In a method for the chemical smoothing of components composed of plastic, said components are immersed at atmospheric pressure in a pre-temperature- controlled process liquid composed of glycol.

A process to cure and/or modify the surface of a three dimensional (3D) printed part comprising the steps of immersing a three dimensional (3D) printed part, containing reactive moieties, into a liquid bath at an elevated temperature to effect polymerization of the reactive moieties of the 3D printed part to provide a cured 3D printed part is described. The liquid bath can further contain reactive molecules that can react with the surface of the 3D printed part to provide a coating which alters the surface characteristics of the 3D printed part.

In a golf ball having a core and a cover of one or more layer encasing the core, an outermost layer of the cover is molded of a thermoplastic material selected from the group consisting of polyurethane, polyurea and mixtures thereof, and the surface of the cover is treated with a polyisocyanate compound that is free of organic solvent. A method of manufacturing the golf ball is also described. Such golf balls are endowed with an excellent spin performance and scuff resistance, in addition to which productivity of the golf balls is high.

The method according to the present disclosure provides a plastic housing or other plastic component also according to the present disclosure, wherein the plastic contains a flame retardant, preferably red phosphorus. According to the present disclosure, near-surface regions of the plastic housing or of the rest of the component are depleted of phosphorus. This measure, without impairment of the flame retardancy of the phosphorus used as flame retardant, achieves inertization of the plastic surface in that the plastic surface no longer corrosively attacks adjacent metal components and especially electrical or electronic components.

Technologies are generally described to increase a surface smoothness of a 3D printed article implementing a water-based treatment using layer by layer (LBL) deposition. An initial 3D printed article having an anionic surface may be treated with a first aqueous solution comprising at least one polycation that may bind to the anionic surface to produce a first treated surface, which may be rinsed with water to remove the first aqueous solution. The first treated surface may be treated with a second aqueous solution comprising at least one anionic microparticle that may bind to the polycation to produce a final 3D printed article having a second treated surface, which may be rinsed with water to remove the second aqueous solution. The bound polycation and anionic microparticle may be present as a single layer in the final 3D printed article that may act as a conformal coating to increase the surface smoothness.

Various embodiments disclosed relate to melt-stabilized materials including ultra high molecular weight polyethylene (UHMWPE), methods of making the same, and medical implants including the same. In various embodiments, the present invention provides a method of melt-stabilizing a material including UHMWPE. The method includes obtaining or providing a solid material including UHMWPE including a first concentration of free-radicals. The method includes coating at least part of the solid material with a liquid composition including at least one antioxidant, to provide a coated solid material. The method includes heating the coated solid material in an environment including oxygen, the heating being sufficient to melt at least part of the UHMWPE, to provide a heated material. The method also includes solidifying the heated material, to provide a melt-stabilized material including UHMWPE including a second concentration of free-radicals, wherein the second concentration of free-radicals is less than the first concentration of free-radicals.

A method of modifying a coating material includes applying a fluid including a population of particles to a wet coating material disposed on a substrate. The method also includes drying the wet coating material so as to give rise to a coated article, where the particles are at least partially embedded in a surface of the dried coating material. The particles can be metallic nanowires, and a loading of the metallic nanowires in the dried coating material can be above an electric percolation threshold.

Low waste methods for three-dimensional printing techniques are provided. A method includes performing a preceding additive infusion process including: solubilizing an additive into a medium in a supercritical fluid state; contacting a preceding material with the medium to infuse a portion of the additive into the preceding material to form a preceding additive-infused material; and separating remaining additive from the medium. Further, the method includes performing at least one succeeding additive infusion process including: solubilizing the remaining additive and, optionally, additional additive, into the medium in a supercritical fluid state; and contacting a succeeding material with the medium to infuse at least a portion of the remaining and additional additive into the succeeding material to form a succeeding additive-infused material, wherein the medium from the preceding additive infusion process is reused in the at least one succeeding additive infusion process.

Augmented three-dimensional (3D) printing systems and methods for constructing and mineralizing a hydrogel structure with defined geometry are disclosed. One example embodiment is a system for three-dimensional printing and mineralizing a polymer. The system includes a three-dimensional printer unit with a syringe extruder, a fluid delivery system operatively coupled to the three-dimensional printer unit, and a control unit. The control unit is operatively coupled to the three-dimensional printer unit and fluid delivery system, and is configured to (i) cause the three-dimensional printer unit to print a portion of a three-dimensional polymer object, (ii) cause the fluid delivery system to flush the portion of the three-dimensional polymer object with a fluid to mineralize the portion of the three-dimensional polymer object, and (iii) cause the three-dimensional printer unit to print a subsequent portion of the three-dimensional polymer object. Applications of embodiments include manufacturing of tooth, bone, and other biomaterial articles.

The invention relates to a method for the post-treatment of 3D objects (10) printed from a light-curing resin formulation. A 3D object (10) removed from a 3D printer is post-treated according to the following steps: a) exposing the surface (11) of the 3D object (10) to a post-treatment liquid (16) comprising a light-curing resin formulation for a prescribed exposure time, wherein the post-treatment liquid (16) and the exposure time are chosen such that the post-treatment liquid (16) can penetrate into a crack (12) or a pore (13) on the surface (11) of the 3D object within the exposure time as a result of capillarity; b) removing the post-treatment liquid (16) remaining on the surface of the 3D object (10); and c) irradiating the 3D object (10) with light for post-curing the light-curing resin formulation used for the printing of the 3D object (10) and curing the post-treatment liquid (16) that has penetrated into cracks (12) and/or pores (13) on the surface (11) of the 3D object (10).