A method for manufacturing a sintered product from a three-dimensional object as a solution includes: a preparation step S11, a degreasing step S12, and a sintering step S13. In S11, a multilayer made of an ink containing inorganic particles and an organic material is formed to prepare a three-dimensional object. S12 includes: a first degreasing step of heating the three-dimensional object under an inert gas atmosphere at a first average degreasing temperature (T1) for a first heating time to degrease the organic material; and a second degreasing step of heating the three-dimensional object degreased in the first degreasing step, under an inert gas atmosphere at a second average degreasing temperature (T2) higher than Ti for a second heating time to degrease the organic material. In S13, the three-dimensional object degreased in the second degreasing step is sintered at an average sintering temperature higher than T2 to obtain a sintered product.

A method for manufacturing a sintered product from a three-dimensional object as a solution includes: a preparation step S11, a degreasing step S12, and a sintering step S13. In S11, a multilayer made of an ink containing inorganic particles and an organic material is formed to prepare a three-dimensional object. S12 includes: a first degreasing step of heating the three-dimensional object under an inert gas atmosphere at a first average degreasing temperature (T1) for a first heating time to degrease the organic material; and a second degreasing step of heating the three-dimensional object degreased in the first degreasing step, under an inert gas atmosphere at a second average degreasing temperature (T2) higher than Ti for a second heating time to degrease the organic material. In S13, the three-dimensional object degreased in the second degreasing step is sintered at an average sintering temperature higher than T2 to obtain a sintered product.

Processes for tailoring the macroscopic shape, metallic composition, mechanical properties, and pore structure of nanoporous metal foams prepared through combustion synthesis via direct write 3D printing of metal energetic ligand precursor inks made with water and an organic thickening agent are disclosed. Such processes enable production of never before obtainable metal structures with hierarchical porosity, tailorable from the millimeter size regime to the nanometer size regime. Structures produced by these processes have numerous applications including, but not limited to, catalysts, heat exchangers, low density structural materials, biomedical implants, hydrogen storage medium, fuel cells, and batteries.

Processes for tailoring the macroscopic shape, metallic composition, mechanical properties, and pore structure of nanoporous metal foams prepared through combustion synthesis via direct write 3D printing of metal energetic ligand precursor inks made with water and an organic thickening agent are disclosed. Such processes enable production of never before obtainable metal structures with hierarchical porosity, tailorable from the millimeter size regime to the nanometer size regime. Structures produced by these processes have numerous applications including, but not limited to, catalysts, heat exchangers, low density structural materials, biomedical implants, hydrogen storage medium, fuel cells, and batteries.

A method of titanium rod additive manufacturing may comprise: mixing a plurality of powdered metals comprising titanium, iron, vanadium, and aluminum to produce a powder blend; isostatic pressing the powder blend to form a billet having a cross-sectional profile; cutting the billet to form a rod feedstock having the first cross-sectional profile; loading the rod feedstock into an additive manufacturing machine configured to deposit the rod feedstock; and producing a metallic component from the rod feedstock.

A method of forming a rod feedstock for titanium stir friction welding additive manufacturing may comprise: mixing a plurality of powdered metals comprising titanium, iron, vanadium, and aluminum to produce a powder blend; at least one of die pressing the powder blend to form a die pressed powder or continuously powder rolling the powder blend to form a die pressed powder; and sintering the powder blend to form a rod feedstock having a cross-sectional profile.

A method for preparing the prefabricated crack defects includes defining a defect area, defining a volume percentage of the crack defects in the defect area, adjusting the proportion of spherical powder, the proportion of hollow powder and process parameters of defect preparation according to the volume percentage of the crack defects, based on the technique of laser melting deposition, printing the defect area layer by layer by using the defect preparation powder and the process parameters of defect preparation, wherein the particle size of the defect preparation powder is between 45 μm and 150 μm, the proportion of spherical powder≥93% and the proportion of hollow powder<0.5%, the process parameters of defect preparation including: laser power of 450W-550W, scanning rate of 600 mm/min-1200 mm/min, powder feeding rate of 4 g/min-12 g/min, spot diameter of 1 mm-1.2 mm, scanning spacing of 0.5 mm-0.8 mm and layer thickness of 0.08 mm-0.2 mm.

A method for preparing the prefabricated crack defects includes defining a defect area, defining a volume percentage of the crack defects in the defect area, adjusting the proportion of spherical powder, the proportion of hollow powder and process parameters of defect preparation according to the volume percentage of the crack defects, based on the technique of laser melting deposition, printing the defect area layer by layer by using the defect preparation powder and the process parameters of defect preparation, wherein the particle size of the defect preparation powder is between 45 μm and 150 μm, the proportion of spherical powder≥93% and the proportion of hollow powder<0.5%, the process parameters of defect preparation including: laser power of 450W-550W, scanning rate of 600 mm/min-1200 mm/min, powder feeding rate of 4 g/min-12 g/min, spot diameter of 1 mm-1.2 mm, scanning spacing of 0.5 mm-0.8 mm and layer thickness of 0.08 mm-0.2 mm.

A method for preparing the prefabricated crack defects includes defining a defect area, defining a volume percentage of the crack defects in the defect area, adjusting the proportion of spherical powder, the proportion of hollow powder and process parameters of defect preparation according to the volume percentage of the crack defects, based on the technique of laser melting deposition, printing the defect area layer by layer by using the defect preparation powder and the process parameters of defect preparation, wherein the particle size of the defect preparation powder is between 45 μm and 150 μm, the proportion of spherical powder≥93% and the proportion of hollow powder<0.5%, the process parameters of defect preparation including: laser power of 450W-550W, scanning rate of 600 mm/min-1200 mm/min, powder feeding rate of 4 g/min-12 g/min, spot diameter of 1 mm-1.2 mm, scanning spacing of 0.5 mm-0.8 mm and layer thickness of 0.08 mm-0.2 mm.

A method for preparing prefabricated gas pore defects includes: defining a defect area, defining a volume percentage of the gas pore defects in the defect area, adjusting the proportion of satellite powder, the proportion of hollow powder and the process parameters of defect preparation according to the volume percentage of the gas pore defects, based on the technique of laser melting deposition, printing the defect area layer by layer by using the defect preparation powder and the process parameters of defect preparation, wherein the particle size of the defect preparation powder is between 45 μm and 106 μm, the proportion of satellite powder is 55-65% and the proportion of hollow powder is 2.9-3.1%, the process parameters of defect preparation comprises: laser power of 600W-1000W, scanning rate of 400 mm/min-800 mm/min, powder feeding rate of 12 g/min-20 g/min, spot diameter of 1 mm-2 mm, scanning spacing of 0.5 mm-1 mm and layer thickness of 0.15 mm-0.2 mm.