Method for manufacturing an inert solid support with optionally functionalised carbon nanotubes (CNTs), comprising the steps of: i) providing an inert solid support and at least one catalytic metal associated with, or absorbed in, or adsorbed/deposited on, said support, said metal being optionally selected from among the group consisting of iron, cobalt, nickel, molybdenum and combinations thereof; ii) supplying a source of gaseous, liquid or solid carbon to the catalytic metal; iii) through chemical vapor deposition (CVD), depositing at least part of the carbon source at the catalytic metal as CNTs, stably connected to the inert solid support. The present invention further regards an inert solid support and a separation method.

A hyper-productive chromatography technique includes providing a scalable and stackable chromatographic cassette, loading a sample to be processed, operating the scalable chromatographic cassette having an adsorptive chromatographic bed having a volume greater than 0.5 liter by establishing a flow at a linear velocity greater than 500 cm/hr with a residence time of the loading step of less than one minute.

The present invention provides that powder is mainly constituted from secondary particles of hydroxyapatite. The secondary particles are obtained by drying a slurry containing primary particles of hydroxyapatite and aggregates thereof and granulating the primary particles and the aggregates. A bulk density of the powder is 0.65 g/mL or more and a specific surface area of the secondary particles is 70 m.sup.2/g or more. The powder of the present invention has high strength and is capable of exhibiting superior adsorption capability when it is used for an adsorbent an adsorption apparatus has.

Described herein is a system (100) for storage and releasing of carbon dioxide comprising at least one solids reactor (1), at least one compressor (7, 8) for compressing the carbon dioxide-containing gas or fluid, respectively, which is introduced through the inlet (3) of the solids reactor, wherein the compressor (7, 8) is constructed in such a way that it adiabatically expands the gas or fluid, respectively, depleted of carbon dioxide that is discharged from the reactor by means of the outlet (2) of the solids reactor, and at least one countercurrent recuperator (6), which is constructed for the heat exchange of the compressed exhaust gas or fluid, respectively, that contains carbon dioxide and the gas or fluid, respectively, depleted of carbon dioxide.

Described is furthermore a solids reactor for storage and releasing carbon dioxide, comprising a gas-tight or fluid-tight, respectively, housing, which has an interior, at least one inlet for feeding in fluids and at least one outlet for discharging of gases or fluids, respectively, wherein the interior of the housing is filled with at least two different solids, wherein one solid is provided for storing thermal energy and the other solid is provided for regenerative storage and releasing of carbon dioxide.

Furthermore described is a method for storage and releasing of carbon dioxide.

A device, system, and method for small scale CO.sub.2 extraction is disclosed. The device includes a sorbent bed having a sorbent resin. The device also includes a blower in fluid communication with the sorbent bed through at least one duct, as well as a collection tray beneath the sorbent bed and having a drain. The device also includes a capture configuration and a regeneration configuration. The capture configuration includes an air flow driven by the blower passing through the sorbent resin. The regeneration configuration includes the flooding of at least the sorbent resin with regeneration fluid. The regeneration fluid has a higher dissolve inorganic carbon concentration after flooding the sorbent resin. Multiple devices may be employed together as a system capable of providing a continuous product stream having an upgraded concentration of CO.sub.2.

Disclosed in certain embodiments are sorbents for capturing heavy hydrocarbons via thermal swing adsorption processes.

A method for separating mixed xylene includes steps that the mixed xylene is subjected to adsorption separation by means of an adsorbent having a metal organic framework material, so that one or more of xylene isomers are separated out. An organic ligand in the metal organic framework material is 2,5-dihydroxy-1,4-benzoquinone. Xylene isomers can be effectively separated using this method.

A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.

Process for converting waste plastics to refining feedstock. The process includes conducting pyrolysis of a plastic feedstock comprising waste plastics to produce a liquid stream of plastic pyrolysis oil; directly feeding the liquid stream of plastic pyrolysis oil to an adsorption based purification process to generate a treated plastic pyrolysis oil stream; and collecting the treated plastic pyrolysis oil stream from the adsorption vessel for further processing into value added products as a feedstock for conventional refining processes. The adsorption based purification process includes contacting the liquid stream of plastic pyrolysis oil with one or more adsorbent materials in an adsorption vessel, the adsorbent materials with at least one of the one or more adsorbent materials being configured for adsorption of organic molecules having heteroatoms of each of sulfur, nitrogen, oxygen, and chlorine. Such system may be integrated with a conventional refinery.

A method and exhaust gas treatment system for treating an ammonia-containing exhaust gas, for example a livestock house exhaust gas. The exhaust gas treatment system comprises a plurality of sorbent beds comprising a copper-doped small-pore zeolite, a valve system configured to establish independently for each sorbent bed fluid communication in a first or second configuration, wherein in the first configuration a flow of ammonia-containing exhaust gas contacts the sorbent bed at a temperature of less than 50° C. for storing the ammonia; and in the second configuration a flow of heated gas maintains the sorbent bed at a temperature of at least 300° C. for releasing and treating the ammonia in situ.