A nanostructured porous catalyst for rubber vulcanization, the catalyst comprising a high surface area.

A millimeter-scale peroxymonosulfate activator ZSM-5-(C@Fe) and a preparation method and an application thereof are provided. According to the method, a PMS activator ZSM-5-(C@Fe) with a millimeter-scale stable structure is synthesized in the following steps: (1) preprocessing a ZSM-5 by a carboxylation method to obtain a ZSM-5-COOH; (2) synthesizing a ferrous metal organic framework material by a thermal method to obtain a precursor Fe (II)-MOF-74; (3) dispersing the ZSM-5-COOH in the step (1) and an ethyldiol methacrylate in an acetonitrile, and mixing evenly to obtain a mixed solution; and adding the precursor Fe(II)-MOF-74 in the step (2) into the mixed solution, carrying out a stirring reaction under an action of an initiator, filtering to obtain a precipitate, washing, and drying in vacuum to obtain ZSM-5-MOFs; and (4) in a nitrogen atmosphere, heating the ZSM-5-MOFs in the step (3) to carry out high-temperature pyrolysis to obtain the millimeter-scale peroxymonosulfate activator ZSM-5-(C@Fe).

A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.

A method for modifying the surface of a molecular sieve, comprising reacting a molecular sieve with an aminosilane, wherein the reaction is carried out in an aqueous solvent. A modified molecular sieve obtained by the method is also described.

Provided is a beta zeolite satisfying P>76.79Q−29.514 in a range in which Q is less than 0.4011 nm, wherein, P represents an AB value that is an intensity ratio of A to B, A represents a diffraction intensity of a main peak of the beta zeolite observed by X-ray diffraction measurement, B represents a diffraction intensity of the (116) plane of α-alumina obtained by X-ray diffraction measurement under the same conditions as those for the X-ray diffraction measurement on the beta zeolite, the α-alumina being the standard substance 674a distributed by the American National Institute of Standards and Technology, and Q represents a lattice interplanar spacing of the main peak of the beta zeolite observed by X-ray diffraction measurement. It is preferable that the formula (1) above is satisfied in a range in which Q is from 0.3940 to 0.4000 nm.

An inorganic porous carrier including a linker of formula (1) and having mode diameter of 0.04 μm to 1 μm in a pore distribution and the density of voids having an opening area of 0.0025 μm.sup.2 or more of 12 to 30 voids/μm.sup.2 [a bond * represents a linkage to the oxygen atom in a silanol group of an inorganic porous substance; n is an integer; R represents an alkyl group containing 3 to 10 carbon atoms which may optionally have a substituent such as an alkoxy group; and L represents a single bond; an alkylene group of 1 to 20 carbon atoms; or an alkylene group containing 2 to 20 carbon atoms containing —CH.sub.2-Q-CH.sub.2— group wherein Q selected from a group consisting of —O— etc. is inserted into at least one of —CH.sub.2—CH.sub.2— group constituting the alkylene group]; and a method for preparing a nucleic acid using the same.

##STR00001##

This invention discloses a preparation method of a hydrocracking catalyst. According to the method, a new functional group is modified through chemical bonds on the surface of a traditionally prepared inorganic carrier, and a VIB group metal element and a VIIIB metal element are then loaded on the carrier to prepare the hydrocracking catalyst. The hydrocracking catalyst prepared according to the invention has a higher diesel liquid yield.

An inorganic porous carrier that can be used to increase the purity of nucleic acid in a production thereof, and that comprises a linker of formula (1), wherein a Survival Bone Rate (SBR) value is 5.0% or more. In the formula (1), a bond * represents a linkage of an inorganic porous substance to the oxygen atom of a silanol group; n is an integer of 1 etc.; R represents independently of each other an alkyl group containing 3 to 10 carbon atoms which may have a substituent such as an alkoxy group etc.; and L represents a single bond; an alkylene group of 1 to 20 carbon atoms; or an alkylene group containing 2 to 20 carbon atoms which contains —CH.sub.2-Q-CH.sub.2— group wherein any group Q selected from a group consisting of —O— etc. is inserted into at least one of —CH.sub.2—CH.sub.2— group constituting the alkylene group.

##STR00001##

Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

Catalysts for the direct decomposition of NO are provided. The catalysts comprise SiO.sub.2 pillared magadiite or ilerite comprising intercalated Cu, Fe or Mn oxide. Methods and systems for using the catalysts to directly decompose NO are also provided.