An article for magnetic heat exchange comprising a magnetocalorically active phase with a NaZn.sub.13-type crystal structure is provided by hydrogenating a bulk precursor article. The bulk precursor article is heated from a temperature of less than 50° C. to at least 300° C. in an inert atmosphere and hydrogen gas only introduced when a temperature of at least 300° C. is reached. The bulk precursor article is maintained in a hydrogen containing atmosphere at a temperature in the range 300° C. to 700° C. for a selected duration of time, and then cooled to a temperature of less than 50° C.

An article for magnetic heat exchange comprising a magnetocalorically active phase with a NaZn.sub.13-type crystal structure is provided by hydrogenating a bulk precursor article. The bulk precursor article is heated from a temperature of less than 50° C. to at least 300° C. in an inert atmosphere and hydrogen gas only introduced when a temperature of at least 300° C. is reached. The bulk precursor article is maintained in a hydrogen containing atmosphere at a temperature in the range 300° C. to 700° C. for a selected duration of time, and then cooled to a temperature of less than 50° C.

A finish heat treatment apparatus for an iron powder. Raw iron powder is placed on a continuous moving hearth and continuously charged into the apparatus. In a pretreatment zone, the raw iron powder is subjected to a pretreatment of heating the raw iron powder in an atmosphere of hydrogen gas and/or inert gas at 450 to 1100° C. In decarburization, deoxidation, and denitrification zones, the pretreated iron powder is subsequently subjected to at least two treatments of decarburization, deoxidation, and denitrification. In the pretreatment zone, a hydrogen gas and/or an inert gas serving as a pretreatment ambient gas is introduced separately from an ambient gas used in the at least two treatments is introduced from the upstream side of the pretreatment zone and released from the downstream side so as to flow in the same direction as a moving direction of the moving hearth.

A finish heat treatment apparatus for an iron powder. Raw iron powder is placed on a continuous moving hearth and continuously charged into the apparatus. In a pretreatment zone, the raw iron powder is subjected to a pretreatment of heating the raw iron powder in an atmosphere of hydrogen gas and/or inert gas at 450 to 1100° C. In decarburization, deoxidation, and denitrification zones, the pretreated iron powder is subsequently subjected to at least two treatments of decarburization, deoxidation, and denitrification. In the pretreatment zone, a hydrogen gas and/or an inert gas serving as a pretreatment ambient gas is introduced separately from an ambient gas used in the at least two treatments is introduced from the upstream side of the pretreatment zone and released from the downstream side so as to flow in the same direction as a moving direction of the moving hearth.

A process includes sintering hydrogenated titanium or titanium hydride (TiH.sub.2) and/or Ti metal in a dynamically controlled hydrogen atmosphere with hydrogen partial pressure greater than 0.01 atmosphere and at elevated temperature, to form a sintered titanium material; equilibrate the sintered material at an equilibration temperature below the sintering temperature and above the phase transformations including eutectoid decomposition temperature for an equilibration time sufficient for the hydrogen within the sample to reach equilibrium and homogenize the sintered titanium material; holding the sintered titanium material at a hold temperature below the temperature of sintering and a hold time sufficient for phase transformations including eutectoid decomposition of the sintered titanium material; and heating the sintered titanium material under vacuum, inert atmosphere, or a combination of both at a hold temperature which is less than that of the sintering temperature, to form titanium metal, or a titanium metal alloy with fine or ultrafine grain sizes; where the dynamically controlled hydrogen atmosphere varies as a function of time and temperature throughout the thermal cycle and includes hydrogen during the sintering and phase transformations including eutectoid decomposition steps.

A process includes sintering hydrogenated titanium or titanium hydride (TiH.sub.2) and/or Ti metal in a dynamically controlled hydrogen atmosphere with hydrogen partial pressure greater than 0.01 atmosphere and at elevated temperature, to form a sintered titanium material; equilibrate the sintered material at an equilibration temperature below the sintering temperature and above the phase transformations including eutectoid decomposition temperature for an equilibration time sufficient for the hydrogen within the sample to reach equilibrium and homogenize the sintered titanium material; holding the sintered titanium material at a hold temperature below the temperature of sintering and a hold time sufficient for phase transformations including eutectoid decomposition of the sintered titanium material; and heating the sintered titanium material under vacuum, inert atmosphere, or a combination of both at a hold temperature which is less than that of the sintering temperature, to form titanium metal, or a titanium metal alloy with fine or ultrafine grain sizes; where the dynamically controlled hydrogen atmosphere varies as a function of time and temperature throughout the thermal cycle and includes hydrogen during the sintering and phase transformations including eutectoid decomposition steps.

A system for producing technetium-99m from molybdate-100. The system comprises: a target capsule apparatus for housing a Mo-100-coated target plate; a target capsule pickup apparatus for engaging and delivering the target cell apparatus into a target station apparatus; a target station apparatus for receiving and mounting therein the target capsule apparatus. The target station apparatus is engaged with a cyclotron for irradiating the Mo-100-coated target plate with protons. The irradiated target capsule apparatus is transferred to a receiving cell apparatus comprising a dissolution/purification module for receiving therein a proton-irradiated Mo-100-coated target plate. A conveyance conduit infrastructure interconnects: (i) the target capsule pickup apparatus with the target station apparatus, (ii) the target station apparatus and the receiving cell apparatus; and (iii) the receiving cell apparatus and the dissolution/purification module.

A system for producing technetium-99m from molybdate-100. The system comprises: a target capsule apparatus for housing a Mo-100-coated target plate; a target capsule pickup apparatus for engaging and delivering the target cell apparatus into a target station apparatus; a target station apparatus for receiving and mounting therein the target capsule apparatus. The target station apparatus is engaged with a cyclotron for irradiating the Mo-100-coated target plate with protons. The irradiated target capsule apparatus is transferred to a receiving cell apparatus comprising a dissolution/purification module for receiving therein a proton-irradiated Mo-100-coated target plate. A conveyance conduit infrastructure interconnects: (i) the target capsule pickup apparatus with the target station apparatus, (ii) the target station apparatus and the receiving cell apparatus; and (iii) the receiving cell apparatus and the dissolution/purification module.

A method for producing a cermet composition, including mixing a first predetermined amount of a yttria stabilized zirconia powder with between 2 and 8 weight percent mu-metal powder to define a homogeneous admixture, oxidizing the mu-metal in the admixture, forming the homogeneous admixture into a green body, calcining the green body in a first reducing atmosphere to remove oxygen from the oxidized mu-metal to yield a calcined body, and sintering the calcined body in a second reducing atmosphere to yield a densified body having no more than 0.8% porosity. The densified body has a plurality of mu-metal particles distributed therethrough, a hardness of at least 1450 HV, flexural strength of at least 200 kPSI, and a relative permeability μ/μ.sub.o of at least 850.

A method for producing a cermet composition, including mixing a first predetermined amount of a yttria stabilized zirconia powder with between 2 and 8 weight percent mu-metal powder to define a homogeneous admixture, oxidizing the mu-metal in the admixture, forming the homogeneous admixture into a green body, calcining the green body in a first reducing atmosphere to remove oxygen from the oxidized mu-metal to yield a calcined body, and sintering the calcined body in a second reducing atmosphere to yield a densified body having no more than 0.8% porosity. The densified body has a plurality of mu-metal particles distributed therethrough, a hardness of at least 1450 HV, flexural strength of at least 200 kPSI, and a relative permeability μ/μ.sub.o of at least 850.