Provided are methods and systems for manufacturing and using heat-shrink elastomeric. An example method of manufacturing a heat-shrink elastomeric element comprises providing a thermoplastic elastomeric element having a first shape; modifying the thermoplastic elastomeric element to produce a thermoset elastomeric element having the first shape; heating the thermoset elastomeric element to a temperature of at least the glass transition temperature of the thermoset elastomeric element; adjusting the first shape of the thermoset elastomeric element to produce a second shape with at least one dimension greater than that of the first shape; and cooling the thermoset elastomeric element to a temperature below that of the glass transition temperature of the thermoset elastomeric element to produce the heat-shrink elastomeric element.

Curved heat shrink tubing and methods of making the same are described herein. An example method includes inserting heat shrink tubing into a tube, curving the tube, and deforming the heat shrink tubing, inside of the tube, to have a curved shape along a length of the heat shrink tubing where a first length of the heat shrink tubing along an outer radius of the curved shape is longer than a second length of the heat shrink tubing along an inner radius of the curved shape.

Curved heat shrink tubing and methods of making the same are described herein. An example method includes inserting heat shrink tubing into a tube, curving the tube, and deforming the heat shrink tubing, inside of the tube, to have a curved shape along a length of the heat shrink tubing where a first length of the heat shrink tubing along an outer radius of the curved shape is longer than a second length of the heat shrink tubing along an inner radius of the curved shape.

A heat-shrinkable tube according to an aspect of the present disclosure includes a base layer that is tubular and that covers outer peripheries of a plurality of electric wires, and a plurality of ridges that are formed on an inner peripheral surface of the base layer and that extend in an axial direction of the base layer.

Systems and method of constructing a 4D-printed ceramic object, the method including extruding inks including particles and polymeric ceramic precursors through a nozzle to deposit the inks to form a first elastic structure and a second elastic structure, subjecting the first elastic structure to a tensile stress along at least one axis, attaching the second elastic structure to the first elastic structure, releasing the application of the tensile stress from the first elastic structure to allow the first elastic structure and second elastic structure to form a 4D-printed elastomeric object, and converting the 4D-printed elastomeric object into the 4D-printed ceramic object.

Systems and method of constructing a 4D-printed ceramic object, the method including extruding inks including particles and polymeric ceramic precursors through a nozzle to deposit the inks to form a first elastic structure and a second elastic structure, subjecting the first elastic structure to a tensile stress along at least one axis, attaching the second elastic structure to the first elastic structure, releasing the application of the tensile stress from the first elastic structure to allow the first elastic structure and second elastic structure to form a 4D-printed elastomeric object, and converting the 4D-printed elastomeric object into the 4D-printed ceramic object.

There is provided a thermoplastic fluororesin tube that, during the production of a catheter, can prevent a gap or air bubbles from being formed in the connection part of the catheter, and can be suitably used for the production of a catheter. A thermoplastic fluororesin tube, the thermoplastic fluororesin tube having tearability in a longitudinal direction, wherein a thermal expansion coefficient in the longitudinal direction upon heating in a gaseous phase at a temperature of 100 C. for 5 minutes is 0% or more.

Curved heat shrink tubing and methods of making the same are described herein. An example method includes inserting heat shrink tubing into a tube, curving the tube, and deforming the heat shrink tubing, inside of the tube, to have a curved shape along a length of the heat shrink tubing where a first length of the heat shrink tubing along an outer radius of the curved shape is longer than a second length of the heat shrink tubing along an inner radius of the curved shape.

Curved heat shrink tubing and methods of making the same are described herein. An example method includes inserting heat shrink tubing into a tube, curving the tube, and deforming the heat shrink tubing, inside of the tube, to have a curved shape along a length of the heat shrink tubing where a first length of the heat shrink tubing along an outer radius of the curved shape is longer than a second length of the heat shrink tubing along an inner radius of the curved shape.

An object of the present invention is to provide a heat shrink tube excellent in peelability and transparency, and a method for producing the heat shrink tube. The present invention provides a peelable heat shrink tube comprising a composition containing a melt-processable fluororesin and PTFE, the PTFE lacking a heat history of its melting point or higher after polymerization and having a specific gravity, as measured according to ASTM D4894, of 2.20 or less. The content of the PTFE is 0.05 to 3.0 wt % based on the total weight of the melt-processable fluororesin and the PTFE. The present invention also provides a method for producing the tube which comprises melt-extruding the composition at a temperature lower than the melting point of the PTFE.