Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula R.sub.A—NH—C(O)—N(R.sup.4)—R.sup.11—[O—C(O)NH—R.sub.S].sub.n, or R.sub.S—NH—C(O)—N(R.sup.4)—R.sup.11—[O—C(O)NH—R.sub.A].sub.n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.

Compositions and methods for producing smoke suppressants are disclosed. The smoke suppressant molecularly encapsulates a naturally-occurring inorganic substrate, such as expanded volcanic ash. These intercalated smoke suppressant compositions have particular utility for smoke suppression in polyvinyl chloride (PVC), both flexible and rigid compounds as well as other polymeric resins and materials.

The present disclosure provides fluid barriers as well as systems and methods of forming fluid barriers. The method includes cleaning, via a blast media, a first side of a component and heating the component to a first temperature. Subsequently, the component is cleaned using a solvent. Subsequent to heating at least the component, a primer coating layer is formed on the first side of the component, and a topcoat layer is formed in contact with the primer coating layer. A primer coating material can be heated to a second temperature prior to formation of the primer coating layer. The first temperature can be different than the second temperature.

Systems and methods relate to applying a coating to a substrate. Coatings can be generated using layer-by-layer application techniques. Typically, application of a first aqueous solution is alternated with application of a second aqueous solution. Example first aqueous solutions include polyethyleneimine (PEI) and hydroxy-terminated poly(dimethylsiloxane) (PDMS-OH). Example second aqueous solutions include silicate and PDMS-OH. In some instances, first aqueous solutions and/or second aqueous solutions additionally include methyl-terminated PDMS (PDMS-CH.sub.3).

A graded-index optical element may include a nanovoided material including a first surface and a second surface opposite the first surface. The nanovoided material may be transparent between the first surface and the second surface. Additionally, the nanovoided material may have a predefined change in effective refractive index in at least one axis due to a change in at least one of nanovoid size or nanovoid distribution along the at least one axis. Various other elements, devices, systems, materials, and methods are also disclosed.

A nanovoided polymer-based material may include a bulk polymer material defining a plurality of nanovoids and an interfacial film disposed at an interface between each of the plurality of nanovoids and the bulk polymer material. The interfacial film may include one or more layers of material. A method of forming a nanovoided polymer-based material may include (1) forming a bulk polymer material defining a plurality of nanovoids and (2) forming an interfacial film at an interface between each of the plurality of nanovoids and the bulk polymer material. Various other methods, systems, and materials are also disclosed.

The invention particularly relates to a method of applying a permanent coating to a plastic surface of a first part, comprising the following steps: applying to said plastic surface a layer of a polyamide-based hot-melt material, maintaining this layer of hot-melt material on said plastic surface for a period of time ranging from a few minutes to several hours, removing this layer of hot-melt material from this plastic surface; and applying a permanent coating to said surface, said permanent coating being based on polyurethane, an epoxy resin or polyesters, a polycarbonate and/or an acrylic resin; as well as the use of such a method in the automotive industry.

Provided is a method for coating an implant using heat, and more particularly to a method for coating only the surface of an implant with a biocompatible polymer by using heat while maintaining physical characteristics of the implant.

The method for coating an implant using heat according to the present invention may effectively introduce a biocompatible polymer onto a three-dimensional material surface and thus may overcome the spatial limitations of light, and enables mass-coating and thus may be effectively used in the manufacture of an implant coated with a biocompatible polymer.

In some examples, a method includes forming a material layer on a substrate, partially polymerizing a component of the material layer, to form fluid-filled droplets within a partially polymerized matrix, deforming the material layer to form anisotropic fluid-filled droplets, and further polymerizing the partially polymerized matrix to form an anisotropic voided polymer, including anisotropic voids in a polymer matrix. The anisotropic voids may include anisotropic nanovoids. Example methods may further include depositing electrodes on the anisotropic voided polymer so that at least a portion of the anisotropic voided polymer is located between the electrodes. Examples may include forming electroactive elements including an anisotropic nanovoided polymer, and devices (such as sensors and/or actuators) including electroactive elements.

In some examples, a device includes a multilayer structure, a first electrode, and a second electrode, where the multilayer structure is located at least in part between the first electrode and the second electrode, and the multilayer structure includes a nanovoided polymer layer, and a solid layer. The solid layer may include a non-nanovoided layer. The nanovoided polymer layer may be an electroactive layer. The device may further include a control circuit configured to apply an electrical potential between the first electrode and the second electrode, which may induce a mechanical deformation of the multilayer.