B01J2531/66

TRANSITION METAL TUNGSTEN OXY-HYDROXIDE
20170165656 · 2017-06-15 ·

A hydroprocessing catalyst has been developed. The catalyst is a unique transition metal tungsten oxy-hydroxide material. The hydroprocessing using the transition metal tungsten oxy-hydroxide material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS

In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I

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with a metathesis reaction partner according to Formula IIb

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in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb:

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and b) converting the metathesis product to the fatty olefin derivative. Each R.sup.1 is independently selected from H, C.sub.1-18 alkyl, and C.sub.2-18 alkenyl; R.sup.2b is C.sub.1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.

Z-SELECTIVE RING-CLOSING METATHESIS REACTIONS
20170129910 · 2017-05-11 ·

The present invention relates generally to olefin metathesis. In some embodiments, the present invention provides methods for Z-selective ring-closing metathesis.

Compounds having low ionization energy

The present invention provides compounds that are soluble in a non-polar solvent and having a low ionization energy and negative oxidation potentials in tetrahydrofuran (THF). The present invention also provides a method for producing and using the same.

Membrane-supported catalyst removal in the epoxidation of cyclic unsaturated C12 compounds, for example cyclododecene (CDEN)

A homogeneous catalyst system is removed from a reaction mixture of two liquid phases by separating the two liquid phases with a membrane having at least one separation-active layer in such a way that the homogeneous catalyst system is at least partially concentrated in a membrane retentate; wherein the reaction mixture contains at least one partially epoxidized cyclic unsaturated compound having twelve carbon atoms; and wherein the membrane separation-active layer contains crosslinked a silicone acrylate and/or polydimethylsiloxane and/or polyimide.

HIGHLY Z-SELECTIVE OLEFIN METATHESIS

The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

MEMBRANE-SUPPORTED CATALYST REMOVAL IN THE EPOXIDATION OF CYCLIC UNSATURATED C12 COMPOUNDS, FOR EXAMPLE CYCLODODECENE (CDEN)

An apparatus for the epoxidation of a cyclic unsaturated C.sub.12 compound with hydrogen peroxide is provided. The apparatus includes a reactor for carrying out the reaction, wherein the walls of the reactor are at least partially furnished with a separation-active layer of crosslinked silicone acrylates and/or polydimethylsiloxane.

Catalysts and methods for ring opening metathesis polymerization

The present invention, among other things, provides highly syndiotactic poly(dicyclopentadiene) and/or hydrogenated poly(dicyclopentadiene), compositions thereof, and compounds and methods for preparing the same. In some embodiments, a provided compound is a compound of formula I, II or III. In some embodiments, a provided method comprises providing a compound of formula I, II or III.

Transition metal based pro-catalyst and a process for its preparation

The present disclosure relates to a transition metal based pro-catalyst represented by Formula I: wherein, the substituents have the meaning as defined in the specification. The present disclosure also relates to a process for preparing the transition metal based pro-catalyst represented by Formula I and the catalyst composition obtained therefrom. Further, the present disclosure relates to a process for polymerizing olefins by employing the catalyst composition comprising the transition metal based pro-catalyst represented by Formula I. ##STR00001##

HYDROTREATING CATALYST, METHOD FOR PRODUCING THE CATALYST, AND HYDROTREATING PROCESS FOR HYDROCARBON OIL USING THE CATALYST

To provide a catalyst having hydrotreatment (hydrogenation, desulfurization and denitrification) performance that is equal to or superior to the prior art, as a hydrotreating catalyst for hydrocarbon oils, and a hydrotreating process for hydrocarbon oils using the catalyst. The catalyst comprises 10 to 40 mass % of at least one element of Group 6 of the Periodic Table, 0.5 to 15 mass % of at least one element of Groups 8 to 10 of the Periodic Table based on the oxide catalysts, and a 0.05- to 3-fold amount of an organic additive with respect to the total number of moles of the elements of Group 6 and Groups 8 to 10 of the Periodic Table, added to an inorganic porous support composed mainly of silica-alumina that comprises an oxide of a metal of Group 2 of the Periodic Table.