A composite material comprising a metal matrix and nanocellulose supplement. The metal matrix is formed of a metal base material and may be monolithic throughout the composite material. The nanocellulose supplement improves a material property of the metal matrix and is formed of a nanocellulose supplement material dispersed in the metal base material. Importantly, the nanocellulose supplement material does not become damaged when the composite material is formed.

A method for producing a particulate titanium alloy product can include preparing a composite particulate oxide mixture with TiO.sub.2 powder and at least one alloying element powder. The composite particulate oxide mixture can be co-reduced using a metallic reducing agent under a hydrogen atmosphere at a reduction temperature for a reduction time sufficient to produce a hydrogenated titanium alloy product. The hydrogenated titanium alloy product can then be heat treated under a hydrogen atmosphere and a heat treating temperature to reduce pore size and specific surface area to form a heat treated hydrogenated titanium product. The heat treated hydrogenated titanium product can be deoxygenated to reduce residual oxygen to less than 0.2 wt % to form a deoxygenated hydrogenated titanium product as a particulate. The deoxygenated hydrogenated titanium product can optionally be dehydrogenated to form the titanium alloy product as a particulate.

The present invention relates to a feedstock for 3D printing, a preparation method and an application thereof. The feedstock is polymer binder-coated metal powder, being in a linear shape. After being printed into a green body with a preset shape via a 3D printer, the linear feedstock is sequentially degreased and sintered, so that a metal product with a complex structure and high accuracy can be obtained. Compared with the prior art, the linear feedstock is applied to 3D printing, so that waste of raw materials can be avoided; the accuracy of a product surface is controlled and the quality of products is improved by selecting different wire diameters of the feedstock and controlling the heating temperature; and melting treatment can be performed by a simple thermocouple without need for complex and dear laser heating equipment, so that production cost is reduced. The powder injection molding technology and 3D printing technology are combined, so that complex products can be quickly printed and manufactured, development flow is shortened, and mass production popularization is realized. The feedstock has good economic benefits and wide application prospect.

Some variations provide a method of making a nanofunctionalized metal powder, comprising: providing metal particles containing metals selected from aluminum, iron, nickel, copper, titanium, magnesium, zinc, silicon, lithium, silver, chromium, manganese, vanadium, bismuth, gallium, or lead; providing nanoparticles selected from zirconium, tantalum, niobium, or titanium; disposing the nanoparticles onto surfaces of the metal particles, in the presence of mixing media, thereby generating nanofunctionalized metal particles; and isolating and recovering the nanofunctionalized metal particles as a nanofunctionalized metal powder. Some variations provide a composition comprising a nanofunctionalized metal powder, the composition comprising metal particles and nanoparticles containing one or more elements selected from the group consisting of zirconium, tantalum, niobium, titanium, and oxides, nitrides, hydrides, carbides, or borides thereof, or combinations of the foregoing.

A hardening agent for three-dimensional printing includes a boron-containing hardener and a jettable liquid vehicle, and is devoid of a pigment and a dye. The boron-containing hardener is selected from the group consisting of a water dispersible boron-containing hardener present in an amount ranging from about 6 wt % to about 15 wt %, and a water soluble boron-containing hardener present in an amount ranging from greater than 1 wt % to about 20 wt %.

The present disclosure provides a preparation method of a metal powder material. An alloy sheet composed of a matrix phase and a dispersive phase with different chemical reactivities is prepared by the rapid solidification technique of alloy melt. Metal powder is prepared by the reaction of the alloy sheet and an acid solution. Please refer to the description for the detailed preparation method. This method is simple in operation, can be used to prepare many kinds of metal powder materials of different shapes and at the nanometer scale, the submicron scale and the micron scale, and has a good application prospect in the fields of catalysis, powder metallurgy and 3D printing.

A titanium sintered body has an average crystal grain diameter on the surface of more than 30 m and 500 m or less, and a Vickers hardness on the surface of 300 or more and 800 or less. In the titanium sintered body, it is preferred that crystal structures on the surface have an average aspect ratio of 1 or more and 3 or less. Further, in the titanium sintered body, it is preferred that the oxygen content on the surface is 2000 ppm by mass or more and 5500 ppm by mass or less. Further, in the titanium sintered body, it is preferred that titanium is contained as a main component, and an -phase stabilizing element and a -phase stabilizing element are also present.

The present disclosure provides a preparation method of a metal powder material. An alloy sheet composed of a matrix phase and a dispersive phase with different chemical reactivities is prepared by the rapid solidification technique of alloy melt. Metal powder is prepared by the reaction of the alloy sheet and an acid solution. Please refer to the description for the detailed preparation method. This method is simple in operation, can be used to prepare many kinds of metal powder materials of different shapes and at the nanometer scale, the submicron scale and the micron scale, and has a good application prospect in the fields of catalysis, powder metallurgy and 3D printing.

A three-dimensional deposition device and a three-dimensional deposition method used to highly accurately manufacture a three-dimensional object are provided. A three-dimensional deposition device for forming a three-dimensional shape by depositing a formed layer on a base unit includes: a powder supply unit which supplies a powder material; a light irradiation unit which irradiates the powder material with a light beam so that at least a part of the powder material irradiated with the light beam is sintered or melted and solidified to form the formed layer; a heating unit which selectively heats an area having passed through a position irradiated with the light beam in the base unit or the formed layer or an area not having passed through the position irradiated with the light beam; and a control device which controls operations of the powder supply unit, the light irradiation unit, and the heating unit.

A porous titanium-based sintered body, having a porosity of 45% to 65%, an average pore diameter of 5 m to 15 m, and a bending strength of 100 MPa or more. According to the present invention, a porous titanium-based sintered body having good pore diameter and porosity that are compatible with each other and having a high strength can be provided.