Patent classifications
B01J2229/66
PRODUCTION OF ZEOLITE-BASED COMPOSITE MATERIALS WITH HIERARCHICHAL POROSITY
A method is provided for generating a composite material with a support structure and a coating on the surface of the support structure, the coating comprising, as active component, crystals of a zeolite material or of a zeolite-like material, with intercrystalline mesopores and/or macropores being formed in the coating, characterized in that the method comprises the following steps: a) providing a suspension which comprises nanoscale starting crystals of a zeolite material or of a zeolite-like material, and also precursor compounds of the zeolite material or zeolite-like material, b) applying the suspension provided in step a) to the surface of the support structure, c) compacting the suspension applied in step b) by at least partially removing the solvent that forms the liquid phase of the suspension, to yield a coating which comprises the starting crystals and the precursor compounds, d) keeping the coating obtained in step c) on the surface of the support structure in a vapor-containing atmosphere at an elevated temperature, so that the precursor compounds present are converted into a zeolite material or a zeolite-like material and, together with the starting crystals, form the coating which comprises crystals of a zeolite material or of a zeolite-like material.
Integrated purification method and system for the industrial exhaust gas containing cyanides, hydrocarbons and NOx
An integrated purification method and an integrated purification system for an industrial exhaust gas containing cyanides, hydrocarbons and NO.sub.x. The method comprises the steps of: 1) subjecting the exhaust gas containing pollutants such as cyanides, hydrocarbons and nitrogen oxides (NO.sub.x) to a gas-liquid separation device (1) to separate the free fluid, then mixing with the air blown by the air blower (201, 202), and preheating by the heating unit; 2) the mixture entering into the selective catalytic combustion (SCC) reactor (5) for the selective catalytic combustion reaction to convert harmful substances into CO.sub.2, H.sub.2O and N.sub.2, the catalysis being performed in two stages: the earlier stage is catalyzed by supported molecular sieve catalyst, and the latter stage is catalyzed by supported precious metal catalyst; and 3) the gas came out from the SCC reactor (5) entering into the heating unit to recover the heat, and then the purified exhaust gas being discharged directly through the chimney (6). The system comprises a gas-liquid separation device (1), a heating unit and a selective catalytic combustion reactor (5), a gas outlet of the gas-liquid separation device (1) being connected to the selective catalytic combustion reactor (5) through the heating unit, and an exhaust gas outlet of the selective catalytic combustion reactor (5) being connected to a chimney (6) through the heating unit.
SLURRY COMPOSITION FOR CATALYST AND METHOD FOR PRODUCING SAME, METHOD FOR PRODUCING CATALYST USING THIS SLURRY COMPOSITION FOR CATALYST, AND METHOD FOR PRODUCING CU-CONTAINING ZEOLITE
A slurry composition for a catalyst and a method for producing the same, a catalyst and a method for producing the same using the slurry composition for a catalyst. The method omits many heretofore required treatment steps and reduces catalyst production cost. The method comprising the steps of providing a slurry composition for a catalyst, comprising at least an aluminosilicate, Cu, and water, and having a solid concentration of 0.1% by mass to 90% by mass, wherein a component for a catalyst has composition represented by Al.sub.2O.sub.3.xSiO.sub.2.yT.sub.2O.zCuO (wherein T is a quaternary ammonium cation, and x, y and z are numbers that satisfy 10x40, 0.1y<2.0, and 0.1z<2.0, respectively) in terms of molar ratio based on an oxide; coating at least one side of a support with this slurry composition; and heat-treating at 350 C. or higher.
Monolithic catalyst comprising molecular sieve membrane and method for preparing the monolithic catalyst
A monolithic catalyst, including cobalt, a metal matrix, a molecular sieve membrane, and an additive. The metal matrix is silver, gold, copper, platinum, titanium, molybdenum, iron, tin, or an alloy thereof. The molecular sieve membrane is mesoporous silica SBA-16 which is disposed on the surface of the metal matrix and is a carrier of the active component and the additive. The thickness of the carrier is between 26 and 67 m. The additive is lanthanum, zirconium, cerium, rhodium, platinum, rhenium, ruthenium, titanium, magnesium, calcium, strontium, or a mixture thereof. A method for preparing the monolithic catalyst is also provided.
METHOD OF FORMING AN ALUMINOSILICATE-ZEOLITE LAYER ON AN ALUMINIUM-CONTAINING METALLIC SUBSTRATE AND USE OF THE SUBSTRATE OBTAINED THEREBY
The invention relates to a method of forming an aluminosilicate zeolite layer on an aluminium-containing metallic substrate composed of metallic aluminium or an aluminium alloy which is introduced into an alkalized aqueous reaction dispersion in which silicon and optionally aluminium are present as network-forming elements, where, irrespective of whether or not aluminium is present in the aqueous reaction dispersion, the molar ratio between the aluminium in the aqueous reaction dispersion and the sum total of the network-forming elements present in the aqueous reaction dispersion is below 0.5, where, when aluminium is not present in the aqueous reaction solution, the deficiency molar ratio is 0, and the alkalized aqueous reaction dispersion containing the aluminium-containing metallic substrate is heated and aluminium is removed from the aluminium-containing metallic substrate for the aluminosilicate zeolite formation process and the layer of an aluminosilicate zeolite is formed on the aluminium-containing metallic substrate by in situ crystallizative application. In the course of this, an aluminium complexing agent with anchoring oxygen atoms is incorporated into the alkalized aqueous reaction dispersion. The invention further relates to the advantageous use of the method product in sorption-based fields of application.
REACTIVE FILTER FOR MOTOR VEHICLE
Disclosed is a reactive filter, that is a selective catalytic reduction filter or an oxidative reaction filter, including a porous substrate including internal pores having their inner surface, totally or partially, directly coated with a catalytic zeolite material resulting from an in situ hydrothermal synthesis. Also disclosed is a process for preparing such a reactive filter and the use thereof in an engine exhaust depolluting system.
CATALYST AND METHOD OF PREPARING LIGHT OLEFIN DIRECTLY FROM SYNTHESIS GAS BY ONE-STEP PROCESS
The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C.sub.2-C.sub.4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C.sub.2.sup.?-C.sub.4.sup.?) is 50%-85%.
INTEGRATED PURIFICATION METHOD AND SYSTEM FOR THE INDUSTRIAL EXHAUST GAS CONTAINING CYANIDES, HYDROCARBONS AND NOx
An integrated purification method and an integrated purification system for an industrial exhaust gas containing cyanides, hydrocarbons and NO.sub.x. The method comprises the steps of: 1) subjecting the exhaust gas containing pollutants such as cyanides, hydrocarbons and nitrogen oxides (NO.sub.x) to a gas-liquid separation device (1) to separate the free fluid, then mixing with the air blown by the air blower (201, 202), and preheating by the heating unit; 2) the mixture entering into the selective catalytic combustion (SCC) reactor (5) for the selective catalytic combustion reaction to convert harmful substances into CO.sub.2, H.sub.2O and N.sub.2, the catalysis being performed in two stages: the earlier stage is catalyzed by supported molecular sieve catalyst, and the latter stage is catalyzed by supported precious metal catalyst; and 3) the gas came out from the SCC reactor (5) entering into the heating unit to recover the heat, and then the purified exhaust gas being discharged directly through the chimney (6). The system comprises a gas-liquid separation device (1), a heating unit and a selective catalytic combustion reactor (5), a gas outlet of the gas-liquid separation device (1) being connected to the selective catalytic combustion reactor (5) through the heating unit, and an exhaust gas outlet of the selective catalytic combustion reactor (5) being connected to a chimney (6) through the heating unit.
IN-SITU CRYSTALLIZED ULTRA-LOW ZEOLITE CONTENT FLUID CATALYTIC CRACKING CATALYST
Disclosed herein is a fluid catalytic cracking catalyst comprising an in-situ crystallized zeolite material and a matrix material. In at least one embodiment, the deactivated catalyst has a ratio of zeolite surface area to matrix surface area (Z/M) of less than about 1, and a unit cell size of at least about 24.3 .