Patent classifications
B01J2231/42
PC.SUB.NHC.P metal complexes and uses thereof
PC.sub.NHCP pincer metal complexes are useful as catalysts in various chemical reactions such as hydrogen isotope exchange (HIE) in C(sp.sup.3)-H and/or C(sp.sup.2)-H bond of an organic compound, e.g., a pharmaceutically active compound. The complexes are also useful in hydroboration of alkynes with excellent selectivity; and alkene isomerization with high stereo- and regioselectivity.
ORGANONICKEL INTERMEDIATES USEFUL FOR CARBOXYLATION OF SUBSTRATES WITH CARBON DIOXIDE
The present disclosure relates to a compound having the structure
##STR00001##
where R.sub.1 includes at least one of a methyl group, a halogen, a hydrogen, or a combination thereof, R.sub.2 includes at least one of a benzyl group, an ether, or a combination thereof, R.sub.3 includes at least one of hydrogen, a methyl group, or a combination thereof, and X includes a halogen.