An FeNi ordered alloy has an L1.sub.0 ordered structure, a mean order degree of 0.4 or more throughout a material, and a coercivity of 87.5 kA/m or more. For example, a nitriding treatment of an FeNi random alloy is performed and then a nitriding treatment is performed to obtain an L1.sub.0-FeNi ordered alloy. A volume mean particle size of a FeNi random alloy is, for example, 45 nm or more, and a treatment temperature of the nitriding treatment is, for example, greater than or equal to 300 degrees Celsius and is less than or equal to 500 degrees Celsius, and a treatment period is, for example, 10 hours or longer.

A metal-ceramic article and method for creating the same is disclosed in which the article has undergone machining to remove outer surface volume. The article is then treated to enhance the characteristics of at least the machined surface to be comparable to the original surface. In the disclosed application the machining does not extend to an inner layer of the article in which the article consists purely of a metal.

A metal-ceramic article and method for creating the same is disclosed in which the article has undergone machining to remove outer surface volume. The article is then treated to enhance the characteristics of at least the machined surface to be comparable to the original surface. In the disclosed application the machining does not extend to an inner layer of the article in which the article consists purely of a metal.

A samarium-iron-nitrogen alloy powder according to one embodiment of the present invention is characterized in that a value obtained by dividing the hydrogen content of the samarium-iron-nitrogen alloy powder by the BET specific surface area of the samarium-iron-nitrogen alloy powder is less than or equal to 400 ppm/(m.sup.2/g), and a value obtained by dividing the oxygen content of the samarium-iron-nitrogen alloy powder by the BET specific surface area of the samarium-iron-nitrogen alloy powder is less than or equal to 11,000 ppm/(m.sup.2/g).

A samarium-iron-nitrogen alloy powder according to one embodiment of the present invention is characterized in that a value obtained by dividing the hydrogen content of the samarium-iron-nitrogen alloy powder by the BET specific surface area of the samarium-iron-nitrogen alloy powder is less than or equal to 400 ppm/(m.sup.2/g), and a value obtained by dividing the oxygen content of the samarium-iron-nitrogen alloy powder by the BET specific surface area of the samarium-iron-nitrogen alloy powder is less than or equal to 11,000 ppm/(m.sup.2/g).

There is provided a cobalt-based alloy product comprising: in mass %, 0.08-0.25% C; more than 0.04% and 0.2% or less N, the total amount of C and N being more than 0.12% and 0.28% or less; 0.1% or less B; 10-30% Cr; 5% or less Fe and 30% or less Ni, the total amount of Fe and Ni being 30% or less; W and/or Mo, the total amount of W and Mo being 5-12%; 0.5% or less Si; 0.5% or less Mn; 0.5 to 2 mass % of an M component being a transition metal other than W and Mo and having an atomic radius of more than 130 pm; and the balance being Co and impurities. The product comprises matrix phase crystal grains, in which particles of MC carbides, M(C,N) carbonitrides and/or MN nitrides including the M component are precipitated at an average interparticle distance of 0.13-2 μm.

There is provided a cobalt-based alloy product comprising: in mass %, 0.08-0.25% C; more than 0.04% and 0.2% or less N, the total amount of C and N being more than 0.12% and 0.28% or less; 0.1% or less B; 10-30% Cr; 5% or less Fe and 30% or less Ni, the total amount of Fe and Ni being 30% or less; W and/or Mo, the total amount of W and Mo being 5-12%; 0.5% or less Si; 0.5% or less Mn; 0.5 to 2 mass % of an M component being a transition metal other than W and Mo and having an atomic radius of more than 130 pm; and the balance being Co and impurities. The product comprises matrix phase crystal grains, in which particles of MC carbides, M(C,N) carbonitrides and/or MN nitrides including the M component are precipitated at an average interparticle distance of 0.13-2 μm.

A 3-D printing method and a 3-D printout are provided. In an embodiment, the 3-D printing method includes laser-scanning a printing material according to a 3-D printing model so that the printing material starts to be sintered into a printout in a shape, layer by layer from the bottom up; and feeding a treatment gas into a 3-D printing device and laser-scan a local area of the printout so that the treatment gas reacts with the surface of the local area of the printout and a hardened layer is formed. The laser scanning and the feeding of the treatment gas are performed alternately until a printout with local hardened layers is formed. By adjusting the gas environment, the components can be manufactured by selective laser melting equipment to have a wear- and corrosion-resistant nitrided surface layer and keep the expected ductility of the central area.

A 3-D printing method and a 3-D printout are provided. In an embodiment, the 3-D printing method includes laser-scanning a printing material according to a 3-D printing model so that the printing material starts to be sintered into a printout in a shape, layer by layer from the bottom up; and feeding a treatment gas into a 3-D printing device and laser-scan a local area of the printout so that the treatment gas reacts with the surface of the local area of the printout and a hardened layer is formed. The laser scanning and the feeding of the treatment gas are performed alternately until a printout with local hardened layers is formed. By adjusting the gas environment, the components can be manufactured by selective laser melting equipment to have a wear- and corrosion-resistant nitrided surface layer and keep the expected ductility of the central area.

One embodiment of the present invention is that in samarium-iron-nitrogen magnet powder, a non-magnetic phase is formed on a surface of the samarium-iron-nitrogen magnet phase, and an arithmetic mean roughness Ra of the surface is 3.5 nm or less.