The invention relates to the use of compounds of formulae (I) and/or (II) as colorless IR absorbers wherein M is Ni, Pd, Pt, Au, Ir, Fe, Zn, W, Cu, Mo, In, Mn, Co, Mg, V, Cr or Ti, X.sub.1, X.sub.2 and X.sub.3 are each independently of the others sulfur or oxygen, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each independently of the others hydrogen, NR.sub.7R.sub.8, unsubstituted or substituted C.sub.1-C.sub.18alkyl, C.sub.1-C.sub.18 alkyl wherein the alkylene chain is interrupted with oxygen, unsubstituted or substituted C.sub.1-C.sub.18alkenyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, R.sub.7 and R.sub.8, each independently of the other, being unsubstituted or substituted C.sub.1-C.sub.18alkyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, a further IR absorber optionally being added to the compounds of formulae (I) and (II). The invention relates also to novel dithiolene compounds of formulae (I) and (II) wherein X.sub.1 is oxygen and X.sub.2 and X.sub.3 are oxygen or sulfur. The invention relates furthermore to novel dithiolene compounds of formulae (I) and (II) wherein R.sub.1 to R.sub.6 are NR.sub.7R.sub.8. ##STR00001##

The invention relates to the use of compounds of formulae (I) and/or (II) as colorless IR absorbers wherein M is Ni, Pd, Pt, Au, Ir, Fe, Zn, W, Cu, Mo, In, Mn, Co, Mg, V, Cr or Ti, X.sub.1, X.sub.2 and X.sub.3 are each independently of the others sulfur or oxygen, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each independently of the others hydrogen, NR.sub.7R.sub.8, unsubstituted or substituted C.sub.1-C.sub.18alkyl, C.sub.1-C.sub.18 alkyl wherein the alkylene chain is interrupted with oxygen, unsubstituted or substituted C.sub.1-C.sub.18alkenyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, R.sub.7 and R.sub.8, each independently of the other, being unsubstituted or substituted C.sub.1-C.sub.18alkyl, unsubstituted or substituted aryl, unsubstituted or substituted arylalkyl or unsubstituted or substituted heteroarylalkyl, a further IR absorber optionally being added to the compounds of formulae (I) and (II). The invention relates also to novel dithiolene compounds of formulae (I) and (II) wherein X.sub.1 is oxygen and X.sub.2 and X.sub.3 are oxygen or sulfur. The invention relates furthermore to novel dithiolene compounds of formulae (I) and (II) wherein R.sub.1 to R.sub.6 are NR.sub.7R.sub.8. ##STR00001##

A transparent acrylic-based polymer composition has an increased resistance to alcohols, oils and fats. The polymer composition contains: (A) a copolymer of alkyl(meth)acrylates, aromatic vinyl monomer and unsaturated carboxylic acid anhydride; (B) a copolymer containing aromatic vinyl monomer and a vinyl cyanide monomer; and (C) a particulate core-shell type graft copolymer containing a butadiene-based core as a rubbery phase and a copolymer containing alkyl(meth)acrylates and, optionally, aromatic vinyl monomer as a hard phase. The components A and B form a polymer matrix and the particulate core-shell type graft copolymer C is dispersed in said polymer matrix.

A oil gel composition, consisting essentially of: 65-80 wt. % of a mineral oil, 15-25 wt. % of a hydrogenated styrenic block copolymer (HSBC), 1 to 15 wt. % of glass spheres having an average particle size of at least 15 microns, 1 at least 50 wt. % of a plasticizer selected from mineral oil, a paraffinic oil, an oil-enriched in paraffin, and mixtures thereof, and 0.25-5 wt. % of a tack reducing component selected from the group of steric acid, metal stearates, long chain fatty acids, fatty acid salts, fatty acid esters, amide waxes, ethylene-bis-stearamides, erucamide, polyester modified siloxanes, and mixtures thereof. The oil gel composition has an average peel strength of less than 0.3 lbf/in measured according to ASTM D 1876. Articles formed from the oil gel composition are characterized as being tack-free.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component. Printed parts having piezoelectric properties may be formed using a composite filament comprising a plurality of piezoelectric particles dispersed in a thermoplastic polymer. The composite filaments may be formed through melt blending and extrusion. The composite filament is compatible with fused filament fabrication and has a length and diameter compatible with fused filament fabrication, and the piezoelectric particles are substantially non-agglomerated and dispersed along the length of the composite filament. The piezoelectric particles may remain substantially non-agglomerated when dispersed in the thermoplastic polymer through melt blending. Additive manufacturing processes may comprise heating such a composite filament at or above a melting point or softening temperature thereof to form a softened composite material, and depositing the softened composite material layer by layer to form a printed part.

In one aspect, a method of packaging a semiconductor module includes providing a semiconductor module having a first surface, a second surface opposite the first surface and edge sides extending between the first surface and the second surface. A packaging assembly is formed at least partly by a 3D printing process. The packaging assembly includes the semiconductor module and a protective covering that extends over the first surface.

In a 3D composite printer, toolpaths defining fill material shells are received, as are toolpaths defining support material shells. A 3D toolpath defining a long fiber composite material curved shell is also received. A fill material deposition head traces the toolpaths to deposit some of the fill material shells or support material shells at least in part non-parallel to a printing substrate. A long fiber deposition head traces the 3D toolpath at least in part non-parallel to the printing substrate to deposit the long fiber composite material curved, concave, ring, tube, or winding shells to enclose, surround, or envelop at least a portion of the fill or support material shells.

The present invention relates to a thermoplastic resin composition with excellent chemical resistance and, more specifically, to a resin composition for blow molding and a molded product obtained by molding the same, the composition maintaining the balance of flowability and impact resistance and improving chemical resistance by controlling the glass transition temperature (Tg) and the weight average molecular weight (Mw) of an α-methylstyrene (AMS)-based heat-resistant resin in a copolymer of vinyl cyanide compound-rubbery polymer-aromatic vinyl compound, having reinforced heat resistance, particularly, in an acrylonitrile-butadiene-styrene (ABS) copolymer resin. According to the present invention, an ABS resin composition for blow molding, having excellent chemical resistance while maintaining the balance of flowability, impact resistance and heat resistance to be of at least the same level, and a molded product obtained by applying the same can be obtained.

An apparatus and method for manufacturing a crash pad with a foaming layer formed by injecting a foaming solution between a core and a skin are disclosed. The apparatus includes a first mold and a second mold used to form the skin by injecting molten resin of a skin material into a skin forming cavity when the first and second molds are combined. In addition, a third mold and the fourth mold form the core by injecting molten resin of a core material into a core forming cavity when the third and fourth molds are combined. The first mold has a vacuum aperture in an inner surface of the first mold to adsorb and fix a thread to implement a stitch before the forming of the skin, and the vacuum aperture exerts a vacuum suctioning force to absorb and fix via a vacuum pressure applied from a vacuum pressure providing unit.

This invention relates to a multilayered patch, comprising: a first layer, and a pressure-sensitive adhesive layer comprising a mixture of: a styrene-based triblock copolymer, a styrene-based diblock copolymer, and at least one hydrocarbon resin selected from the group of aromatic modified aliphatic hydrocarbon resins, partially hydrogenated resins, and fully hydrogenated resins; wherein the first layer comprises a metal or a metal alloy, or wherein the first layer comprises a polymer and has a strain at break of at least 10%, the strain at break being measured according to ASTM D638 or ASTM D882. The multilayered patch exhibits favourable properties as sealing material for vehicle body holes against ingression of noise, moisture and/or dirt. Also described are methods of sealing and methods of manufacturing the multilayered patch.