An R-T-B based permanent magnet includes R-T-B based compounds as main-phase crystal grains. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. A two-grain boundary is contained between the two adjacent main-phase crystal grains. An average grain size of the main-phase crystal grains is 0.9 m or more and 2.8 m or less. A thickness of the two-grain boundary is 5 nm or more and 200 nm or less.

The present disclosure is directed at methods of preparing rare earth-based permanent magnets having improved coercivity and remanence, the method comprising one or more steps comprising: (a) homogenizing a first population of particles of a first GBM alloy with a second population of particles of a second core alloy to form a composite alloy preform, the first GBM alloy being substantially represented by the formula: AC.sub.bR.sub.xCo.sub.yCu.sub.dM.sub.z, the second core alloy being substantially represented by the formula G.sub.2Fe.sub.14B, where AC, R, M, G, b, x, y, and z are defined; (b) heating the composite alloy preform particles to form a population of mixed alloy particles; (c) compressing the mixed alloy particles, under a magnetic field of a suitable strength to align the magnetic particles with a common direction of magnetization and inert atmosphere, to form a green body; (d) sintering the green body; and (e) annealing the sintered body. Particular embodiments include magnets comprising neodymium-iron-boron core alloys, including Nd.sub.2Fe.sub.14B.

The present disclosure is directed at methods of preparing rare earth-based permanent magnets having improved coercivity and remanence, the method comprising one or more steps comprising: (a) homogenizing a first population of particles of a first GBM alloy with a second population of particles of a second core alloy to form a composite alloy preform, the first GBM alloy being substantially represented by the formula: AC.sub.bR.sub.xCo.sub.yCu.sub.dM.sub.z, the second core alloy being substantially represented by the formula G.sub.2Fe.sub.14B, where AC, R, M, G, b, x, y, and z are defined; (b) heating the composite alloy preform particles to form a population of mixed alloy particles; (c) compressing the mixed alloy particles, under a magnetic field of a suitable strength to align the magnetic particles with a common direction of magnetization and inert atmosphere, to form a green body; (d) sintering the green body; and (e) annealing the sintered body. Particular embodiments include magnets comprising neodymium-iron-boron core alloys, including Nd.sub.2Fe.sub.14B.

A bonding wire for a semiconductor device includes a Cu alloy core material and a Pd coating layer formed on a surface thereof, and the boding wire contains one or more elements of As, Te, Sn, Sb, Bi and Se in a total amount of 0.1 to 100 ppm by mass. The bonding longevity of a ball bonded part can increase in a high-temperature and high-humidity environment, improving the bonding reliability. When the Cu alloy core material further contains one or more of Ni, Zn, Rh, In, Ir, Pt, Ga and Ge in an amount, for each, of 0.011 to 1.2% by mass, it is able to increase the reliability of a ball bonded part in a high-temperature environment of 170 C. or more. When an alloy skin layer containing Au and Pd is further formed on a surface of the Pd coating layer, wedge bondability improves.

A bonding wire for a semiconductor device includes a Cu alloy core material and a Pd coating layer formed on a surface thereof, and the boding wire contains one or more elements of As, Te, Sn, Sb, Bi and Se in a total amount of 0.1 to 100 ppm by mass. The bonding longevity of a ball bonded part can increase in a high-temperature and high-humidity environment, improving the bonding reliability. When the Cu alloy core material further contains one or more of Ni, Zn, Rh, In, Ir, Pt, Ga and Ge in an amount, for each, of 0.011 to 1.2% by mass, it is able to increase the reliability of a ball bonded part in a high-temperature environment of 170 C. or more. When an alloy skin layer containing Au and Pd is further formed on a surface of the Pd coating layer, wedge bondability improves.

A manufacturing method of oxidation resistant alloy includes: producing a first formed member by applying compression forming to metal powder; and applying compression forming to the first formed member in a state in which the first formed member is covered with alloy powder different from the metal powder. The oxidation resistance of the major constituent of the alloy powder is higher than the oxidation resistance of the major constituent of the metal powder. Producing the first formed member may include applying the compression forming to the metal powder without melting the metal powder. Applying the compression forming to the first formed member may include: producing a second formed member by applying compression forming to the alloy powder without melting the alloy powder; and sintering the second formed member.

A manufacturing method of oxidation resistant alloy includes: producing a first formed member by applying compression forming to metal powder; and applying compression forming to the first formed member in a state in which the first formed member is covered with alloy powder different from the metal powder. The oxidation resistance of the major constituent of the alloy powder is higher than the oxidation resistance of the major constituent of the metal powder. Producing the first formed member may include applying the compression forming to the metal powder without melting the metal powder. Applying the compression forming to the first formed member may include: producing a second formed member by applying compression forming to the alloy powder without melting the alloy powder; and sintering the second formed member.

The invention is concerned with the fields of cemented carbide materials and ceramic and/or powder-metallurgical process engineering and relates to a sintered cemented carbide granulate such as that which can, for example, be used for the production of wear parts or tools with cemented carbides, and to its use.

The object of the present invention is to specify a cemented carbide granulate with which cemented carbide green bodies and cemented carbide sintered bodies that exhibit a high green density and high green strength can be produced, and to specify the use thereof.

The object is attained with a sintered cemented carbide granulate which, for the majority of granules, has an inhomogeneous distribution of hard material and metallic binder in the individual granule, wherein the concentration of the metallic binder at the surface of the individual granule is, in total, at least 25% greater than in the interior of the granule.

A heat exchanger and method for making a heat exchanger assembly is described, involving generating a digital model of a heat exchanger assembly that comprises a heat exchanger core within a housing. The digital model is inputted into an additive manufacturing apparatus or system comprising an energy source. The additive manufacturing apparatus applies energy from the energy source to successively applied incremental quantities of a metal powder, which fuses the powder to form incremental portions of the heat exchanger core and housing according to the digital model. Unfused or partially fused metal powder is enclosed in a first region of the heat exchanger assembly between the heat exchanger core and the housing.

A heat exchanger and method for making a heat exchanger assembly is described, involving generating a digital model of a heat exchanger assembly that comprises a heat exchanger core within a housing. The digital model is inputted into an additive manufacturing apparatus or system comprising an energy source. The additive manufacturing apparatus applies energy from the energy source to successively applied incremental quantities of a metal powder, which fuses the powder to form incremental portions of the heat exchanger core and housing according to the digital model. Unfused or partially fused metal powder is enclosed in a first region of the heat exchanger assembly between the heat exchanger core and the housing.