A liquid repellent composition which can provide an article with good alcohol repellency is provided. A liquid repellent composition comprising a fluorinated polymer and an aqueous medium, wherein the fluorinated polymer comprises units based on a monomer a, units based on a monomer b and units based on a monomer c. Monomer a: a compound represented by CH.sub.2═CH—R.sup.f (wherein R.sup.f is a C.sub.1-8 perfluoroalkyl group). Monomer b: a fluorine-free nonionic surfactant having a polymerizable carbon-carbon double bond. Monomer c: another monomer copolymerizable with the monomer a and the monomer b.

A uniform oleophobic or oleo- and hydrophobic film is applied to equipment used in the petroleum industry. The methods can be applied to new equipment or equipment pulled from service, with the application process being performed in a controlled environment or the field. Applicator tools for efficient delivery and application of cleaners, solvents, and films used in the coating process are also described.

A fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer and a method for producing it are provided. The fluorinated ether compound is represented by A-O—(R.sup.f1O).sub.m-Q.sup.1(R.sup.1).sub.b, wherein A is a C.sub.1-20, perfluoroalkyl group, R.sup.f1 is a perfluoroalkylene group, m is an integer of from 2 to 500, (R.sup.f1O).sub.m a n d may consist of two or more types of R.sup.f1O differing in the number of carbon atoms, Q.sup.1 is a (b+1) valent perfluorohydrocarbon group which may have a hydroxy group, R.sup.1 is a monovalent organic group having at least one hydrolyzable silyl group, b is an integer of at least 2, and the b R.sup.1 may be the same or different.

Methods and apparatus for preparing a protective coating are described. In one example aspect, an apparatus for preparing a protective coating includes a chamber, a substrate positioned within the chamber configured to hold at least a target object, an inlet pipe configured to direct a monomer vapor into the chamber, and one or more electrodes configured to perform a chemical vapor deposition process to produce a multi-layer coating. The chemical vapor deposition process comprises multiple cycles, each cycle comprising a pretreatment phase and a coating phase to produce a layer of the multi-layer coating.

Examples of a susceptor for supporting a substrate includes a base metal formed of aluminum or a material containing aluminum, an anodized layer covering a surface of the base metal and having cracks therein, and a CF coating of polymer provided in the cracks such that the exposure of the base metal is avoided.

A method for rendering material surfaces inert is provided. Exemplary surfaces include ceramic, metal or plastic surfaces. The method is accomplished with functionalized perfluorinated compounds for the formation of hyperhydrophobic structures on the surfaces to create inert surfaces. The inert surfaces produced or can be produced in this way have an extremely low surface energy, are resistant to deposits of substances or cells and have a very low coefficient of friction. Practical uses of the inert surfaces are also provided.

Systems, methods, and compositions for producing liquid repellant materials include a first support configured to support a spool of flexible substrate, a second support configured to support a plurality of compressing rollers configured to apply a force to a segment of the flexible substrate that extends from the roll. The segment is located within a zone between the compressing rollers. The system, in an embodiment, has a plurality of gas directors, wherein each one of the gas directors is configured to direct a stream of gas that flows at least partially around one of the compressing rollers. The streams cause an air pressure reduction in the zone. Also, the system has a precursor supply configured to expose the substrate to a precursor (e.g., a siloxane precursor), resulting in a coated material or protected material.

A method of manufacturing a dew formation preventing member having a super water repellent surface of the present invention comprises the steps of: mixing a particular paint and polytetrafluorethylene at a predetermined ratio; particulate painting the mixed paint on a substrate surface; and heat treating the particulate painted substrate. A method of manufacturing a dew formation preventing member having a super water repellent surface according to another aspect of the present invention comprises the steps of: immersing a substrate in an electro deposition paint, and applying a direct current to conduct electro deposition painting; heat treating the substrate that has undergone the electro deposition painting; and plasma treating the surface of the substrate that has undergone the electro deposition painting.

Methods and apparatus for preparing a protective coating are described. In one example aspect, a method for preparing a protective coating includes positioning one or more target objects into a chamber. The chamber comprises a movable substrate and one or more trays coupled to the movable substrate to hold the one or more target objects such that the one or more target objects are movable within the chamber. The method also includes adding a monomer vapor into the chamber and performing a chemical vapor deposition process that comprises at least one cycle, each including a pretreatment phase and a coating phase.

Described herein are articles and methods of making articles, for example glass articles, including a sheet and a carrier, wherein the sheet and carrier are bonded together using a coating layer, which is, for example, a fluorocarbon polymer coating layer, and associated deposition methods and inert gas treatments that may be applied on the sheet, the carrier, or both, to control the fluorine content of the coating layer and van der Waals, hydrogen and covalent bonding between the sheet and the carrier. The coating layer bonds the sheet and carrier together with sufficient bond strength to prevent delamination of the sheet and the carrier during high temperature processing to while preventing a permanent bond at during high temperature processing while at the same time maintaining a sufficient bond to prevent delamination during high temperature processing.