed in the liquid by stirring, injection of gas and/or a liquid jet, a reaction mixture consecutively traverses the backmixed zone and a zone of limited backmixing, and a liquid reaction product is withdrawn at a reaction product outlet of the zone of limited backmixing, wherein the reactor comprises: an interior formed by a cylindrical vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by means of internals into the backmixed zone, the zone of limited backmixing and a cavity, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a third internal element which in the interior extends in the longitudinal direction of the reactor and is open at the bottom, wherein the third internal element forms the cavity in which gas bubbles collect and do not escape upwards, thus preventing the volume of the cavity from being occupied by liquid and reducing the reaction volume. The reaction volume of the reactor used in the process can be reversibly reduced in simple fashion. The invention further relates to a process for adapting the reaction volume of a reactor suitable for performing a gas/liquid biphasic high-pressure reaction having an outlet for a liquid reaction product in which an internal element is arranged so as to form a cavity open at the bottom in which gas bubbles collect and do not escape upwards, thus preventing the volume of the cavity from being occupied by liquid and reducing the reaction volume.

Method, an arrangement and use of an arrangement of preparing polymer

A method and arrangement of producing polymer comprising polymerizing in reactor having a top zone having a generally conical shape, a middle zone in direct contact with and below said top zone having a generally cylindrical shape, a bottom zone having a generally conical shape thereby polymerizing at least one olefin, in the presence of a polymerization catalyst and fluidization gas to obtain (i) a first stream comprising fluidization gas and particles of olefin polymer, (ii) a second stream comprising fluidization gas and agglomerates of olefin polymer, (iii) a third olefin polymer product stream, —directing the first stream comprising fluidization gas and olefin polymer particles to a series of at least three cyclones connected to the fluidized bed reactor, —separating agglomerates of olefin polymer from the second stream, withdrawing from the fluidized bed polymerization reactor the third olefin polymer product stream.

Reactor for a metallocene catalyst-based solution polymerization process for preparing polyolefin polymers
11219877 · 2022-01-11 · ·

Disclosed is a reactor for solution polymerization process using a metallocene catalyst for preparing polyolefin. The reactor includes: a reaction vessel for mixing a hydrocarbon-based solvent and an olefin monomer to produce polyolefin; a feed inlet installed at a lower portion of the reaction vessel to feed a feed including an unreacted monomer, a solvent, and a catalyst into the reaction vessel; a guide pipe having a cylinder shape being open at respective ends, installed along a central axis of the reaction vessel, and dividing an internal space of the reaction vessel into an up-flow region where a reaction mixture flows upward and a down-flow region where the reaction mixture flows downward; a swirling flow-inducing blade attached to the exterior surface of the guide pipe, causing the reaction mixture in the reaction vessel to rise along the exterior surface of the guide pipe while forming a swirling flow.

Separating sweet gas from a sour gas stream

An oxidation-reduction desulfurization system includes a reactor vessel with sour gas inlet at the bottom and a gas outlet at the top. A primary stage phase separator includes a vertically-oriented pipe with an inlet located inside the reactor vessel. The ratio of the reactor vessel diameter to the pipe inlet diameter is in a range of 2:1 to 5:1. Surface foam and non-gaseous multi-phase mixture including emulsion flow into a partially gas-filled upper section of the vertically-oriented pipe and freefall to a lower level, thereby facilitating mechanical breaking of the foam and the emulsion. A secondary stage phase separator connected to the gas outlet separates non-gaseous surge from sweet gas. Valves and a controller automatically maintain target levels of the non-gaseous multi-phase mixture and non-gaseous surge.

A METHOD FOR PREPARING NANOMETER-SIZED SURFACE FLUORINATED BATTERY MATERIALS
20230299263 · 2023-09-21 ·

A method uses mild fluorinating agents, such as hydrofluorocarbons—HCFs, perfluorocarbons—PFCs, hydrochlorofluorocarbons HCFCs and chlorofluorocarbons—CFCs, to fine-tune the fluorination process in battery material preparation in order to obtain uniform nanometer-sized surface fluoride coated battery materials. The use of a vertical flow-type tube reactor permits a fine-tuning of the fluorination process by accurately regulating the active gas or mixture of gases flow over battery materials using mass-flow regulators, and precisely setting the temperature with vertical rube furnace. Additionally, these fluorinating agents have slightly different reactivity, decomposing and reacting with battery materials at different temperatures, and therefore, offering additional parameter of fluorination fine-tuning. The method is scalable and can be easily adapted as an industrial solution. Moreover, all these gases are non-toxic, non-corrosive and non-flammable gases at room temperatures, hence, they are more convenient to handle than highly-toxic and highly-corrosive HF and F.sub.2 gases.

METHANE CRACKING APPARATUS

A methane cracking apparatus includes a supply pipeline that supplies a gas, a reactor having an interior space, and in which a catalyst for decomposing the gas may be disposed in the interior space, an agitator provided in the interior space and that agitates a material in the interior space, a first discharge pipeline connected to the reactor and that discharges decomposition materials generated as the gas may be decomposed, and a second discharge pipeline connected to the reactor, that discharges the decomposition materials, and disposed on an upper side of the first discharge pipeline.