An alloy treatment method is provided, in which a solution containing nickel and/or cobalt is obtained from an alloy containing nickel and/or cobalt and also containing copper and zinc, the method comprising: a leaching step for subjecting the alloy to a leaching treatment with an acid under the condition where a sulfating agent is present to produce a leachate; a reduction step for subjecting the leachate to a reduction treatment using a reducing agent to produce a reduced solution; an oxidation/neutralization step for adding an oxidizing agent and a neutralizing agent to the reduced solution to produce a neutralized solution containing nickel and/or cobalt and also containing zinc; and a solvent extraction step for subjecting the neutralized solution to a solvent extraction procedure using an acidic phosphorus compound-based extractant to produce a solution containing nickel and/or cobalt.

An alloy treatment method is provided, in which a solution containing nickel and/or cobalt is obtained from an alloy containing nickel and/or cobalt and also containing copper and zinc, the method comprising: a leaching step for subjecting the alloy to a leaching treatment with an acid under the condition where a sulfating agent is present to produce a leachate; a reduction step for subjecting the leachate to a reduction treatment using a reducing agent to produce a reduced solution; an oxidation/neutralization step for adding an oxidizing agent and a neutralizing agent to the reduced solution to produce a neutralized solution containing nickel and/or cobalt and also containing zinc; and a solvent extraction step for subjecting the neutralized solution to a solvent extraction procedure using an acidic phosphorus compound-based extractant to produce a solution containing nickel and/or cobalt.

Active metal particles in which the surface layer is hardly oxidized and a method for producing the active metal particles is provided. In the method for modifying the surface of active metal particles, heat is generated by moving active metal powder in a fluid, and the surface layer of the active metal particles is reacted with an arbitrary component in the fluid by the heat to modify the surface layer. Preferably, moving the active metal powder draws a substantially circular orbit while vibrating. A vibrating mill is preferably used when making such movement with respect to the active metal powder. Then, the powder obtained by the surface modification has a nitrogen-containing coating as a surface layer with a thickness more than 1 nm and less than or equal to 6 nm. The powder has a fluidity in the range of 25 seconds/50 g or more and 45 seconds/50 g or less.

Active metal particles in which the surface layer is hardly oxidized and a method for producing the active metal particles is provided. In the method for modifying the surface of active metal particles, heat is generated by moving active metal powder in a fluid, and the surface layer of the active metal particles is reacted with an arbitrary component in the fluid by the heat to modify the surface layer. Preferably, moving the active metal powder draws a substantially circular orbit while vibrating. A vibrating mill is preferably used when making such movement with respect to the active metal powder. Then, the powder obtained by the surface modification has a nitrogen-containing coating as a surface layer with a thickness more than 1 nm and less than or equal to 6 nm. The powder has a fluidity in the range of 25 seconds/50 g or more and 45 seconds/50 g or less.

This disclosure relates to a manufacture method of a bushing, a bushing and an excavator to alleviate the problems of insufficient lubricity and wear resistance of the bushing. The bushing includes an inner ring and an outer ring. The manufacture method of the bushing includes the following steps: grinding a first mixed powder containing Fe, Al, Ti, Cr and V, nitriding the ground first mixed powder to form a nitrogen-rich stable compound powder, and then carrying out molding by pressing and sintering the nitrogen-rich stable compound powder to form the outer ring; grinding a second mixed powder containing Fe and Mo, sulfurizing the ground second mixed powder to form a sulfurized powder containing FeS and MoS.sub.2, and carrying out molding by pressing the sulfurized powder to form the inner ring; and placing the inner ring in the outer ring and carrying out sintering to obtain the bushing.

This disclosure relates to a manufacture method of a bushing, a bushing and an excavator to alleviate the problems of insufficient lubricity and wear resistance of the bushing. The bushing includes an inner ring and an outer ring. The manufacture method of the bushing includes the following steps: grinding a first mixed powder containing Fe, Al, Ti, Cr and V, nitriding the ground first mixed powder to form a nitrogen-rich stable compound powder, and then carrying out molding by pressing and sintering the nitrogen-rich stable compound powder to form the outer ring; grinding a second mixed powder containing Fe and Mo, sulfurizing the ground second mixed powder to form a sulfurized powder containing FeS and MoS.sub.2, and carrying out molding by pressing the sulfurized powder to form the inner ring; and placing the inner ring in the outer ring and carrying out sintering to obtain the bushing.

A method for processing a powder material includes cleaning surfaces of a powder material that has spherical metal particles, coating the cleaned surfaces with an organic bonding agent, mixing the coated particles with a dispersion that contains ceramic nanoparticles, drying the mixture to remove a carrier of the dispersion and deposit the ceramic nanoparticles with a spaced-apart distribution onto the organic bonding agent on the surfaces of the particles, and thermally removing the organic bonding agent to attach the ceramic nanoparticles to the surface of the particles.

A method for processing a powder material includes cleaning surfaces of a powder material that has spherical metal particles, coating the cleaned surfaces with an organic bonding agent, mixing the coated particles with a dispersion that contains ceramic nanoparticles, drying the mixture to remove a carrier of the dispersion and deposit the ceramic nanoparticles with a spaced-apart distribution onto the organic bonding agent on the surfaces of the particles, and thermally removing the organic bonding agent to attach the ceramic nanoparticles to the surface of the particles.

An additive manufacturing method includes using hydrogenated titanium in forming an object by additive manufacturing, the object having a first microstructure. The method includes heat treating the hydrogenated titanium and, after completing a shape of the object, dehydrogenating the object. The dehydrogenated object has a second microstructure different from the first microstructure. Also, another additive manufacturing method includes forming an object containing Ti-6Al-4V, the object having a first microstructure containing columnar structures along a build direction of the additive manufacturing and the object exhibiting mechanical property anisotropy resulting from the columnar structures. After completing a shape of the object, the method includes hydrogenating the Ti-6Al-4V, heat treating the object containing the hydrogenated titanium, and dehydrogenating the heat treated object. The method reduces mechanical property anisotropy and the dehydrogenated object has a second microstructure different from the first microstructure.

An additive manufacturing method includes using hydrogenated titanium in forming an object by additive manufacturing, the object having a first microstructure. The method includes heat treating the hydrogenated titanium and, after completing a shape of the object, dehydrogenating the object. The dehydrogenated object has a second microstructure different from the first microstructure. Also, another additive manufacturing method includes forming an object containing Ti-6Al-4V, the object having a first microstructure containing columnar structures along a build direction of the additive manufacturing and the object exhibiting mechanical property anisotropy resulting from the columnar structures. After completing a shape of the object, the method includes hydrogenating the Ti-6Al-4V, heat treating the object containing the hydrogenated titanium, and dehydrogenating the heat treated object. The method reduces mechanical property anisotropy and the dehydrogenated object has a second microstructure different from the first microstructure.