A radiation-curable composition includes at least one monofunctional monomer and/or at least one multifunctional monomer, at least one photoinitiator compound, and at least one matting agent, wherein the at least one matting agent is at least one aminoplast resin. Methods of producing the radiation-curable composition, methods of coating a substrate with the radiation-curable composition, and substrates coated with the radiation-cured composition are also disclosed.

The present disclosure relates to multi-layered elastomer-based liners. In at least one embodiment, a coated substrate includes a substrate and a first elastomer coating disposed on the substrate. The first elastomer coating is substantially free of sulfur and includes a first elastomer selected from the group consisting of a polyurea, a polyurethane, a polyurea-polyurethane copolymer, and combinations thereof. The coated substrate includes a second elastomer coating disposed on the first coating. The second elastomer coating includes a second elastomer selected from the group consisting of a polyurea, a polyurethane, a polyurea-polyurethane copolymer, and combinations thereof. The first elastomer is the same as or different than the second elastomer and at least one of the first elastomer or the second elastomer is a polyurea-polyurethane copolymer.

A resin composition includes a polymer resin, a fluoride resin, and a radical polymerization initiator, where the polymer resin includes at least one selected from an epoxy siloxane-based compound, a (meth)acrylate monomer, and a tetrahydrofurfuryl acrylic acid.

A liquid repellent composition which can provide an article with good alcohol repellency is provided. A liquid repellent composition comprising a fluorinated polymer and an aqueous medium, wherein the fluorinated polymer comprises units based on a monomer a, units based on a monomer b and units based on a monomer c. Monomer a: a compound represented by CH.sub.2CHR.sup.f (wherein R.sup.f is a C.sub.1-8 perfluoroalkyl group). Monomer b: a fluorine-free nonionic surfactant having a polymerizable carbon-carbon double bond. Monomer c: another monomer copolymerizable with the monomer a and the monomer b.

The present invention relates to a process for producing a coating from an aqueous, radiation-curable coating composition, wherein the process comprises the steps in the sequence (1) to (4): (1) applying an aqueous, radiation-curable coating composition on a surface of a substrate, (2) drying the aqueous, radiation-curable coating composition, affording an at least partially dried coating composition, (3) irradiating the at least partially dried coating composition with UV light having a wavelength s 220 nm under inert atmosphere, followed by (4) irradiating with UV light having a wavelength 300 nm or with E-beam, wherein the aqueous, radiation-curable coating composition is a dispersion comprising: (A) at least one water-dispersible polyurethane (A), wherein the polyurethane (A) has a urea group (NHCONH) concentration of at least 0.1 milli-equivalents per g of polyurethane (A) and of at most 2.6 milli-equivalents per g of polyurethane (A) and the polyurethane (A) is essentially free of radiation-curable, ethylenically unsaturated bonds, (B) at least one radiation-curable diluent (B) with a molar mass less than 750 g/mol and with an acrylate functionality of from 2 to 5, and (C) water and optionally organic solvent, whereby the optional organic solvent is present in an amount of at most 30 wt. %, based on the total amount of water and organic solvent, wherein the amount of (A) is from 30 to 85 wt. % and the amount of (B) is from 15 to 70 wt. %, based on the total amount of (A) and (B).

The present disclosure provides novel polymerizable compositions that can produce coating layers on polymeric materials thereby imparting excellent stain resistance. Further provided herein are methods of producing polymerizable coatings, coated devices, and coated polymeric materials. Also provided herein are methods of using polymer coated materials, and coated polymeric materials fabricated via additive manufacturing processes (e.g., via 3D printing), such as orthodontic appliances with increased stain resistance.

Methods for applying a polymeric coating to a substrate are provided comprising: (a) generating reactive functional groups on the polymeric substrate; (b) contacting the substrate with a radical polymerization initiator; (c) allowing the polymerization initiator to be chemically bonded to the substrate by reaction of the polymerization initiator with the reactive functional groups on the substrate; (d) contacting the polymerization initiator that is chemically bonded to the substrate with a monomer composition comprising a free-radical polymerizable monomer having at least one hydrophilic functional group; (e) forming a polymeric coating layer on the substrate via a radical polymerization process; and optionally (f) subjecting the polymeric coating layer on the substrate to conditions to effect curing of reactive functional groups on the polymers of the polymeric coating layer. The monomer composition may comprise at least 10 percent by weight of a (meth)acrylamide monomer having at least one ionic functional group.