Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

The use of a water-soluble thermoset binder for binder jetting of a cemented carbide or cermet green body is provided. The water-soluble thermoset binder includes a compound A, being at least one organic, non-aromatic substance, including at least two hydroxyl groups and a compound B, being at least one organic, non-aromatic substance, including at least two carboxyl groups, wherein the compound A and compound B are monomers or oligomers. The binder will lead to an increased strength of the printed green body.

The use of a water-soluble thermoset binder for binder jetting of a cemented carbide or cermet green body is provided. The water-soluble thermoset binder includes a compound A, being at least one organic, non-aromatic substance, including at least two hydroxyl groups and a compound B, being at least one organic, non-aromatic substance, including at least two carboxyl groups, wherein the compound A and compound B are monomers or oligomers. The binder will lead to an increased strength of the printed green body.

The object of the invention is a method for the layered construction of bodies comprising refractory molding base material and resol resins as binders having, in addition to phenol, ortho- and/or para-substituted phenols as monomer structural elements and three-dimensional bodies produced according to this method, and a binder for 3-dimensionally constructing bodies, in particular molds and cores for the metal casting.

The object of the invention is a method for the layered construction of bodies comprising refractory molding base material and resol resins as binders having, in addition to phenol, ortho- and/or para-substituted phenols as monomer structural elements and three-dimensional bodies produced according to this method, and a binder for 3-dimensionally constructing bodies, in particular molds and cores for the metal casting.

A three-dimensional printing kit can include a wetting agent, a binding agent, and a particulate build material. The wetting agent an include water, from about 5 wt % to about 60 wt % organic co-solvent, and from about 0.1 wt % to about 10 wt% surfactant. The binding agent can include from about 2 wt % to about 25 wt % polymer binder and a liquid vehicle. The particulate build material can include from about 80 wt % to 100 wt % metal particles that can have a D50 particle size ranging from about 2 gm to about 150 μm.

An example method includes obtaining a geometric compensation profile characterising a relationship between a location of an object within a first fabrication volume having a first depth of build material and a geometrical compensation to be applied to a model of said object. The method further includes determining that a first object is to be generated in a first build operation having a second fabrication volume which has a second depth. The method may further include determining a geometrical compensation to be applied to a model of the first object by: determining a first offset of the first object from the top of the second fabrication volume; identifying the geometrical compensation value associated with a location having the first offset from the top of the first fabrication volume; and determining the compensation to be applied to the model of the first object based on the identified geometrical compensation value.

Herein disclosed is a method of treating a component of a fuel cell, which includes the step of exposing the component of the fuel cell to a source of electromagnetic radiation (EMR). The component comprises a first material. The EMR has a wavelength ranging from 10 to 1500 nm and the EMR has a minimum energy density of 0.1 Joule/cm2. Preferably, the treatment process has one or more of the following effects: heating, drying, curing, sintering, annealing, sealing, alloying, evaporating, restructuring, foaming. In an embodiment, the substrate is a component in a fuel cell. Such component comprises an anode, a cathode, an electrolyte, a catalyst, a barrier layer, a interconnect, a reformer, or reformer catalyst. In an embodiment, the substrate is a layer in a fuel cell or a portion of a layer in a fuel cell or a combination of layers in a fuel cell or a combination of partial layers in a fuel cell.

Herein disclosed is a method of treating a component of a fuel cell, which includes the step of exposing the component of the fuel cell to a source of electromagnetic radiation (EMR). The component comprises a first material. The EMR has a wavelength ranging from 10 to 1500 nm and the EMR has a minimum energy density of 0.1 Joule/cm2. Preferably, the treatment process has one or more of the following effects: heating, drying, curing, sintering, annealing, sealing, alloying, evaporating, restructuring, foaming. In an embodiment, the substrate is a component in a fuel cell. Such component comprises an anode, a cathode, an electrolyte, a catalyst, a barrier layer, a interconnect, a reformer, or reformer catalyst. In an embodiment, the substrate is a layer in a fuel cell or a portion of a layer in a fuel cell or a combination of layers in a fuel cell or a combination of partial layers in a fuel cell.

A method of forming a catalyst is provided herein. The method comprises combining a binder, a support, and an active metal to form a slurry composition. The method further comprises applying the slurry composition using an additive manufacturing process to form a green part. The method further comprises exposing the green part to heat at a temperature of from about 10° C. to about 150° C. to form the hardened part. The method further comprises applying a ceramic-based coating material to the hardened part to form the catalyst.