The disclosure is directed to a sample preparation apparatus for grinding or homogenizing test samples. More specifically, the disclosure relates to grinding samples using rotational and linear motion. Grinding samples can be accomplished with an apparatus with a slider-crank mechanism that is attached to an oscillating connecting linkage. The amplitude of oscillatory motion can be greater than or equal to a length of a sample processing chamber.

The disclosure is directed to a sample preparation apparatus for grinding or homogenizing test samples. More specifically, the disclosure relates to grinding samples using rotational and linear motion. Grinding samples can be accomplished with an apparatus with a slider-crank mechanism that is attached to an oscillating connecting linkage. The amplitude of oscillatory motion can be greater than or equal to a length of a sample processing chamber.

An arrangement and method for detaching an adhering charge from an inner wall of a grinding tube, wherein the grinding tube is rotated backwards in a drive-free manner from a pre-determinable, assumed rotary position by the weight force of the adhering charge, where at least one movement state variable of the grinding tube is detected and the grinding tube is braked while being rotated back in dependence on the at least one detected movement state variable in order to detach the adhering charge from the inner wall of the grinding tube, and where the arrangement includes a detecting device, a drive unit, a braking device and a control device.

An arrangement and method for detaching an adhering charge from an inner wall of a grinding tube, wherein the grinding tube is rotated backwards in a drive-free manner from a pre-determinable, assumed rotary position by the weight force of the adhering charge, where at least one movement state variable of the grinding tube is detected and the grinding tube is braked while being rotated back in dependence on the at least one detected movement state variable in order to detach the adhering charge from the inner wall of the grinding tube, and where the arrangement includes a detecting device, a drive unit, a braking device and a control device.

A rock crushing assembly is provided in the form of a pulverizing tumbler. The apparatus includes a faceted tumbler having a plurality of faceted end walls, a pair of parallel sidewalls, and an open interior. A power source and a drivetrain assembly attach to the sidewalls of the tumbler and rotate the same. Within the tumbler is adapted to be placed rocks and minerals to be pulverized, wherein pulverizing media is placed in the tumbler with the rocks to break down the rocks into fine, granular material. One of the end walls of the tumbler is removable to allow access to the tumbler interior. One or more gaps or apertures through one or more of the end walls allow the pulverized material to exit the tumbler during operation, thereby reducing build-up of loose material that can dampen impacts within the tumbler.

A rock crushing assembly is provided in the form of a pulverizing tumbler. The apparatus includes a faceted tumbler having a plurality of faceted end walls, a pair of parallel sidewalls, and an open interior. A power source and a drivetrain assembly attach to the sidewalls of the tumbler and rotate the same. Within the tumbler is adapted to be placed rocks and minerals to be pulverized, wherein pulverizing media is placed in the tumbler with the rocks to break down the rocks into fine, granular material. One of the end walls of the tumbler is removable to allow access to the tumbler interior. One or more gaps or apertures through one or more of the end walls allow the pulverized material to exit the tumbler during operation, thereby reducing build-up of loose material that can dampen impacts within the tumbler.

Embodiments of the present disclosure are directed to hydrogen-selective oxygen carrier materials and methods of using hydrogen-selective oxygen carrier materials. The hydrogen-selective oxygen carrier material may comprise a core material, which includes a redox-active transition metal oxide; a shell material, which includes one or more alkali transition metal oxides; and a support material. The shell material may be in direct contact with at least a majority of an outer surface of the core material. At least a portion of the core material may be in direct contact with the support material. The hydrogen-selective oxygen carrier material may be selective to combust hydrogen in an environment that includes hydrogen and hydrocarbons.

Embodiments of the present disclosure are directed to hydrogen-selective oxygen carrier materials and methods of using hydrogen-selective oxygen carrier materials. The hydrogen-selective oxygen carrier material may comprise a core material, which includes a redox-active transition metal oxide; a shell material, which includes one or more alkali transition metal oxides; and a support material. The shell material may be in direct contact with at least a majority of an outer surface of the core material. At least a portion of the core material may be in direct contact with the support material. The hydrogen-selective oxygen carrier material may be selective to combust hydrogen in an environment that includes hydrogen and hydrocarbons.

Disclosed herein are devices, apparatuses, and methods for grinding of samples. A method includes securing a sample vial in a holder attached to a connecting linkage, the sample vial having a grinding media in the sample vial. The method includes rotating a crank that is operatively coupled to a proximal end of the connecting linkage at a proximal pivot point so that the proximal pivot point undergoes rotational motion. The method includes restricting a distal pivot point of the connecting linkage to a linear path, the distal pivot point near a distal end of the connecting linkage. A result being that the sample vial undergoes a combination of rotational and linear motion.

Disclosed herein are devices, apparatuses, and methods for generating a reciprocating motion for the purpose of grinding or homogenizing samples. An apparatus includes a connecting linkage that extends along a longitudinal axis. The apparatus includes a sample vial holder attached to the connecting linkage. The apparatus includes a crank operatively connected to the proximal end of the connecting linkage, the crank configured to impart rotational motion to the proximal end of the connecting linkage. The apparatus includes a sliding carriage operatively connected to the distal end of the connecting linkage, the sliding carriage configured to restrict the distal end of the connecting linkage to a linear path. The apparatus includes a motor operatively connected to the crank to rotate the crank such that the sample vial holder, in use, moves with a combination of rotational and linear motion.