B01J2523/25

METHANE UPGRADE TO ETHANE AND ETHYLENE WITHIN CERAMIC MEMBRANE REACTORS

A ceramic membrane for oxidative coupling of methane can include a perovskite oxide and catalyst material on a surface of the membrane.

Honeycomb-structured catalyst for organic substance decomposition and organic substance decomposing apparatus

A honeycomb-structured catalyst for decomposing an organic substance, which includes a catalyst particle. The catalyst particle contains a perovskite-type composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, where the A contains at least of Ba and Sr, the B contains Zr, the M is at least one of Mn, Co, Ni, and Fe, y+z=1, 1.001≤x≤1.05, 0.05≤z≤0.2, and w is a positive value that satisfies electrical neutrality. The toluene decomposition rate is greater than 90% when toluene is decomposed using the honeycomb-structured catalyst subjected to a heat treatment at 1200° C. for 48 hours and a gas that contains 50 ppm toluene, 80% nitrogen, and 20% oxygen as a volume concentration as a target at a space velocity of 30,000/h and a catalyst temperature of 400° C.

Honeycomb-structured catalyst for organic substance decomposition and organic substance decomposing apparatus

A honeycomb-structured catalyst for decomposing an organic substance, which includes a catalyst particle. The catalyst particle contains a perovskite-type composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, where the A contains at least of Ba and Sr, the B contains Zr, the M is at least one of Mn, Co, Ni, and Fe, y+z=1, 1.001≤x≤1.05, 0.05≤z≤0.2, and w is a positive value that satisfies electrical neutrality. The toluene decomposition rate is greater than 90% when toluene is decomposed using the honeycomb-structured catalyst subjected to a heat treatment at 1200° C. for 48 hours and a gas that contains 50 ppm toluene, 80% nitrogen, and 20% oxygen as a volume concentration as a target at a space velocity of 30,000/h and a catalyst temperature of 400° C.

EXHAUST GAS PURIFICATION CATALYST, METHOD OF PURIFYING EXHAUST GAS, AND METHOD OF MANUFACTURING EXHAUST GAS PURIFICATION CATALYST

In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.

EXHAUST GAS PURIFICATION CATALYST, METHOD OF PURIFYING EXHAUST GAS, AND METHOD OF MANUFACTURING EXHAUST GAS PURIFICATION CATALYST

In an exhaust gas purification catalyst, a catalytic component (100) containing a first oxide (21), a second oxide (22), and a precious metal (30) is supported on a three-dimensional structure (10); the ratio of the amount of precious metal (30) supported on the first oxide (21) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22), or the ratio of the amount of precious metal (30) supported on the second oxide (22) to the total amount of precious metal (30) supported on the first oxide (21) and precious metal (30) supported on the second oxide (22) is 70% or more to 100% or less, as measured by an electron probe microanalyzer (EPMA); and the amount of carbon monoxide that the precious metal (30) can adsorb per unit mass is 15 mL/g or more to 100 mL/g or less.

CATALYTICALLY ACTIVE PARTICLE FILTER WITH A HIGH DEGREE OF FILTRATION EFFICIENCY

The invention relates to a wall-flow filter as a particle filter with catalytically active coatings in the channels which are closed in a gas-tight manner at the opposing closed ends of the channels A at the first end, wherein the inlet region of the filter is additionally supplied with a dry powder-gas aerosol which contains metal compounds with a high melting point (such as the metal oxides Al203, Si02, Fe02, Ti02, Zn02, etc. for example) and which is to simultaneously improve the catalytic activity and the degree of filtration efficiency with respect to the exhaust gas back-pressure.

CATALYTICALLY ACTIVE PARTICLE FILTER WITH A HIGH DEGREE OF FILTRATION EFFICIENCY

The invention relates to a wall-flow filter as a particle filter with catalytically active coatings in the channels which are closed in a gas-tight manner at the opposing closed ends of the channels A at the first end, wherein the inlet region of the filter is additionally supplied with a dry powder-gas aerosol which contains metal compounds with a high melting point (such as the metal oxides Al203, Si02, Fe02, Ti02, Zn02, etc. for example) and which is to simultaneously improve the catalytic activity and the degree of filtration efficiency with respect to the exhaust gas back-pressure.

Molten salt catalytic compositions and methods for the cracking of carbon-containing feedstocks

A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.

Molten salt catalytic compositions and methods for the cracking of carbon-containing feedstocks

A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.

POROUS ALUMINA AND CATALYST

Porous alumina having excellent heat resistance and coking resistance is provided. The porous alumina can include silica and barium oxide added to aluminum oxide, wherein a ratio of SiO2 addition amount to a total mass of aluminum oxide and SiO2 addition amount is defined as SiO2 addition ratio (mass %), a ratio of BaO addition amount to a total mass of aluminum oxide and SiO2 addition amount is defined as BaO addition ratio (mass %), when the SiO2 addition ratio is within a range of 3 mass % or less and the BaO addition ratio is within a range of 14 mass % or less, the silica and the barium oxide are respectively added to the aluminum oxide so that a specific surface area of the porous alumina measured by a measuring method after heat treatment is equal to or larger than a reference specific surface area of reference porous alumina.