Composite structures having a reinforced material intermingled with a substrate wherein the reinforced material includes titanium monoboride, titanium diboride, or a combination thereof.

Composite structures having a reinforced material intermingled with a substrate wherein the reinforced material includes titanium monoboride, titanium diboride, or a combination thereof.

The disclosed technology generally relates to consumable electrode wires and more particularly to consumable electrode wires having a core-shell structure, where the core comprises chromium. In one aspect, a welding wire comprises a sheath having a steel composition and a core surrounded by the sheath. The core comprises chromium (Cr) at a concentration between about 12 weight % and about 18 weight % on the basis of the total weight of the welding wire, manganese (Mn) at a concentration between about 12 weight % and about 18 weight % on the basis of the total weight of the welding wire, nickel (Ni) at a concentration between zero and about 5 weight % on the basis of the total weight of the welding wire, and carbon (C) at a concentration greater than zero weight %, wherein concentrations of Ni, C and Mn are such that [Ni]+30[C]+0.5[Mn] is less than about 12 weight %, wherein [Ni], [C], and [Mn] represent weight percentages of respective elements on the basis of the total weight of the welding wire. The disclosed technology also relates to welding methods and systems adapted for using the chromium-comprising electrode wires.

The disclosed technology generally relates to consumable electrode wires and more particularly to consumable electrode wires having a core-shell structure, where the core comprises chromium. In one aspect, a welding wire comprises a sheath having a steel composition and a core surrounded by the sheath. The core comprises chromium (Cr) at a concentration between about 12 weight % and about 18 weight % on the basis of the total weight of the welding wire, manganese (Mn) at a concentration between about 12 weight % and about 18 weight % on the basis of the total weight of the welding wire, nickel (Ni) at a concentration between zero and about 5 weight % on the basis of the total weight of the welding wire, and carbon (C) at a concentration greater than zero weight %, wherein concentrations of Ni, C and Mn are such that [Ni]+30[C]+0.5[Mn] is less than about 12 weight %, wherein [Ni], [C], and [Mn] represent weight percentages of respective elements on the basis of the total weight of the welding wire. The disclosed technology also relates to welding methods and systems adapted for using the chromium-comprising electrode wires.

Systems and methods for low-manganese welding alloys are disclosed. An example arc welding consumable may comprise: less than 0.4 wt % manganese; strengthening agents selected from the group consisting of nickel, cobalt, copper, carbon, molybdenum, chromium, vanadium, silicon, and boron; and grain control agents selected from the group consisting of niobium, tantalum, titanium, zirconium, and boron. The grain control agents may comprise greater than 0.06 wt % and less than 0.6 wt % of the welding consumable. The resulting weld deposit may comprise a tensile strength greater than or equal to 70 ksi, a yield strength greater than or equal to 58 ksi, a ductility (as measured by percent elongation) of at least 22%, and a Charpy V-notch toughness greater than or equal to 20 ft-lbs at 20 F. The welding consumable may provide a manganese fume generation rate less than 0.01 grams per minute during the arc welding operation.

Systems and methods for low-manganese welding alloys are disclosed. An example arc welding consumable may comprise: less than 0.4 wt % manganese; strengthening agents selected from the group consisting of nickel, cobalt, copper, carbon, molybdenum, chromium, vanadium, silicon, and boron; and grain control agents selected from the group consisting of niobium, tantalum, titanium, zirconium, and boron. The grain control agents may comprise greater than 0.06 wt % and less than 0.6 wt % of the welding consumable. The resulting weld deposit may comprise a tensile strength greater than or equal to 70 ksi, a yield strength greater than or equal to 58 ksi, a ductility (as measured by percent elongation) of at least 22%, and a Charpy V-notch toughness greater than or equal to 20 ft-lbs at 20 F. The welding consumable may provide a manganese fume generation rate less than 0.01 grams per minute during the arc welding operation.

Provided is a high Cr Ni-based alloy welding wire with which tensile strength and weld cracking resistance of a welded portion, the integrity of the microstructure of a welded metal, and inhibition of scale generation are improved. The high Cr Ni-based alloy welding wire is configured to have an alloy composition comprising, by mass, C: 0.04% or less, Mn: 7% or less, Fe: 1 to 12%, Si: 0.75% or less, Al: 0.01 to 0.7%, Ti: 0.01 to 0.7%, Cr: 25.0 to 31.5%, Ta: 1 to 10%, and Mo: 1 to 6%, and as inevitable impurities, Ca+Mg: less than 0.002%, N: 0.1% or less, P: 0.02% or less, O: 0.01% or less, S: 0.0015% or less, H: 0.0015% or less, Cu: 0.08% or less, and Co: 0.05% or less, and the balance: Ni. Then, the high CrNi-based alloy welding wire is configured such that the contents of S, Ta, Al, and Ti satisfy the following relation (1) and the contents of Ta, Mo, and N satisfy the following relation (2):
12000S+0.58Ta2.6Al2Ti19.3(1)
Ta+1.6Mo+187N.sup.35.7(2).

A nanoparticle powder is disclosed including a plurality of stabilized nanoparticles having a superalloy composition. At least about 90% of the particles have a convexity between about 0.980-1 and a circularity between about 0.850-1. A method for forming a braze paste is disclosed including mixing the plurality of stabilized nanoparticles with at least one organometallic precursor and up to about 5 wt % binder. A method for modifying an article is disclosed including applying the braze paste to a substrate including at least one crack, removing at least about 70% of the binder in the braze paste, and then applying additional braze paste over the first portion. Under vacuum or inert gas atmosphere, essentially all remaining binder is evaporated. The braze paste is brazed to the article at about 40-60% of the superalloy's bulk liquidus temperature, forming a brazed material and thereby sealing the at least one crack.

A nanoparticle powder is disclosed including a plurality of stabilized nanoparticles having a superalloy composition. At least about 90% of the particles have a convexity between about 0.980-1 and a circularity between about 0.850-1. A method for forming a braze paste is disclosed including mixing the plurality of stabilized nanoparticles with at least one organometallic precursor and up to about 5 wt % binder. A method for modifying an article is disclosed including applying the braze paste to a substrate including at least one crack, removing at least about 70% of the binder in the braze paste, and then applying additional braze paste over the first portion. Under vacuum or inert gas atmosphere, essentially all remaining binder is evaporated. The braze paste is brazed to the article at about 40-60% of the superalloy's bulk liquidus temperature, forming a brazed material and thereby sealing the at least one crack.

Systems and methods for low-manganese welding alloys are disclosed. An example arc welding consumable that forms a weld deposit on a steel workpiece during an arc welding operation, wherein the welding consumable comprises: less than 0.4 wt % manganese; strengthening agents selected from the group consisting of nickel, cobalt, copper, carbon, molybdenum, chromium, vanadium, silicon, and boron; and grain control agents selected from the group consisting of niobium, tantalum, titanium, zirconium, and boron, wherein the grain control agents comprise greater than 0.06 wt % and less than 0.6 wt % of the welding consumable, wherein the weld deposit comprises a tensile strength greater than or equal to 70 ksi, a yield strength greater than or equal to 58 ksi, a ductility, as measured by percent elongation, that is at least 22%, and a Charpy V-notch toughness greater than or equal to 20 ft-lbs at 20 F., and wherein the welding consumable provides a manganese fume generation rate less than 0.01 grams per minute during the arc welding operation.