A pumpable resin system for installation of mine bolts includes a resin injection cylinder comprising a resin chamber and a resin hydraulic cylinder, a catalyst injection cylinder including a catalyst chamber and a catalyst hydraulic cylinder, with the resin hydraulic cylinder synchronized with the catalyst hydraulic cylinder, a hydraulic pump in fluid communication with the resin hydraulic cylinder and the catalyst hydraulic cylinder, a hydraulic reservoir in fluid communication with the hydraulic pump, and a delivery line in fluid communication with the resin injection cylinder and the catalyst injection cylinder. The delivery line is configured to deliver resin and catalyst from the resin injection cylinder and catalyst injection cylinder into a borehole.

A method is disclosed for preparing and dispensing a mixture obtained by mixing at least one first chemically reactive component and at least one second chemically reactive component containing a dispersed solid material i.e. a filler, by a high pressure mixing device comprising a head provided with injectors and one or more interception and supply devices defined by respective nozzles for narrowing the passage of the flows and with correlated plug members that are movable axially and settable for controlling said narrowing. The injectors and the interception and supply device transform the pressure energy of the fluids into kinematic energy of the jets that clash in the mixing chamber to mix the components for turbulence induced by the jets, in which a valve member is slidable, in particular a slide-valve, provided with longitudinal slots for recirculating the components to respective storage tanks. The method provides: removing from at least one tank, by pumping arrangement connected to a respective hydraulic delivery line to the head, a dosed quantity of the at least second chemically reactive second component to with filler material is added; preventing, once said quantity is removed, that the second component flows back from the pumping arrangement to the tank; dosing the component with a controlled flowrate B to the delivery line to the mixing head; keeping the slide-valve closed in a recirculating position and preventing the entry of the at least second component to the head and to the respective recirculating slot and pressurizing, by a dosed quantity Vot, the delivery line to subject the at least second polymeric component to a pressure increase along the delivery line until a value is reached that is near that reached by the passage through the nozzle of the respective interception and supply device; subsequently enabling the entry of the second component into the head to make the second component recirculate to the slots of the slide-valve for a period of time that is comparatively very reduced until it is reduced virtually to zero with respect to a recirculating step of the at least first component through the slide-valve, and subsequently opening by retracting the slide-valve to permit mixing by high pressure collision of the first and at least one second components to dispense the resulting mixture through the mixing chamber and the dispensing conduit for pouring the mixture into a cavity or into a shape to make an object by reaction of the aforesaid first and second chemically reactive components. An apparatus for preparing and dispensing the mixture is also disclosed.

The present invention provides an assembly comprising a thermally conductive thermoplastic polymer as a heat sink to provide thermal management for an electrical/electronic component and a reaction injection molded (RIM) polyurethane to replace the potting compound typically used in such assemblies. In addition to replacing the potting compound, the cured polyurethane forms the part, such as the base of the LED bulb, which heretofore has been a separate component, thus reducing the number of components and saving a production step.

A melting device includes a container capable of melting a material supplied in a free-flowing state and storing the material in a liquid state. The container includes a first storage section for storing the material in the free-flowing state, a second storage section for storing the material in the liquid state, and a dividing section provided between the first storage section and the second storage section and configured to hold back the material, when the material is in a non-molten or free-flowing state and to allow passage of the material from the first storage section into the second storage section, when the material is in a molten or liquid state.

A method for manufacturing a liquid formulation for reaction injection molding for polymerizing a norbornene-based monomer in the presence of a metathesis polymerization catalyst comprising tungsten as a center metal, the liquid formulation comprising a norbornene-based monomer, provided that in case where the norbornene-based monomer includes exo-dicyclopentadiene, a content of exo-dicyclopentadiene is from 0 to 2% by mass of the norbornene-based monomer, an activator of the catalyst, and a specific ether compound.

A method for creating a three dimensional (3D) object from reactive components that form a thermoset product. In one embodiment, a method includes providing first and second reactive components that are effective to form the thermoset product. In one embodiment, the thermoset product includes a urethane and/or urea-containing polymer. In one embodiment, the first reactive component includes an isocyanate and the second reactive component includes a polyol having at least one terminal hydroxyl group, a polyamine having at least one amine that includes an isocyanate reactive hydrogen, or a combination of the polyol and the polyamine. In one embodiment, the first reactive component includes a prepolymer, and optionally the ratio of viscosity of the first and second reactive components is from 1:3 to 3:1. Also provided is a 3D object that includes a completely reacted thermoset product, and a thermoset system that includes a first and a second reactive component.

Devices and methods are described that provide printing of three-dimensional objects using reactive materials such as materials that result in a polyurethane formulation. Three-dimensional printing in accordance with the present disclosure can be performed using an inkjet printer or other systems that deposit or dispense material. A formulation made up of two or more reactive materials and, optionally, one or more UV-curable materials is also provided. The materials can be jetted based on a desired configuration to achieve a maximum reaction between materials, and can be based on desired jetting or molar ratios. By heating or applying energy on the jetted materials, their reaction and related solidifying can be accelerated. Corrective printing is also provided for, and can be used at desired intervals to eliminate printing errors relative to the object as modeled. Systems and methods used in conjunction with all of the same are provided.

A method for creating a three dimensional (3D) object from reactive components that form a thermoset product. In one embodiment, a method includes providing first and second reactive components that are effective to form the thermoset product. In one embodiment, the thermoset product includes a urethane and/or urea-containing polymer. In one embodiment, the first reactive component includes an isocyanate and the second reactive component includes a polyol having at least one terminal hydroxyl group, a polyamine having at least one amine that includes an isocyanate reactive hydrogen, or a combination of the polyol and the polyamine. In one embodiment, the first reactive component includes a prepolymer, and optionally the ratio of viscosity of the first and second reactive components is from 1:3 to 3:1. Also provided is a 3D object that includes a completely reacted thermoset product, and a thermoset system that includes a first and a second reactive component.

Articles are provided including at least one polyurethane prepared from: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; (c) about 0.01 to about 1.0 equivalent of at least one polyol selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, octadecanediol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, bis(2-hydroxyethyl) terephthalate, 1,4-bis(hydroxyethyl)piperazine, N,N′,bis(2-hydroxyethyl)oxamide and mixtures thereof; and (d) about 0.01 to about 0.5 equivalent of at least one polyol selected from the group consisting of glycerol, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof, each based upon the about 1 equivalent of the at least one polyisocyanate, wherein the article has a Gardner Impact strength of at least about 400 in-lb according to ASTM D-5420-04.

Disclosed are processes for In-Mold coating of a substrate. The processes include: introducing a curable composition to a mixhead at a first elevated pressure, the curable composition comprising a first polymeric component and a second polymeric component, the introducing of the curable composition to the mixhead comprising mixing the first and second polymeric components by impingement to form an intermediate composition; introducing the intermediate composition to a secondary mixer, the introducing of the intermediate composition to the secondary mixer comprising mixing the intermediate composition to form a coating composition; and introducing the coating composition into a mold containing a substrate to form a curable coating on a surface of the substrate.