A method for depositing lithium on a substrate to form an electrode is provided. The method includes applying a printable lithium composition comprised of lithium metal powder, a polymer binder compatible with the lithium metal powder, a rheology modifier compatible with the lithium metal powder and a solvent compatible with the lithium metal powder and with the polymer binder, to a substrate.

A solid-state battery comprising a cathode, an anode and a solid electrolyte is provided. In one embodiment, the cathode, anode and/or solid electrolyte is formed from a printable lithium composition including lithium metal powder, a polymer binder compatible with the lithium metal powder, a rheology modifier compatible with the lithium metal powder, and a solvent compatible with the lithium metal powder and with the polymer binder. In another embodiment, lithium is deposited onto the solid electrolyte with a lithium printable lithium composition including lithium metal powder, a polymer binder compatible with the lithium metal powder, a rheology modifier compatible with the lithium metal powder, and a solvent compatible with the lithium metal powder and with the polymer binder.

A method of making a lithiated silicon-based precursor material for a negative electrode material of an electrochemical cell that cycles lithium ions is provided. An admixture comprising a plurality of lithium particles and a plurality of silicon particles is briquetted by applying pressure of greater than or equal to about 10 MPa and applying heat at a temperature of less than or equal to about 180° C. to form a precursor briquette. The briquette has lithium particles and silicon particles distributed in a matrix and has a porosity level of less than or equal to about 60% of the total volume of the precursor briquette. The briquetting is conducted in an environment having less than or equal to about 0.002% by weight of any oxygen-bearing species or nitrogen (N.sub.2).

The present disclosure provides a negative electrode material, a preparation method thereof, and an all-solid-state lithium battery. The negative electrode material includes a core and an amorphous lithium-silicon alloy layer cladding the core. The core includes a glassy solid electrolyte and amorphous lithium-silicon alloy particles dispersed in the glassy solid electrolyte. The material of the amorphous lithium-silicon alloy particles is Li.sub.xSi, 0<x4.4. The material of the amorphous lithium-silicon alloy layer is Li.sub.ySi, 0<y4.4.

A method for producing a metal powder includes maintaining molten reducing metal in a sealed reaction vessel that is free of added oxygen and water, establishing a vortex in the molten reducing metal, introducing a metal halide into the vortex so that the molten reducing metal is in a stoichiometric excess to the metal halide, thereby producing metal particles and salt, removing unreacted reducing metal, removing the salt, and recovering the metal powder. The molten reducing metal can be a Group I metal, a Group II metal, or aluminum.

A method for manufacturing a material layer includes a first step S101 of arranging first particles P1 in a pattern on a base material 11 and a second step S102 of arranging second particles in regions in which the first particles P1 are not arranged on the base material 11. The second step S102 includes a step of rubbing bearing materials S2 that carry the second particles P2 against the base material 11 on which the first particles P1 are arranged.

A printable lithium composition is provided. The printable lithium composition includes lithium metal powder; a polymer binder, wherein the polymer binder is compatible with the lithium powder; and a rheology modifier, wherein the rheology modifier is compatible with the lithium powder and the polymer binder. The printable lithium composition may further include a solvent compatible with the lithium powder and with the polymer binder.

The present disclosure discloses flake metal lithium powder and a preparing method thereof; by ultrasonically pulverizing the metal lithium placed in a low-viscosity inert organic resolvent using a vacuum ultrasonic pulverization method, a micrometer scale flake metal lithium powder is prepared. The metal lithium powder may be used as an anode material for a lithium cell or lithium ion cell. The present method has advantages of high product purity, simple operation, low processing temperature, low cost, high efficiency, and less demanding on equipment, etc., and has a high prospect of being applied to mass production of metal lithium powder.

A prelithiated anode is provided. The prelithiated anode includes an active anode material having deposited thereon a printable composition. The printable lithium composition includes comprising on a solution basis of about 10 to about 50 percent of a lithium metal powder about 0.1 to about 20 percent of a polymer binder, wherein the polymer binder is compatible with the lithium metal powder and is selected from the group consisting of unsaturated elastomers, saturated elastomers, polyacrylic acid, polyvinylidene chloride and polyvinyl acetate, about 0.1 to about 30 percent of a rheology modifier, wherein the rheology modifier is compatible with the lithium metal powder and the polymer binder, and about 50 to about 95 percent of a non-polar solvent, wherein the solvent is compatible with the lithium metal powder and with the polymer binder and wherein the solvent is selected from the group consisting of hydrocarbons, acyclic hydrocarbons, and aromatic hydrocarbons.

A material of formula Li.sub.aTi.sub.b(A.sub.xS.sub.3-x).sub.c wherein A is a metalloid element chosen from selenium, tellurium and mixtures thereof, and the stoichiometric coefficients a, b, c and x are such that 0<x<2.2; 0.4a4.5; 0.9b1.1; and 0.9c1.1.