B01J2523/14

CATALYST, METHOD FOR PRODUCING CATALYST, AND METHOD FOR PRODUCING ACRYLONITRILE

The present invention provides a catalyst comprising molybdenum, bismuth, and iron, wherein a reduction rate is in a range of 0.20 to 5.00%.

CATALYST, METHOD FOR PRODUCING CATALYST, AND METHOD FOR PRODUCING ACRYLONITRILE

The present invention provides a catalyst comprising molybdenum, bismuth, and iron, wherein a reduction rate is in a range of 0.20 to 5.00%.

METHOD FOR PRODUCING CATALYST FOR AMMOXIDATION, AND METHOD FOR PRODUCING ACRYLONITRILE

The present invention provides a method for producing a catalyst for ammoxidation, comprising steps of: preparing a catalyst precursor slurry comprising a liquid phase and a solid phase; drying the catalyst precursor slurry to obtain dry a particle; and calcining the dry particle to obtain a catalyst for ammoxidation, wherein the solid phase of the catalyst precursor slurry comprises an aggregate containing a metal and a carrier, metal primary particles constituting the aggregate have a particle size of 1 μm or smaller, and an average particle size of the metal primary particles is 40 nm or larger and 200 nm or smaller.

METHOD FOR PRODUCING CATALYST FOR AMMOXIDATION, AND METHOD FOR PRODUCING ACRYLONITRILE

The present invention provides a method for producing a catalyst for ammoxidation, comprising steps of: preparing a catalyst precursor slurry comprising a liquid phase and a solid phase; drying the catalyst precursor slurry to obtain dry a particle; and calcining the dry particle to obtain a catalyst for ammoxidation, wherein the solid phase of the catalyst precursor slurry comprises an aggregate containing a metal and a carrier, metal primary particles constituting the aggregate have a particle size of 1 μm or smaller, and an average particle size of the metal primary particles is 40 nm or larger and 200 nm or smaller.

Oxidative conversion of hydrocarbons using sulfur oxides as oxygen carriers
11104625 · 2021-08-31 · ·

The oxidative coupling of methane (OCM) and the oxidative dehydrogenation (ODH) of ethane and higher hydrocarbons is described using SO.sub.3 and sulfate, sulfite, bisulfite and metabifulfite salts as oxygen transfer agents in the presence of one or more elements selected from Groups 3 to 14 of the periodic table, optionally further in the presence of alkali or alkaline salts and/or sulfur-containing compounds.

METHOD FOR PRODUCING AT LEAST ONE OF UNSATURATED ALDEHYDE AND UNSATURATED CARBOXYLIC ACID AND CATALYST FOR PRODUCING AT LEAST ONE OF UNSATURATED ALDEHYDE AND UNSATURATED CARBOXYLIC ACID

Provided is a method for producing at least one of an unsaturated aldehyde and an unsaturated carboxylic acid from an alkene by an oxidation reaction, in which a n-layered catalyst layer (n≥2) is provided in a gas flow direction in a reaction tube, two or more kinds of catalysts having different activities are used; and the catalysts are packed in such a manner that dT≤20° C. is satisfied, when a difference between a temperature PT.sub.n of an exothermic peak in a n-th layer as counted from a gas inlet and a minimum value mT.sub.n-1 of a temperature of a catalyst layer which appears between an exothermic peak in a (n−1)th layer and an exothermic peak in a n-th layer from the gas inlet is represented as dT (=PT.sub.n−mT.sub.n-1), and the change rate of dT is 2.5 or less at a reaction bath temperature within a range of ±6° C. of a reaction bath temperature at which the highest yield is obtained.

METHOD FOR PRODUCING AT LEAST ONE OF UNSATURATED ALDEHYDE AND UNSATURATED CARBOXYLIC ACID AND CATALYST FOR PRODUCING AT LEAST ONE OF UNSATURATED ALDEHYDE AND UNSATURATED CARBOXYLIC ACID

Provided is a method for producing at least one of an unsaturated aldehyde and an unsaturated carboxylic acid from an alkene by an oxidation reaction, in which a n-layered catalyst layer (n≥2) is provided in a gas flow direction in a reaction tube, two or more kinds of catalysts having different activities are used; and the catalysts are packed in such a manner that dT≤20° C. is satisfied, when a difference between a temperature PT.sub.n of an exothermic peak in a n-th layer as counted from a gas inlet and a minimum value mT.sub.n-1 of a temperature of a catalyst layer which appears between an exothermic peak in a (n−1)th layer and an exothermic peak in a n-th layer from the gas inlet is represented as dT (=PT.sub.n−mT.sub.n-1), and the change rate of dT is 2.5 or less at a reaction bath temperature within a range of ±6° C. of a reaction bath temperature at which the highest yield is obtained.

METHOD FOR PRODUCING CATALYST AND METHOD FOR PRODUCING UNSATURATED NITRILE

A method for producing a catalyst, including a slurry preparation step of preparing a slurry comprising a Mo compound, an Fe compound, a Bi compound, and an additive having a decomposition temperature of 500° C. or less; a drying step of drying the slurry to obtain a dried material; and a calcination step of calcining the dried material to obtain a calcined material, wherein the calcination step comprises a step of raising temperature of a calcination atmosphere to a predetermined temperature, and a temperature raising rate is 10° C./min or less at least at a temperature equal to or lower than the decomposition temperature of the additive.

METHOD FOR PRODUCING CATALYST AND METHOD FOR PRODUCING UNSATURATED NITRILE

A method for producing a catalyst, including a slurry preparation step of preparing a slurry comprising a Mo compound, an Fe compound, a Bi compound, and an additive having a decomposition temperature of 500° C. or less; a drying step of drying the slurry to obtain a dried material; and a calcination step of calcining the dried material to obtain a calcined material, wherein the calcination step comprises a step of raising temperature of a calcination atmosphere to a predetermined temperature, and a temperature raising rate is 10° C./min or less at least at a temperature equal to or lower than the decomposition temperature of the additive.

A CATALYST FOR CONVERTING SYNTHESIS GAS TO ALCOHOLS

A catalyst for converting a synthesis gas, said catalyst comprising a first catalyst component and a second catalyst component, wherein the first catalyst component comprises, supported on a first porous oxidic substrate, Rh, Mn, an alkali metal M and Fe, and wherein the second catalyst component comprises, supported on a second porous oxidic support material, Cu and a transition metal other than Cu.