FF properties of a multilayer coating film configured to exhibit a warm color through a lustrous layer (14) and a translucent colored layer (15) are improved to achieve a metallic textured color having a high-quality color tone. The lustrous layer (14) is configured such that Y(10) is 50 or more and 950 or less and that Y(25) is 0.05 or more and 0.35 or less times the Y(10), where Y(10) represents a Y value, of an XYZ color system, of reflected light measured at a light receiving angle of 10 and Y(25) represents a Y value of the reflected light measured at the light receiving angle of 25 in a case where a light incident angle is 45. A concentration C of a warm color pigment of the colored layer (15) is 1% by mass or more and 17% by mass or less.

This invention relates to a multilayer coating film sequentially comprising, on a substrate, a colored coating film, an effect coating film, and a clear coating film, wherein the multilayer coating film has a lightness L*110 within a range of 60 to 90, the lightness L*110 being based on a spectral reflectance of light illuminated at an angle of 45 degrees with respect to the coating surface and received at an angle of 110 degrees with respect to the specularly reflected light; a 60-degree specular gloss within a range of 105 to 180, a graininess HG within a range of 10 to 40; and a flip-flop value within a range of 1.0 to 1.8.

The problem to be solved by the present invention is to provide an effect pigment dispersion that exhibits excellent water resistance, that can form metallic or pearly luster, and that further exhibits high stability; and to provide a method for forming a multilayer coating film. The present invention provides an effect pigment dispersion that contains water, a wetting agent (A), a flake-effect pigment (B), and a phosphate-group-containing cellulose-based rheology control agent (C). The effect pigment dispersion has a solids content of 0.1 to 10 parts by mass, per 100 parts by mass of all of the components of the effect pigment dispersion; and has a viscosity of 100 to 10000 mPa.Math.sec as measured with a Brookfield viscometer at a rotational speed of 6 revolutions per minute.

The problem to be solved by the present invention is to provide an effect pigment dispersion that exhibits excellent water resistance, that can form metallic or pearly luster, and that further exhibits high stability; and to provide a method for forming a multilayer coating film. The present invention provides an effect pigment dispersion that contains water, a wetting agent (A), a flake-effect pigment (B), and a phosphate-group-containing cellulose-based rheology control agent (C). The effect pigment dispersion has a solids content of 0.1 to 10 parts by mass, per 100 parts by mass of all of the components of the effect pigment dispersion; and has a viscosity of 100 to 10000 mPa.Math.sec as measured with a Brookfield viscometer at a rotational speed of 6 revolutions per minute.

A metallic base coating film 15 is stacked on a colored base coating film 14 provided on a surface of an article to be coated. While the colored base coating film 14 alone is formed on the surface of the article to be coated, a light reflectance at light receiving angles of 15? and 45? is measured to be 2% or below in a wavelength ranging from 450 nm to 700 nm inclusive. On the metallic base coating film 15 alone, the light reflectance measured at the light receiving angle of 15? ranges from 20% to 50% inclusive in the wavelength ranging from 450 nm to 700 nm inclusive, and the light reflectance measured at the light receiving angle of 45? is 2.5% or below in the wavelength ranging from 450 nm to 700 nm inclusive.

The present invention relates to Disclosed herein is a multilayer coating system being present on an optionally pre-coated substrate and including at least three coatings layers L1, L2 and L3 being different from one another, the first layer L1 applied on an optionally pre-coated substrate, the second layer L2 applied over L1, and the third top coating layer L3 applied over L2, where layer L1 is formed from a primer coating composition and layer L2 is formed from a basecoat composition different from the primer coating composition, where the primer coating composition is free of or essentially free of metal effect pigments. Further disclosed herein are a method of preparing the multilayer coating system, a kit-of-parts and a method of using the kit-of-parts for improving the LiDAR reflectivity, measured at an angle of incidence of 0?, and the flop index, of multilayer coating systems.

The present invention relates to Disclosed herein is a multilayer coating system being present on an optionally pre-coated substrate and including at least three coatings layers L1, L2 and L3 being different from one another, the first layer L1 applied on an optionally pre-coated substrate, the second layer L2 applied over L1, and the third top coating layer L3 applied over L2, where layer L1 is formed from a primer coating composition and layer L2 is formed from a basecoat composition different from the primer coating composition, where the primer coating composition is free of or essentially free of metal effect pigments. Further disclosed herein are a method of preparing the multilayer coating system, a kit-of-parts and a method of using the kit-of-parts for improving the LiDAR reflectivity, measured at an angle of incidence of 0?, and the flop index, of multilayer coating systems.

This invention provides a method for forming a multilayer coating film, comprising applying a base paint (X) having a solids content ratio of 30 to 62 mass % to a substrate to form a base coating film having a cured film thickness of 6 to 45 ?m; applying an effect pigment dispersion (Y) having a solids content ratio of 0.1 to 10 mass % to the base coating film to form an effect coating film having a cured film thickness of 0.1 to 5.0 ?m; applying a two-component clear paint (Z) containing a hydroxy-containing resin and a polyisocyanate compound to the effect coating film to form a clear coating film; and heating the base coating film, the effect coating film, and the clear coating film to simultaneously cure these coating films; wherein the base paint (X) contains a polyurethane resin (A), an alcohol (B) containing 6 to 12 carbon atoms, and an organic solvent (C) having an HLB of 7 to 9, and the effect pigment dispersion (Y) contains water, a flake-effect pigment (P), a resin emulsion (Q), and cellulose nanofibers (R).

This invention provides a method for forming a multilayer coating film, comprising applying a base paint (X) having a solids content ratio of 30 to 62 mass % to a substrate to form a base coating film having a cured film thickness of 6 to 45 ?m; applying an effect pigment dispersion (Y) having a solids content ratio of 0.1 to 10 mass % to the base coating film to form an effect coating film having a cured film thickness of 0.1 to 5.0 ?m; applying a two-component clear paint (Z) containing a hydroxy-containing resin and a polyisocyanate compound to the effect coating film to form a clear coating film; and heating the base coating film, the effect coating film, and the clear coating film to simultaneously cure these coating films; wherein the base paint (X) contains a polyurethane resin (A), an alcohol (B) containing 6 to 12 carbon atoms, and an organic solvent (C) having an HLB of 7 to 9, and the effect pigment dispersion (Y) contains water, a flake-effect pigment (P), a resin emulsion (Q), and cellulose nanofibers (R).

Disclosed herein is a multilayer coating including at least one ground coat layer, the at least one ground coat layer including at least one non-platelet-shaped titanium dioxide pigment (T); at least one midcoat layer on top of the at least one ground coat layer, and at least one clearcoat layer on top of the at least one midcoat layer; and having a lightness L* according to CIELab in the viewing angle range from ?15? to +45? of at least 80; in the viewing angle range from +75? to +110? of at least 70, if a metal effect pigment is contained in the midcoat layer; in the viewing angle range from +75? to +110? of at least 75, if no metal effect pigment is contained in the midcoat layer. Further disclosed herein are a method for producing such multilayer coating and a multilayer coated substrate.