The present invention relates to a process for the preparation of catalyst(s), comprising the cokneading of boehmite with an active phase comprising a salt of heteropolyanion of Keggin and/or lacunary Keggin and/or substituted lacunary Keggin and/or Anderson and/or Strandberg type, and their mixtures, exhibiting, in its structure, molybdenum and cobalt and/or nickel. The present invention also relates to a process for the hydrotreating and/or hydroconversion of a heavy hydrocarbon feedstock in the presence of catalyst(s) prepared according to said process.

The present invention relates to a process for the preparation of catalyst(s), comprising the cokneading of boehmite with an active phase comprising a salt of heteropolyanion of Keggin and/or lacunary Keggin and/or substituted lacunary Keggin and/or Anderson and/or Strandberg type, and their mixtures, exhibiting, in its structure, molybdenum and cobalt and/or nickel. The present invention also relates to a process for the hydrotreating and/or hydroconversion of a heavy hydrocarbon feedstock in the presence of catalyst(s) prepared according to said process.

The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and an organic compound of formula (I) ##STR00001##
in which R1, R2, R3, R4 and R5 are selected from among a hydrogen atom, or a hydroxyl radical, or a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, and R6 is selected from a hydrogen atom, a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, a methacryloyl radical, an acryloyl radical or an acetyl radical. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.

The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and an organic compound of formula (I) ##STR00001##
in which R1, R2, R3, R4 and R5 are selected from among a hydrogen atom, or a hydroxyl radical, or a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, and R6 is selected from a hydrogen atom, a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, a methacryloyl radical, an acryloyl radical or an acetyl radical. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.

Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H.sub.2O.sub.2 in an amount equivalent to 0.30-2.8 mL H.sub.2O.sub.2 of a 30% solution per gram of catalyst precursor prior to calcining.

Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H.sub.2O.sub.2 in an amount equivalent to 0.30-2.8 mL H.sub.2O.sub.2 of a 30% solution per gram of catalyst precursor prior to calcining.

The present invention provides a production method of a 3-cyanopyrrole compound possibly useful as an intermediate for pharmaceutical products. A production method of compound (II) including subjecting compound (I) to a reduction reaction, in which the aforementioned reduction reaction is continuous hydrogenation reaction in a fixed bed reactor filled with a supported metal catalyst. A production method of compound (III) including subjecting compound (I) to a reduction reaction followed by a cyclization reaction, in which the aforementioned reduction reaction is continuous hydrogenation reaction in a fixed bed reactor filled with a supported metal catalyst. ##STR00001##

The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one group VIII element, at least one group VIB element and at least one organic compound of formula (I)

##STR00001##

in which R.sub.1 is a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, R.sub.2 and R.sub.3 are chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, X is chosen from an oxygen atom or a sulfur atom except when R.sub.2 and R.sub.3 represent a hydrogen atom, in which case X is an oxygen atom, Y is chosen from a hydrogen atom, a hydrocarbon-based radical comprising from 1 to 12 carbon atoms or a unit —C(O)R.sub.4, R.sub.4 being chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms.

The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one group VIII element, at least one group VIB element and at least one organic compound of formula (I)

##STR00001##

in which R.sub.1 is a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, R.sub.2 and R.sub.3 are chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, X is chosen from an oxygen atom or a sulfur atom except when R.sub.2 and R.sub.3 represent a hydrogen atom, in which case X is an oxygen atom, Y is chosen from a hydrogen atom, a hydrocarbon-based radical comprising from 1 to 12 carbon atoms or a unit —C(O)R.sub.4, R.sub.4 being chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms.

A system for continuously treating recycled polymeric material includes a hopper configured to feed the recycled polymeric material into the system. An extruder can turn the recycled polymeric material in a molten material. In some embodiments, the extruder uses thermal fluids, electric heaters, and/or a separate heater. The molten material is depolymerized in a reactor. In some embodiments, a catalyst is used to aid in depolymerizing the material. In certain embodiments, the catalyst is contained in a permeable container. The depolymerized molten material can then be cooled via a heat exchanger. In some embodiments, multiple reactors are used. In certain embodiments, these reactors are connected in series. In some embodiments, the reactor(s) contain removable static mixer(s) and/or removable annular inserts.