Patent classifications
B01J2229/20
HYDROCARBON CONVERSION CATALYST COMPOSITION
A hydrocarbon conversion catalyst composition which comprises ZSM-48 and/or EU-2 zeolite particles and refractory oxide binder essentially free of alumina in which the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.3 times the aluminium concentration at the surface of the particles, processes for preparing such catalyst compositions and processes for converting hydrocarbon feedstock with the help of such compositions.
Process for preparing a molybdenum-platinum-based catalyst for the synthesis of benzene by transalkylation
A process for preparing a catalyst composition comprising (a) preparing a carrier comprising (i) mordenite in an amount in the range of from 20 to 80 wt %, based on total weight of carrier, (ii) ZSM-5 type zeolite in an amount in the range of from 10 to 70 wt %, based on total weight of carrier; and (iii) an inorganic binder in an amount in the range of from 10 to 50 wt %, based on total weight of carrier; (b) incorporating in the carrier molybdenum in an amount in the range of from 1 to 10 wt %, as metal based on total weight of catalyst composition, and subjecting the thus treated carrier to a temperature of from 100 to at most 300 C. and (c) incorporating in the molybdenum containing carrier obtained in step (b) platinum in an amount of from 0.005 to 1 wt %, as metal based on total weight of catalyst composition, and subjecting the thus treated carrier to a temperature of from 200 to at most 600 C.; and a process for conversion of alkylaromatic hydrocarbons containing feedstock using a catalyst prepared by said process. Process using the prepared catalyst composition for alkylaromatic hydrocarbon conversion.
MANUFACTURING HYRDOCRACKING CATALYST
A method including subjecting an ultra-stable Y-type zeolite having a low silica-to-alumina molar ratio (SAR), such as in a range of 3 to 6, to acid treatment and heteroatom incorporation contemporaneously to give a framework-modified ultra-stable Y-type zeolite.
AROMATIZATION CATALYST, PREPARATION METHOD, REGENERATION METHOD THEREOF, AND AROMATIZATION METHOD
The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.
Acidic aromatization catalysts with improved activity and selectivity
Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of impregnating the bound zeolite base with the transition metal, fluorine, and high loadings of chlorine. The resultant high chlorine content supported catalysts have improved catalyst activity in aromatization reactions.
Process for preparing a catalyst based on IZM-2 from a solution comprising specific precursors and use for the isomerization of paraffinic feedstocks
The present invention relates to a process for preparing a difunctional catalyst using a zeolite IZM-2, a hydrogenating function and a matrix. The preparation process according to the invention simultaneously allows preferential localization of said hydrogenating function on the surface and/or in the microporosity of zeolite IZM-2 and homogeneous distribution of the hydrogenating function in the catalyst and preferably on zeolite IZM-2 by means of using an impregnation solution comprising specific noble metal precursors combined with the presence of ammonium salts, with a quite precise ratio of ammonium salt to noble metal.
METHOD FOR PREPARING HYDROCRACKING CATALYST
This invention discloses a preparation method of a hydrocracking catalyst. According to the method, a new functional group is modified through chemical bonds on the surface of a traditionally prepared inorganic carrier, and a VIB group metal element and a VIIIB metal element are then loaded on the carrier to prepare the hydrocracking catalyst. The hydrocracking catalyst prepared according to the invention has a higher diesel liquid yield.
UZM-54 AND TRANSALKYLATION PROCESS USING SAME
A catalyst suitable for the conversion of aromatic hydrocarbons is described. The catalyst comprises UZM-54 zeolite; a mordenite zeolite; a binder comprising alumina, silica, or combinations, thereof; and a metal selected from one or more of: Groups VIB(6) VIIB(7), VIII(8-10) and IVA(14) of the Periodic Table. A process for transalkylation using the catalyst is also described.
Zeolitic catalytic conversion of alcohols to olefins
A catalyst composition for converting an alcohol to olefins, the catalyst composition comprising the following components: (a) beta zeolite; (b) at least one element selected from the group consisting of zinc, magnesium, calcium, strontium, sodium, and potassium; and (c) at least one element selected from the group consisting of hafnium, yttrium, zirconium, tantalum, niobium, and tin; wherein the components (b) and (c) are independently within or on a surface of said beta zeolite. The catalyst may also further include component (d), which is copper or silver. Also described herein is a method for converting an alcohol to one or more olefinic compounds, the method comprising contacting the alcohol with a catalyst at a temperature of at least 100 C. and up to 500 C. to result in the alcohol being converted to the one or more olefinic compounds.
SINGLE STEP PROCESS FOR THE SIMULTANEOUS PRODUCTION OF AROMATICS, NAPHTHENICS AND ISOPARAFFINS USING TRANSITION METAL FUNCTIONALIZED ZEOLITE BASED CATALYST
Hydrocarbon composition plays vital role in fuel quality. For gasoline/motor spirit applications the hydrocarbon should have more octane-possessing molecules from the groups of aromatics, naphthenics and isoparaffins, while n-paraffins are not preferred due to their poor octane. Among the high-octane groups, again aromatics occupy the top but not more than 35 vol % aromatics can be mixed in gasoline for engine applications to avoid harmful emission, But there is no single process that addresses so far the issue of co-producing all the desired hydrocarbon components in a single process. Thus, it is interesting to have a single once-through process working on single catalyst system to produce mixture of all three high-octane molecules namely, aromatics, naphthenics and isoparaffins directly from low-value, low-octane n-paraffin feed. Herein, we report a novel single-step catalytic process for the simultaneous production of aromatics, naphthenics and isoparaffins for gasoline and petrochemical applications.