Patent classifications
B01J2523/47
Honeycomb catalyst body
The honeycomb catalyst body is equipped with a honeycomb structure body having partition walls that define a plurality of cells extending from a first end face as one of the end faces to a second end face as the other end face and serving as through channels of a fluid. The partition walls each have a base layer containing from 50 to 90 mass % of zeolite and a coat layer with which the surface of the base layer 11 is coated with a thickness of from 1 to 50 μm. The coat layer is either a coat layer (A) containing from 1 to 5 mass % vanadia and titania or a coat layer (B) containing from 1 to 5 mass % vanadia and a composite oxide of titania and tungsten oxide.
Methods for making supported chromium catalysts with increased polymerization activity
Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650° C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.
Methods for making supported chromium catalysts with increased polymerization activity
Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650° C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.
Catalyst for oxidative coupling reaction of methane, method for preparing the same, and method for oxidative coupling reaction of methane using the same
Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.
Catalyst for oxidative coupling reaction of methane, method for preparing the same, and method for oxidative coupling reaction of methane using the same
Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.
SUPPORTED CATALYST USED FOR SYNTHESIZING POLYETHER AMINE, PREPARATION METHOD, AND APPLICATION
The present invention relates to a supported catalyst used for synthesizing polyether amine, a preparation method, and an application. The supported catalyst introduces Mo and CeO.sub.2 into Ni and Cu active components. By means of the cooperation of Ni, Cu and Mo, CeO.sub.2 and Ni form more active sites, such that the supported catalyst can have high reaction activity and selectivity. By using the supported catalyst to synthesize polyether amine, the amination efficiency and selectivity of polyether polyol can be greatly enhanced, thereby preparing the polyether amine with light color and narrow molecular weight distribution. In addition, the cost of the catalyst can be reduced, a process condition is relatively mild, and the disadvantage of low reaction activity of a nickel-based catalyst in synthesizing small molecule polyether amine can be overcome, such that the supported catalyst has a desirable industrial application prospect.
Method for preparation of oxide support-nanoparticle composites
There is provided a method for preparation of oxide support-nanoparticle composites, in which metal nanoparticles decorate with uniform size and distribution on the surface of an oxide support, and thus, high performance oxide support-nanoparticle composites that can be applied in the fields of heterogeneous catalysis can be provided.
Method for preparation of oxide support-nanoparticle composites
There is provided a method for preparation of oxide support-nanoparticle composites, in which metal nanoparticles decorate with uniform size and distribution on the surface of an oxide support, and thus, high performance oxide support-nanoparticle composites that can be applied in the fields of heterogeneous catalysis can be provided.
Selective catalytic reduction (SCR) catalyst comprising a composite oxide containing V and SB, preparation process thereof, and use thereof for nitrogen oxides removal
A catalyst composition comprising—a support comprising TiO.sub.2,—a composite oxide containing vanadium and antimony, which has a rutile-type structure different from VSbO.sub.4 and V.sub.0.92Sb.sub.0.92O.sub.4 as determined by X-ray diffraction (XRD) analysis with CuKα radiation, and—optionally, one or more selected from the group consisting of oxides of silicon, oxides of vanadium and oxides of antimony, for selective catalytic reduction of nitrogen oxides; to a process for preparing the catalyst composition, to the catalyst composition obtained/obtainable by the process and to use of the same for selective catalytic reduction of nitrogen oxides.
Selective catalytic reduction (SCR) catalyst comprising a composite oxide containing V and SB, preparation process thereof, and use thereof for nitrogen oxides removal
A catalyst composition comprising—a support comprising TiO.sub.2,—a composite oxide containing vanadium and antimony, which has a rutile-type structure different from VSbO.sub.4 and V.sub.0.92Sb.sub.0.92O.sub.4 as determined by X-ray diffraction (XRD) analysis with CuKα radiation, and—optionally, one or more selected from the group consisting of oxides of silicon, oxides of vanadium and oxides of antimony, for selective catalytic reduction of nitrogen oxides; to a process for preparing the catalyst composition, to the catalyst composition obtained/obtainable by the process and to use of the same for selective catalytic reduction of nitrogen oxides.