The disclosure relates to a method for preparing Ti(C,N)-based superhard metal composite materials, with Ti(C,N) powder and (W,Mo,Ta)(C,N) powder as main raw materials and Co powder as binding phase for preparation, thereby obtaining a material in which a microstructure is a double-core rim structure that has both a black core rim and a white core rim. The material has a complete and evenly distributed double-core rim structure. In the condition that the ensured hardness of the material is not reduced and even slightly increased, the toughness of the material is significantly improved, wherein the fracture toughness of the material is in the range of 11.3 to 12.5 MPa.Math.m.sup.1/2.

The disclosure relates to a method for preparing Ti(C,N)-based superhard metal composite materials, with Ti(C,N) powder and (W,Mo,Ta)(C,N) powder as main raw materials and Co powder as binding phase for preparation, thereby obtaining a material in which a microstructure is a double-core rim structure that has both a black core rim and a white core rim. The material has a complete and evenly distributed double-core rim structure. In the condition that the ensured hardness of the material is not reduced and even slightly increased, the toughness of the material is significantly improved, wherein the fracture toughness of the material is in the range of 11.3 to 12.5 MPa.Math.m.sup.1/2.

A system for additively manufacturing a composite structure is disclosed. The system may include a print head configured to discharge a matrix-coated reinforcement, and a support configured to move the print head in multiple dimensions during discharging of the matrix-coated reinforcement. The system may further include at least one cure enhancer located offboard the print head, and a controller in communication with the support and the at least one cure enhancer. The controller may be configured to selectively activate the at least one cure enhancer to expose the matrix-coated reinforcement to a cure energy during discharging of the matrix-coated reinforcement.

A head is disclosed for use with an additive manufacturing system. The head may include a housing, and a matrix reservoir disposed inside of the housing. The head may also include at least one roller located inside of the housing and configured to engage at least one of a ribbon and a sheet of reinforcement passing through the head. The head may further include a nozzle fluidly connected to the matrix reservoir, and a cure enhancer located outside of the housing and adjacent the nozzle.

A system for additively manufacturing a composite part is disclosed. The system may include a vat configured to hold a supply of resin, and a build surface disposed inside the vat. The system may also include a print head configured to discharge a matrix-coated continuous reinforcement onto the build surface, and an energy source configured to expose resin on a surface of the matrix-coated continuous reinforcement to a cure energy.

A mixture for forming a wear resistant layer on a substrate comprises particles of a first wear resistant particle type, particles of a second wear resistant particle type and a wear resistant layer binder for binding the first and the second wear resistant particles in the wear resistant layer when the layer is formed. As well, wear resistant particle size distributions for the first and second wear resistant particle types have a first mode and a second mode. The first particle type is associated with the first mode and the second particle type is associated with the second mode. Moreover, a number of first wear resistant particles associated with the first mode is larger than a number of second wear resistant particles associated with the second mode. Further, the second mode is larger than the first mode.

A mixture for forming a wear resistant layer on a substrate comprises particles of a first wear resistant particle type, particles of a second wear resistant particle type and a wear resistant layer binder for binding the first and the second wear resistant particles in the wear resistant layer when the layer is formed. As well, wear resistant particle size distributions for the first and second wear resistant particle types have a first mode and a second mode. The first particle type is associated with the first mode and the second particle type is associated with the second mode. Moreover, a number of first wear resistant particles associated with the first mode is larger than a number of second wear resistant particles associated with the second mode. Further, the second mode is larger than the first mode.

Cermet contains a hard phase which contains carbonitride containing Ti and Nb and a metallic binder phase containing an iron-group element. The hard phase includes a granular core portion and a peripheral portion which covers at least a part of the core portion. The core portion contains composite carbonitride expressed as Ti.sub.1-X-YNb.sub.XW.sub.YC.sub.1-ZN.sub.Z, where Y is not smaller than 0 and not greater than 0.05 and Z is not smaller than 0.3 and not greater than 0.6. The peripheral portion is composed to be higher in content of W than the core portion.

Cermet contains a hard phase which contains carbonitride containing Ti and Nb and a metallic binder phase containing an iron-group element. The hard phase includes a granular core portion and a peripheral portion which covers at least a part of the core portion. The core portion contains composite carbonitride expressed as Ti.sub.1-X-YNb.sub.XW.sub.YC.sub.1-ZN.sub.Z, where Y is not smaller than 0 and not greater than 0.05 and Z is not smaller than 0.3 and not greater than 0.6. The peripheral portion is composed to be higher in content of W than the core portion.

A system for additive metal manufacturing, including a deposition mechanism, a translation mechanism mounting the deposition mechanism to the working volume, and a stage. A method for additive metal manufacturing including: selectively depositing a material carrier within the working volume; removing an additive from the material carrier; and treating the resultant material.