Curable compositions comprising 1,1-di-activated vinyl compounds are provided herein. Also provided are coatings formed from 1,1-di-activated vinyl compounds. Also provided are processes for coating substrates and articles. Curable compositions including 1,1-di-activated vinyl compounds that function as crosslinking agents are described.

Provided are a flexible tube for an endoscope, the flexible tube having a flexible tube base made of metal, a resin cover layer that covers an outer periphery of the flexible tube base, and a primer layer that includes at least one compound represented by general formula (1) or (2) and that is disposed between the flexible tube base and the resin cover layer, in which the resin cover layer includes at least one selected from the group consisting of polyamides, polyesters, polyurethanes, and polyolefins on a side of the resin cover layer in contact with the primer layer, an endoscopic medical device including the flexible tube for an endoscope; a method for producing the flexible tube for an endoscope; and a method for producing the endoscopic medical device.

R.sup.1.sub.m-M-(OR.sup.2).sub.n-m  General formula (1):

O-[M-(OR.sup.2).sub.n-1].sub.2  General formula (2): M represents, for example, Al, Ti, or Zr. R.sup.1 and R.sup.2 each represent a hydrogen atom or a specific group. m is an integer of 0 to 3, n is a valence of M, and n>m is satisfied.

The present invention relates to a method of activating an organic coating to enhance adhesion of the coating to a further coating and/or to other entities comprising applying a solvent and a surface chemistry and/or surface topography modifying agent to the organic coating.

The invention also relates to a coated substrate having an activated coating, wherein the adhesion of the coating to a further coating and/or other entities has been enhanced by application of a solvent and a surface chemistry and/or surface topography modifying agent to the coating.

The invention further relates to an activation treatment for an organic coating to enhance adhesion of the coating to a further coating and/or to other entities comprising a solvent and a surface chemistry and/or surface topography modifying agent and a method for the preparation of the activation treatment.

In a three-dimensional printing method example, a pre-treatment coating is formed on a part precursor by applying and drying, alternatingly: a polycation solution including a chloride ion and a polyanion solution including a sodium ion to form at least two layers. An ink is selectively deposited on the pre-treatment coating.

The disclosure relates to omniphobic coatings, related articles including such coatings, and related method for forming such coatings or articles, for example biobased and/or biodegradable omniphobic coatings. The omniphobic coating includes a reaction product between an amino-functional polymer and an amino-reactive functionalized omniphobic polymer having a glass transition temperature (T.sub.g) of 60° C. or less. The omniphobic coating has a weight ratio of amino-functional polymer relative to functionalized omniphobic polymer of at least 1 or 2. A corresponding omniphobic coated article can include the omniphobic coating on a porous substrate such as a cellulosic or paper substrate, for example to provide a water- and oil/fat/grease-resistant coating for a paper-based product. The omniphobic coating can be formed in a reaction medium before being applied to the substrate, or the omniphobic coating can be formed on the substrate with serial application of the amino-reactive functionalized omniphobic polymer and the amino-functional polymer thereon. This disclosure provides a closed loop circular economy approach for fluorine-free, water- and grease-resistant paper as the coating can be easily separated from the pulp/fiber of the paper. The recycled pulp can be used for paper making, while the separated coating in micelle form can be used for recoating.

A composite flock material including a base layer comprising a hot melt adhesive, an elastic adhesive layer disposed on a top surface of the hot melt adhesive, and a plurality of flock fibers potted into the elastic adhesive layer is disclosed. The composite flock material is stretchable up to 20% from an initial unstretched length while maintaining the structural integrity of the composite flock material. Methods of producing a composite flock material are also disclosed.

A method for applying a multi-layer coating includes passing a substrate through a nip defined by two rolls to apply a first thickness of a first liquid coating material, applying a second liquid coating material on the first liquid coating material having the first thickness as applied by passing through the nip, and controlling a thickness of the applied second liquid coating material.

The elastomeric electrode includes: a stretchable substrate 10 having wrinkles formed on one surface thereof, the peaks C and valleys T of the wrinkles being repeated; a wrinkled metal nanoparticle layer 20 including metal nanoparticles 21 and formed by deposition of the metal nanoparticles along the wrinkles of the substrate 10; and a wrinkled monomolecular layer 30 including a monomolecular material having one or more amine groups (—NH.sub.2) and formed by deposition of the monomolecular material onto the metal nanoparticle layer 20. Also disclosed is a method for preparing the elastomeric electrode.

To provide a composite laminate having excellent adhesiveness to a resin material imparted to a metal base material, such as an aluminum, and a method for producing the same, and a metal-resin bonded article using the composite laminate and a method for producing the same. A composite laminate 1 includes a metal base material 2 and one layer or plural layers of a resin coating layer 4 laminated on the metal base material 2, the resin coating layer 4 is laminated on a surface-treated surface of the metal base material 2, and at least one layer of the resin coating layer 4 is formed of a resin composition containing an in situ polymerizable phenoxy resin.

Introduced here is a plasma polymerization apparatus and process. Example embodiments include a vacuum chamber in a substantially symmetrical shape to a central axis. A rotation rack may be operable to rotate about the central axis of the vacuum chamber. Additionally, reactive species discharge mechanisms positioned around a perimeter of the vacuum chamber in a substantially symmetrical manner from the outer perimeter of the vacuum chamber may be configured to disperse reactive species into the vacuum chamber. The reactive species may form a polymeric multi-layer coating on surfaces of the one or more devices. Each layer may have a different composition of atoms to enhance the water resistance, corrosion resistance, and fiction resistance of the polymeric multi-layer coating.