A modified technology of spin coating which is named Two-Axis spin coating is disclosed. The innovative Two-Axis spin coating apparatus is a rotary device that spins the substrate horizontally the same as conventional spin coaters while the whole horizontal spinning system can be rotated vertically. The vertical rotation of the substrate generates a vertical centrifugal force perpendicular to the surface of the substrate which allows the coating face with an elevated artificial gravity acceleration. The elevation of gravity acceleration adjusts and normalizes the local high and low surface tension stresses on the surface of the coated film. This elevation of gravity also increases the weight of coating elements artificially and obliges the wavy surface convex regions to flow toward the concave areas. The elevation of gravity also obliges the lighter probable air bubbles inside the layer, immediately before the coating surface skinning process, move toward the surface and drain out from the layer. The invention provides a method to level the layer's edge beads, level the coated surface, drain out probable micro sized air bubbles inside the layer and form denser film simultaneously.

The invention relates to a decorative panel, comprising at least one substrate comprising an upper surface and a bottom surface and two pairs of opposing side edges, wherein the substrate comprises at least one core layer and at least one decorative layer and the panel comprising at least one coating layer, wherein the coating layer is provided upon the upper surface of the substrate, wherein both the upper surface of the substrate and the upper coating surface of the coating layer have a predetermined Shore D hardness.

Gloss of a surface having a concave-convex structure is measured, and R/V, which is a ratio of a diffuse specular reflection intensity R to a sum total V of diffuse reflection intensities (in formula, the diffuse specular reflection intensity R represents a diffuse reflection intensity measured at an aperture angle of 1 degree by a variable-angle photometer in a diffuse specular reflection direction when visible light is radiated, at an angle of 45 degrees from a normal line, to the surface having the concave-convex structure of the anti-glare film, and the sum total V of diffuse reflection intensities represents a sum total of diffuse reflection intensities measured at an aperture angle of 1 degree by a variable-angle photometer for every 1 degree from −45 degrees up to 45 degrees, including 0 degrees, with respect to the diffuse specular reflection direction when visible light is radiated, at an angle of 45 degrees from a normal line, to the surface having the concave-convex structure of the anti-glare film), is evaluated to manufacture an anti-glare film. The above-described method enables an anti-glare film having high anti-glare properties and high contrast to be manufactured at high productivity.

An optical device includes a substrate, a surface-relief grating including grooves and ridges formed on or in the substrate, and an overcoat layer in the grooves of the surface-relief grating. The ridges of the surface-relief grating or the overcoat layer includes a plurality of clusters of metal oxide (e.g., TiO.sub.2 or NbO.sub.x) nanoparticles. Each cluster of the plurality of clusters of metal oxide nanoparticles includes metal oxide nanoparticles dispersed in an inorganic barrier that isolates the metal oxide nanoparticles from other materials of the optical device. The ridges of the surface-relief grating or the overcoat layer is made of a resin material that includes a resin with inorganic content, and/or TiO.sub.x or NbO.sub.x nanoparticles including inorganic-containing ligands. A high-energy treatment process can remove organics surrounding the metal oxide nanoparticles and form the barrier layers that surround clusters of metal oxide nanoparticles.

A main object of the present disclosure is to provide a decorative sheet including a barrier layer having excellent solid fragrance resistance and close adhesiveness. The present disclosure achieves the object by providing a decorative sheet comprising at least a substrate sheet, a barrier layer, and a surface protecting layer in this order, wherein the barrier layer includes a vinyl alcohol based resin, and a polyurethane resin.

Provided is a method for decorating a kitchen item by means of mechanical treatment in order to produce a decoration. The mechanical treatment involves removing and/or displacing part of a thermostable decorative composition by means of pressure and moving a tool or a compressed air jet over the surface of the decorative layer.

Disclosed is a multi-layer body with high weathering resistance comprising (a) a substrate layer containing at least one thermoplastic polymer (b) one cover layer on at least one side of the substrate layer, characterized in that the substrate layer further contains: (a1) at 0.02 wt. % to 0.2 wt %, at least one colorant on the basis of anthraquinone of structure (1) or (2) with structure (1), R1 and R2 standing, independently of each other, for H, OH, OR5 NH2 and NHR5, R5 being selected from alkyl, cycloalkyl, phenyl and substituted and annulated phenyls, and R3 standing for H, alkyl, alkoxy, and R4 standing for H, OH and p-methylphenyl-NH—; and with structure (2): (a2) at 0.01 wt % to 1.00 wt. %, one or a plurality of demolders, and the cover layer consisting of a coating on the basis of polysiloxane or on the basis of polyacrylate or on the basis of polyurethane acrylate, containing at least one UV-absorber and having a layer thickness of 2-15 [mu]m.

A method is provided for manufacturing a panel. of the method may involve supplying a substrate having an upper side. A layer may be provided onto the upper side. The upper side may be irradiated so as to cure at least a part of the layer by irradiation, hence forming the panel. The layer may include a liquid coating on substantially the entire upper side and a substance which is digitally printed locally on the upper side. The substance and the liquid coating may cooperate such that either (1) the coating and the substance react with each other, whereas the substance is a liquid that is printed on the upper side before the coating is applied and wherein the substance and the coating have different surface tensions, or (2) the coating is non-curable or only curable to a limited extent by the irradiation, whereas the substance makes the coating curable by the irradiation at locations where they meet each other.

The invention relates to a method of making hybrid organic-inorganic core-shell nano-particles, comprising the steps of a) providing colloidal organic particles comprising a synthetic polyampholyte as a template; b) adding at least one inorganic oxide precursor; and c) forming a shell layer from the precursor on the template to result in core-shell nano-particles. With this method it is possible to make colloidal organic template particles having an average particle size in the range of 10 to 300 nm; which size can be controlled by the comonomer composition of the polyampholyte, and/or by selecting dispersion conditions.

The invention also relates to organic-inorganic or hollow-inorganic core-shell nano-particles obtained with this method, to compositions comprising such nano-particles, to different uses of said nano-particles and compositions, and to products comprising or made from said nano-particles and compositions, including anti-reflective coatings and composite materials.

Method for producing a decorative molded part, in which a veneer is joined to a substrate on its rear side opposite a visible surface of the veneer, and in which the visible surface of the veneer is bleached differently to produce a bleaching pattern.