Patent classifications
B01J2523/42
CATALYST AND METHOD OF PREPARING LIGHT OLEFIN DIRECTLY FROM SYNTHESIS GAS BY ONE-STEP PROCESS
The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C.sub.2-C.sub.4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C.sub.2.sup.?-C.sub.4.sup.?) is 50%-85%.
CATALYST AND METHOD OF PREPARING LIGHT OLEFIN DIRECTLY FROM SYNTHESIS GAS BY ONE-STEP PROCESS
The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C.sub.2-C.sub.4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C.sub.2.sup.?-C.sub.4.sup.?) is 50%-85%.
Supported catalyst for production of unsaturated carboxylic acids from alkanes
The present disclosures and inventions relate to a supported catalyst composition for the catalytic oxidation of a hydrocarbon such as propane with oxygen or air, in the presence of a catalyst composition comprising a support material and a mixed metal composition comprising metals in the molar ratios described by the formula Mo.sub.aV.sub.bGa.sub.cPd.sub.dNb.sub.eZ.sub.f, wherein the support material is neutral or oxidative.
Supported catalyst for production of unsaturated carboxylic acids from alkanes
The present disclosures and inventions relate to a supported catalyst composition for the catalytic oxidation of a hydrocarbon such as propane with oxygen or air, in the presence of a catalyst composition comprising a support material and a mixed metal composition comprising metals in the molar ratios described by the formula Mo.sub.aV.sub.bGa.sub.cPd.sub.dNb.sub.eZ.sub.f, wherein the support material is neutral or oxidative.