Provided is a novel exhaust gas purification catalyst, which uses a Cu-based delafossite oxide, capable of increasing the exhaust gas purification performance compared to the case of using the Cu-based delafossite oxide alone. Proposed is an exhaust gas purification catalyst comprising a delafossite-type oxide represented by a general formula ABO.sub.2 and an inorganic porous material, wherein Cu is contained in the A site of the general formula of the delafossite oxide, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are contained in the B site thereof, and Cu is contained in 3 to 30% relative to the total content (mass) of the delafossite-type oxide and the inorganic porous material.

Provided is a novel exhaust gas purification catalyst, which uses a Cu-based delafossite oxide, capable of increasing the exhaust gas purification performance compared to the case of using the Cu-based delafossite oxide alone. Proposed is an exhaust gas purification catalyst comprising a delafossite-type oxide represented by a general formula ABO.sub.2 and an inorganic porous material, wherein Cu is contained in the A site of the general formula of the delafossite oxide, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are contained in the B site thereof, and Cu is contained in 3 to 30% relative to the total content (mass) of the delafossite-type oxide and the inorganic porous material.

An oxidative coupling of methane (OCM) catalyst composition comprising one or more oxides doped with Ag; wherein one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof; and wherein one or more oxides is not La.sub.2O.sub.3 alone. A method of making an OCM catalyst composition comprising calcining one or more oxides and/or oxide precursors to form one or more calcined oxides, wherein the one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof, wherein the one or more oxides is not La.sub.2O.sub.3 alone, and wherein the oxide precursors comprise oxides, nitrates, carbonates, hydroxides, or combinations thereof; doping the one or more calcined oxides with Ag to form the OCM catalyst composition; and thermally treating the OCM catalyst composition.

An oxidative coupling of methane (OCM) catalyst composition comprising one or more oxides doped with Ag; wherein one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof; and wherein one or more oxides is not La.sub.2O.sub.3 alone. A method of making an OCM catalyst composition comprising calcining one or more oxides and/or oxide precursors to form one or more calcined oxides, wherein the one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof, wherein the one or more oxides is not La.sub.2O.sub.3 alone, and wherein the oxide precursors comprise oxides, nitrates, carbonates, hydroxides, or combinations thereof; doping the one or more calcined oxides with Ag to form the OCM catalyst composition; and thermally treating the OCM catalyst composition.

This disclosure provides for routes of synthesis of acrylic acid and other ,-unsaturated carboxylic acids and their salts, including catalytic methods. For example, there is provided a process for producing an ,-unsaturated carboxylic acid or a salt thereof, the process comprising: (1) contacting in any order, a group 8-11 transition metal precursor, an olefin, carbon dioxide, a diluent, and a metal-treated chemically-modified solid oxide such as a sulfur oxoacid anion-modified solid oxide, a phosphorus oxoacid anion-modified solid oxide, or a halide ion-modified solid oxide, to provide a reaction mixture; and (2) applying reaction conditions to the reaction mixture suitable to produce the ,-unsaturated carboxylic acid or the salt thereof. Methods of regenerating the metal-treated chemically-modified solid oxide are described.

Methods for preparing a catalyst system, include providing a catalytic substrate comprising a catalyst support having a surface with a plurality of metal catalytic nanoparticles bound thereto and physically mixing and/or electrostatically combining the catalytic substrate with a plurality of oxide coating nanoparticles to provide a coating of oxide coating nanoparticles on the surface of the catalytic nanoparticles. The metal catalytic nanoparticles can be one or more of ruthenium, rhodium, palladium, osmium, iridium, and platinum, rhenium, copper, silver, and gold. Physically combining can include combining via ball milling, blending, acoustic mixing, or theta composition, and the oxide coating nanoparticles can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, lanthanum, iron, strontium, and calcium. The catalyst support can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, iron, strontium, and calcium.

A plasmonic nanoparticle catalyst for producing hydrocarbon molecules by light irradiation, which comprises at least one plasmonic provider and at least one catalytic property provider, wherein the plasmonic provider and the catalytic property provider are in contact with each other or have distance less than 200 nm, and molecular composition of the hydrocarbon molecules produced by light irradiation is temperature-dependent. And a method for producing hydrocarbon molecules by light irradiation utilizing the plasmonic nanoparticle catalyst.

The invention relates to a device (10) for dispensing oxygen (30) under pressure. The device comprises a canister (12) filled with activated carbon (14) and oxygen (30) at a pressure of between 4 and 20 barg, when measured at room temperature. The canister is sealed with a valve assembly (18) allowing release of oxygen from the canister on actuation of the valve assembly. To ensure the activated carbon does not react with the oxygen generating carbon monoxide the device further comprises a catalyst (16) that prevents or significantly reduces the presence of carbon monoxide. In a further aspect there is a device (10) for dispensing a gas (30) under pressure which device comprises a canister (12) with a volume of 1 l or less filled with activated carbon (14) to adsorb the gas under a pressure of between 4 and 20 barg when measured at room temperature. The canister (12) is sealed with a valve assembly (18) crimped to the canister over a seal allowing release of the gas (30) from the canister on actuation of the valve assembly, wherein the gas is carbon dioxide, oxygen, nitrogen or air, and the canister is a steel canister. In a particularly favoured embodiment the device is filled with carbon dioxide and includes a high volume discharge valve making it useful as a pet behaviour correction device.

The invention relates to a device (10) for dispensing oxygen (30) under pressure. The device comprises a canister (12) filled with activated carbon (14) and oxygen (30) at a pressure of between 4 and 20 barg, when measured at room temperature. The canister is sealed with a valve assembly (18) allowing release of oxygen from the canister on actuation of the valve assembly. To ensure the activated carbon does not react with the oxygen generating carbon monoxide the device further comprises a catalyst (16) that prevents or significantly reduces the presence of carbon monoxide. In a further aspect there is a device (10) for dispensing a gas (30) under pressure which device comprises a canister (12) with a volume of 1 l or less filled with activated carbon (14) to adsorb the gas under a pressure of between 4 and 20 barg when measured at room temperature. The canister (12) is sealed with a valve assembly (18) crimped to the canister over a seal allowing release of the gas (30) from the canister on actuation of the valve assembly, wherein the gas is carbon dioxide, oxygen, nitrogen or air, and the canister is a steel canister. In a particularly favoured embodiment the device is filled with carbon dioxide and includes a high volume discharge valve making it useful as a pet behaviour correction device.

A photocatalyst, represented by the following general formula (1):
X(VO.sub.4).sub.6(OH).sub.2General Formula (1) wherein X represents Z.sub.a1Ti.sub.b1 or Z.sub.a2Ti.sub.b2Ag.sub.c2 (where Z is Ca or Sr; a1 is 7.0 to 9.5; b1 is 0.5 to 3.0; a2 is 7.0 to 9.5; b2 is 0.4 to 1.5; c2 is 0.1 to 2.0; a1+b1 is 9.0 to 10.0; and a2+b2+c2 is 9.0 to 10.0) in the general formula (1).