The present disclosure provides perovskite catalytic materials and catalysts comprising platinum-group metals and perovskites. These catalysts may be used as oxygen storage materials with automotive applications, such as three-way catalysts. They are also useful for water or CO.sub.2 reduction, or thermochemical energy storage.

This invention relates to a catalyst system comprising (a) at least one layer of a first catalyst comprising a dehydrogenation active metal on a solid support; (b) at least one layer of a second catalyst comprising a metal oxide; and (c) at least one layer of a third catalyst comprising a transition metal on an inorganic support; wherein the at least one layer of a second catalyst is sandwiched between the at least one layer of a first catalyst and the at least one layer of a third catalyst; and a process comprising contacting a hydrocarbon feed with the catalyst system.

A catalyst for oxidative coupling of methane, and preparation and application thereof. The catalyst comprises: a manganese sesquioxide, a tungstate, a manganese composite oxide having a perovskite structure and/or a spinel structure, and a carrier. The manganese sesquioxide, tungstate, and manganese composite oxide having a perovskite structure and/or a spinel structure are supported on the carrier, or the manganese sesquioxide and tungstate are supported on the admixture of the said manganese composite oxide having a perovskite structure and/or a spinel structure and the said carrier. Based on 100 parts by weight of the catalyst, the content of the manganese sesquioxide is a parts by weight, the content of the tungstate is b parts by weight, the content of the manganese composite oxide having the perovskite structure and/or the spinel structure is c parts by weight The content of the carrier is d parts by weight. 0<a≤20, 1≤b≤20, 1≤c≤40, 20≤d<98.

A catalyst for oxidative coupling of methane, and preparation and application thereof. The catalyst comprises: a manganese sesquioxide, a tungstate, a manganese composite oxide having a perovskite structure and/or a spinel structure, and a carrier. The manganese sesquioxide, tungstate, and manganese composite oxide having a perovskite structure and/or a spinel structure are supported on the carrier, or the manganese sesquioxide and tungstate are supported on the admixture of the said manganese composite oxide having a perovskite structure and/or a spinel structure and the said carrier. Based on 100 parts by weight of the catalyst, the content of the manganese sesquioxide is a parts by weight, the content of the tungstate is b parts by weight, the content of the manganese composite oxide having the perovskite structure and/or the spinel structure is c parts by weight The content of the carrier is d parts by weight. 0<a≤20, 1≤b≤20, 1≤c≤40, 20≤d<98.

Modified red mud catalyst compositions, methods for production, and methods of use in autothermal reforming, the composition comprising: red mud material produced from an alumina extraction process from bauxite ore; and nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition.

Modified red mud catalyst compositions, methods for production, and methods of use in autothermal reforming, the composition comprising: red mud material produced from an alumina extraction process from bauxite ore; and nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition.

Disclosed herein are processes, systems, and catalysts for improving pyrolysis technology. The disclosed processes and systems utilize a catalyst to increase pyrolysis gas (py-gas) and decrease bio-oil yields in pyrolysis reactions. The disclosed catalysts may include biochar derived from pyrolysis of industrial residuals, such as pyrolysis of wastewater biosolids (WB) and paper mill sludge (PMS). The disclosed catalysts also may include ash derived from incineration of wastewater biosolids (“biosolids incineration ash” (BIA)).

Disclosed herein are processes, systems, and catalysts for improving pyrolysis technology. The disclosed processes and systems utilize a catalyst to increase pyrolysis gas (py-gas) and decrease bio-oil yields in pyrolysis reactions. The disclosed catalysts may include biochar derived from pyrolysis of industrial residuals, such as pyrolysis of wastewater biosolids (WB) and paper mill sludge (PMS). The disclosed catalysts also may include ash derived from incineration of wastewater biosolids (“biosolids incineration ash” (BIA)).

A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.

A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.